BISMARCK BROWN (R) For Microscopy |
| Synonyms : Basic Brown 4 |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
|||
|---|---|---|---|
1.1 Product identifier |
|||
| Chemical Name : | BISMARCK BROWN R (M.S.) | ||
| Catalogue No. : | AL0720 | Product form : | Substance |
| CAS Number : | 5421-66-9 | EC Number : | |
| Grade : | EC Index Number : | ||
| Chemical Formula : | HSN Code : | 32129090 | |
| Synonyms : | Vesuvine / Basic Brown 4 | ||
| Chemical Structure : |
|
||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
|||
| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
|||
| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
||
1.4 Emergency Contact Details |
|||
| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
||
SECTION 2: Hazards identification |
|
|---|---|
2.1 Classification of the substance or mixture |
|
| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
|
Mixture/Substance: SDS EU 2015: According to Annex II of Regulation (EC) No. 453/2010 (REACH Annex II) Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Full text of classification categories and H statements : see section 16 |
|
| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
|
| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS07
|
| Signal word (CLP) : | Warning |
| Hazard statements (CLP) : | H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation |
| Precautionary statements (CLP) : | P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P220 - Keep/Store away from clothing/¦/combustible materials |
2.3 Other hazards |
|
| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
|||
|---|---|---|---|
3.1. Substance |
|||
| Not applicable | |||
| CAS No. : | 5421-66-9 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
|||
| Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
| Water | (CAS No) 7732-18-5 (EC no) 231-791-2 | 75 - 99 | Not classified |
| Nitric acid | (CAS No) 7697-37-2 (EC no) 231-714-2 (EC index no) 007-004-00-1 | 1 - 5 | Ox. Liq. 1, H271 Skin Corr. 1A, H314 |
| BISMUTH (METAL) GRANULAR 99.5% | (CAS No) 7440-69-9 | 0.1 - 1 | Not classified |
| Full text of H-phrases: see section 16 | |||
SECTION 4: First aid measures |
|
|---|---|
4.1 Description of first aid measures |
|
| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. |
| First-aid measures after skin contact : | Gently wash with plenty of soap and water. |
| First-aid measures after eye contact : | Rinse immediately with plenty of water. |
| First-aid measures after ingestion : | Rinse mouth. |
4.2 Most important symptoms and effects, both acute and delayed |
|
| Symptoms relating to use : | No additional information available |
4.3 Indication of any immediate medical attention and special treatment needed |
|
| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
|
|---|---|
5.1 Extinguishing media |
|
| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use extinguishing media containing water. |
5.2 Special hazards arising from the substance or mixture |
|
| Special procedures : | No additional information available |
5.3 Advice for firefighters |
|
| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
|
|---|---|
6.1 Personal precautions, protective equipment and emergency procedures |
|
6.1.1. For non-emergency personnel |
|
| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
|
| Protective equipment | Use personal protective equipment as required |
6.2 Environmental precautions |
|
| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
|
| Methods for cleaning up : | On land, sweep or shovel into suitable containers. Collect spillage. |
6.4 Reference to other sections |
|
| Reference : | No additional information available |
SECTION 7: Handling and storage |
|
|---|---|
7.1 Precautions for safe handling |
|
| Precautions for safe handling : | Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour. |
| Hygiene measures : | Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
|
| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
|
| No additional information available | |
SECTION 8: Exposure controls/personal protection |
|
|---|---|
8.1 Control parameters |
|
| No additional information available | |
8.2 Exposure controls |
|
| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
|
|---|---|
9.1 Information on basic physical and chemical properties |
|
| Physical state : | Liquid Colour |
| Colour : | Clear Colorless. |
| Odour : | No data available |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | No data available |
| Freezing point : | No data available |
| Boiling point : | No data available |
| Flash point : | No data available |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | No data available |
| Solubility : | No data available |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
|
| No additional information available | |
SECTION 10: Stability and reactivity |
|
|---|---|
10.1 Reactivity |
|
| No additional information available | |
10.2 Chemical stability |
|
| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
|
| No additional information available | |
10.4 Conditions to avoid |
|
| Direct sunlight. Overheating. Open flame. Sparks. Heat. | |
10.5 Incompatible materials |
|
| No additional information available | |
10.6 Hazardous decomposition products |
|
| No additional information available |
SECTION 11: Toxicological information |
|
|---|---|
11.1 Information on toxicological effects |
|
| Acute toxicity : | Not classified |
| Skin corrosion/irritation : | Causes skin irritation. |
| Serious eye damage/irritation : | Causes serious eye irritation. |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| Reproductive toxicity : | Not classified |
| Specific target organ toxicity (single exposure) : | May cause respiratory irritation. |
| Specific target organ toxicity (repeated exposure) : | Not classified |
SECTION 12: Ecological information |
|
|---|---|
12.1 Toxicity |
|
| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
|
| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
|
| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
|
| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
|
| No additional information available | |
12.6 Other adverse effects |
|
| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
|
|---|---|
13.1 Waste treatment methods |
|
| Additional Info : | No additional information available |
SECTION 14: Transport information |
|
|---|---|
| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
|
| UN-No. (ADR) : | 3264 |
| UN-No. (IMDG) : | 3264 |
| UN-No. (IATA) : | 3264 |
| UN-No. (ADN) : | 3264 |
| UN-No. (RID) : | 3264 |
14.2. UN proper shipping name |
|
| Proper Shipping Name (ADR) : | CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. |
| Proper Shipping Name (IMDG) : | CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. |
| Proper Shipping Name (IATA) : | CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. |
| Proper Shipping Name (ADN) : | CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. |
| Proper Shipping Name (RID) : | CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. |
| Transport document description (ADR) : | UN 3264, CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, III |
| Transport document description (IMDG) : | UN 3264, CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, III |
| Transport document description (IATA) : | UN 3264, CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, III |
| Transport document description (ADN) : | UN 3264, CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, III |
| Transport document description (RID) : | UN 3264, CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, III |
14.3. Transport hazard class(es) |
|
| ADR | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8 
|
| IMDG | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
|
| IATA | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
|
| ADN | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
|
| RID | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
|
14.4. Packing group |
|
| Packing group (ADR) : | III |
| Packing group (IMDG) : | III |
| Packing group (IATA) : | III |
| Packing group (ADN) : | III |
| Packing group (RID) : | III |
14.5. Environmental hazards |
|
| Dangerous for the environment : | No |
| Marine pollutant : | Yes (IMDG only) |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
|
| - Overland transport | |
|
Classification code (ADR) : C1 Special provision (ADR) : 274 Limited quantities (ADR) : 5L Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP1, TP28 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X APP code : B |
|
| - Transport by sea | |
|
Special provision (IMDG) : 223, 274 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP1, TP28 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : A Stowage and handling (IMDG) : SW2 MFAG-No : 154 |
|
| - Air transport | |
|
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y841 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 852 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 856 CAO max net quantity (IATA) : 60L Special provision (IATA) : A3 ERG code (IATA) : 8L |
|
| - Inland waterway transport | |
|
Classification code (ADN) : C1 Special provisions (ADN) : 274 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 |
|
| - Rail transport | |
|
Classification code (RID) : C1 Special provision (RID) : 274 Limited quantities (RID) : 5L Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP1, TP28 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W12 Colis express (express parcels) (RID) : CE8 Hazard identification number (RID) : 80 |
|
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
|
| Not applicable | |
SECTION 15: Regulatory information |
|---|
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| Contains no substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances. |
| 15.1.2. National regulations |
| Germany |
| AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
||||||||||||