SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	BENZYL BROMIDE
Catalogue No. :	AL0652	Product form :	Substance
CAS Number :	100-39-0	EC Number :	202-847-3
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	29039990
Synonyms :	a-Bromotoluene
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 3 H226 Acute toxicity (oral), Category 4 H302 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 1 H318 Germ cell mutagenicity, Category 1B H340 Carcinogenicity, Category 1B H350 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Specific target organ toxicity Repeated exposure, Category 2 H373 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.2; R45 Muta.Cat.1; R46 T; R23 Xn; R22 Xn; R48/22 Xi; R41 Xi; R37 Xi; R38 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS05 GHS07 GHS08
Signal word (CLP) :	Danger
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		BENZYL CHLORIDE Extra Pure
CAS No. :		100-39-0
EC No. :		202-847-3
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Take off contaminated clothing. Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth out with water. Do not induce vomiting. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : Causes severe skin burns and eye damage. Symptoms/injuries after inhalation : May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/injuries after skin contact : May cause an allergic skin reaction.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Avoid contact with skin and eyes.
6.1.2. For emergency responders
Emergency procedures	Stop release
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Shovel or sweep up and put in a closed container for disposal. Clean contaminated surfaces with an excess of water. Clean up immediately by sweeping or vacuum.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	126.59 g/mol
Colour :	Clear Colorless.
Odour :	pungent odour.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-43 °C
Freezing point :	No data available
Boiling point :	177 - 181
Flash point :	60 °C
Auto-ignition temperature :	6270 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	1.6 at 20C
Relative vapour density at 20°C :	4.36
Density :	1.1 g/cm3
Solubility :	Water: Insoluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Open flame. Overheating. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed.
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye damage.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	May cause genetic defects.
Carcinogenicity :	May cause cancer.
STOT-single exposure :	May cause respiratory irritation.
STOT-repeated exposure :	May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1738
UN-No. (IMDG) :	1738
UN-No. (IATA) :	1738
UN-No. (ADN) :	1738
UN-No. (RID) :	1738
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	BENZYL CHLORIDE
Proper Shipping Name (IMDG) :	BENZYL CHLORIDE
Proper Shipping Name (IATA) :	BENZYL CHLORIDE
Proper Shipping Name (ADN) :	BENZYL CHLORIDE
Proper Shipping Name (RID) :	BENZYL CHLORIDE
Transport document description (ADR) :	UN 1738, BENZYL CHLORIDE, 6.1 (8), II
Transport document description (IMDG) :	UN 1738, BENZYL CHLORIDE, 6.1 (8), II
Transport document description (IATA) :	UN 1738, BENZYL CHLORIDE, 6.1 (8), II
Transport document description (ADN) :	UN 1738, BENZYL CHLORIDE, 6.1 (8), II
Transport document description (RID) :	UN 1738, BENZYL CHLORIDE, 6.1 (8), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
IMDG
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
IATA
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
ADN
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
RID
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TC1 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E4 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T8 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S19 Hazard identification number (Kemler No.) : 68 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 2X
- Transport by sea
Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 IBC special provisions (IMDG) : B20 Tank instructions (IMDG) : T8 Tank special provisions (IMDG) : TP2, TP13 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : D Stowage and handling (IMDG) : SW2, H1 Properties and observations (IMDG) : Colourless liquid with a pungent odour. Causes tears.Immiscible with water, but hydrolyses slowly in contact with it. In the presence of moisture, corrosive to most metals. Toxic if swallowed, by skin contact or by vapour inhalation. Causes burns to skin, eyes and mucous membranes. MFAG-No : 156
- Air transport
PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : 653 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 660 CAO max net quantity (IATA) : 30L ERG code (IATA) : 6C
- Inland waterway transport
Classification code (ADN) : TC1 Special provisions (ADN) : 802 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E4 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : TC1 Limited quantities (RID) : 0 Excepted quantities (RID) : E4 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T8 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE5 Hazard identification number (RID) : 68
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions BENZYL CHLORIDE Extra Pure is not on the REACH Candidate List BENZYL CHLORIDE Extra Pure is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to AwSV; ID No. 33) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : BENZYL CHLORIDE Extra Pure is listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Carc. 1B Carcinogenicity, Category 1B Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Flam. Liq. 3 Flammable liquids, Category 3 Muta. 1B Germ cell mutagenicity, Category 1B Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H226 Flammable liquid and vapour. H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. H340 May cause genetic defects. H350 May cause cancer. H373 May cause damage to organs through prolonged or repeated exposure. R22 Harmful if swallowed R23 Toxic by inhalation R37 Irritating to respiratory system R38 Irritating to skin R41 Risk of serious damage to eyes R45 May cause cancer R46 May cause heritable genetic damage R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed T Toxic Xi Irritant Xn Harmful