SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	o-DICHLORO BENZENE (1, 2-dichlorobenzene)
Catalogue No. :	AL1704	Product form :	Substance
CAS Number :	95-50-1	EC Number :	202-425-9
Grade :		EC Index Number :	602-034-00-7
Chemical Formula :	C6H4Cl2 - (CClCClCHCHCHCH)	HSN Code :	29039120
Synonyms :	o-Dichlorobenzene
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), Category 4 H302 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R22 Xi; R36/37/38 N; R50/53 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS07 GHS09
Signal word (CLP) :	Warning
Hazard statements (CLP) :	H302 - Harmful if swallowed H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H410 - Very toxic to aquatic life with long lasting effects
Precautionary statements (CLP) :	P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P273 - Avoid release to the environment P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P501 - Dispose of contents/container to ...
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		1,2-DICHLOROBENZENE
CAS No. :		95-50-1
EC Index No. :		602-034-00-7
EC No. :		202-425-9
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact :	Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label).
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries after inhalation : May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a wellventilated area.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	147 g/mol
Colour :	Clear Colorless.
Odour :	pleasant odor.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	< 1
Melting point :	-18 - -17
Freezing point :	No data available
Boiling point :	178 - 180
Flash point :	66 °C
Auto-ignition temperature :	648 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	1.6 hPa at 20°C
Relative vapour density at 20°C :	5.1
Density :	1.3 g/cm3
Solubility :	Water: Practically insoluble in water
Log Pow :	5
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.022 - 0.092 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed.
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye irritation.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	May cause respiratory irritation.
Specific target organ toxicity (repeated exposure) :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	1,2-DICHLOROBENZENE (95-50-1) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	1,2-DICHLOROBENZENE (95-50-1) Log Pow 5
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1591
UN-No. (IMDG) :	1591
UN-No. (IATA) :	1591
UN-No. (ADN) :	1591
UN-No. (RID) :	1591
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	O-DICHLOROBENZENE
Proper Shipping Name (IMDG) :	O-DICHLOROBENZENE
Proper Shipping Name (IATA) :	O-DICHLOROBENZENE
Proper Shipping Name (ADN) :	O-DICHLOROBENZENE
Proper Shipping Name (RID) :	O-DICHLOROBENZENE
Transport document description (ADR) :	UN 1591, O-DICHLOROBENZENE, 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1591, O-DICHLOROBENZENE, 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1591, O-DICHLOROBENZENE, 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1591, O-DICHLOROBENZENE, 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1591, O-DICHLOROBENZENE, 6.1, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1
Danger labels :	6.1
IMDG
Transport hazard class(es) :	6.1
Danger labels :	6.1
IATA
Transport hazard class(es) :	6.1
Danger labels :	6.1
ADN
Transport hazard class(es) :	6.1
Danger labels :	6.1
RID
Transport hazard class(es) :	6.1
Danger labels :	6.1
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T1 Special provision (ADR) : 279 Limited quantities (ADR) : 5L Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2Z
- Transport by sea
Special provision (IMDG) : 279 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A MFAG-No : 152
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y642 PCA limited quantity max net quantity (IATA) : 2L PCA packing instructions (IATA) : 655 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 663 CAO max net quantity (IATA) : 220L Special provision (IATA) : A113 ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T1 Special provisions (ADN) : 279, 802 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : T1 Special provision (RID) : 279 Limited quantities (RID) : 5L Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W12 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE8 Hazard identification number (RID) : 60
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions 1,2-DICHLOROBENZENE is not on the REACH Candidate List 1,2-DICHLOROBENZENE is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 2; WGK No 74) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to
Denmark
Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H302 Harmful if swallowed H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H410 Very toxic to aquatic life with long lasting effects R22 Harmful if swallowed R36/37/38 Irritating to eyes, respiratory system and skin R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment N Dangerous for the environment Xi Irritant Xn Harmful