NICKEL SULPHATE HEXAHYDRATE AR/ACS |
| Synonyms : Nickel(II) sulfate hexahydrate |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | NICKEL SULPHATE AR (hexahydrate) | ||
| Catalogue No. : | AL3232 | Product form : | Substance |
| CAS Number : | 10101-97-0 | EC Number : | |
| Grade : | EC Index Number : | ||
| Chemical Formula : | HSN Code : | 28332400 | |
| Synonyms : | Nickel(II) sulfate hexahydrate | ||
| Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Acute toxicity (oral), Category 4 H302 Acute toxicity (inhalation:dust,mist) Category 4 H332 Skin corrosion/irritation, Category 2 H315 Sensitisation Respiratory, category 1 H334 Sensitisation Skin, category 1 H317 Germ cell mutagenicity, Category 2 H341 Carcinogenicity (inhalation) Category 1A H350i Reproductive toxicity, Category 1A H360D Specific target organ toxicity Repeated exposure, Category 1 H372 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of classification categories and H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Carc.Cat.1; R49 Muta.Cat.3; R68 Repr.Cat.1; R61 T; R48/23 Xn; R20/22 R42 Xi; R38 R43 N; R50/53 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS07
 GHS08
 GHS09
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H302+H332 - Harmful if swallowed or if inhaled H315 - Causes skin irritation H317 - May cause an allergic skin reaction H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H341 - Suspected of causing genetic defects H350i - May cause cancer by inhalation H360D - May damage the unborn child H372 - Causes damage to organs through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects |
| Precautionary statements (CLP) : | P201 - Obtain special instructions before use P260 - Do not breathe dust/fume/gas/mist/vapours/spray P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P308+P313 - IF exposed or concerned: Get medical advice/attention P501 - Dispose of contents/container to ... |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | NICKEL SULPHATE HEXAHYDRATE AR/ACS | ||
| CAS No. : | 10101-97-0 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
| First-aid measures after skin contact : | Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label). If skin irritation or rash occurs: Gently wash with plenty of soap and water. |
| First-aid measures after eye contact : | Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. |
| First-aid measures after ingestion : | Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/injuries : May cause damage to organs. Causes damage to organs through prolonged or repeated exposure. Symptoms/injuries after inhalation : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Avoid breathing dust/fume/gas/mist/vapours/spray |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Clean up immediately by sweeping or vacuum. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Avoid breathing dust/fume/gas/mist/vapours/spray. Do not breathe dust/fume/gas/mist/vapours/spray. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear respiratory protection Other information : Do not breathe dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Solid Colour |
| Colour : | Emerald green crystalline. |
| Odour : | odourless. |
| Odour threshold : | No data available |
| pH value : | 4.5 |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 1000 °C |
| Freezing point : | No data available |
| Boiling point : | No data available |
| Flash point : | No data available |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | No data available |
| Density : | 2.03 g/cm3 |
| Solubility : | Water: 75.6 g/100 cc water |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Direct sunlight. Air contact. Moisture. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Oral: Harmful if swallowed. Inhalation:dust/mist: Harmful if inhaled. |
| Skin corrosion/irritation : | Causes skin irritation. pH: 4.5 |
| Serious eye damage/irritation : | Not classified pH: 4.5 |
| Respiratory or skin sensitisation : | May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. |
| Germ cell mutagenicity : | Suspected of causing genetic defects. |
| Carcinogenicity : | May cause cancer by inhalation. |
| Reproductive toxicity : | May damage the unborn child. |
| Specific target organ toxicity (single exposure) : | Not classified |
| Specific target organ toxicity (repeated exposure) : | Causes damage to organs through prolonged or repeated exposure. |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | Ecology - water : Very toxic to aquatic life with long lasting effects. |
12.2 Persistence - degradability |
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| Persistence - degradability : | NICKEL SULPHATE HEXAHYDRATE AR/ACS (10101-97-0) Persistence and degradability May cause long-term adverse effects in the environment. |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 3288 |
| UN-No. (IMDG) : | 3288 |
| UN-No. (IATA) : | 3288 |
| UN-No. (ADN) : | 3288 |
| UN-No. (RID) : | 3288 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | TOXIC SOLID, INORGANIC, N.O.S. |
| Proper Shipping Name (IMDG) : | TOXIC SOLID, INORGANIC, N.O.S. |
| Proper Shipping Name (IATA) : | TOXIC SOLID, INORGANIC, N.O.S. |
| Proper Shipping Name (ADN) : | TOXIC SOLID, INORGANIC, N.O.S. |
| Proper Shipping Name (RID) : | TOXIC SOLID, INORGANIC, N.O.S. |
| Transport document description (ADR) : | UN 3288, TOXIC SOLID, INORGANIC, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 3288, TOXIC SOLID, INORGANIC, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 3288, TOXIC SOLID, INORGANIC, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 3288, TOXIC SOLID, INORGANIC, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 3288, TOXIC SOLID, INORGANIC, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1 
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| IMDG | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| IATA | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| ADN | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| RID | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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14.4. Packing group |
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| Packing group (ADR) : | III |
| Packing group (IMDG) : | III |
| Packing group (IATA) : | III |
| Packing group (ADN) : | III |
| Packing group (RID) : | III |
14.5. Environmental hazards |
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| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : T5 Special provision (ADR) : 274 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P002, IBC08, LP02, R001 Special packing provisions (ADR) : B3 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T1 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAH, L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Bulk (ADR) : VC1, VC2, AP7 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X |
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| - Transport by sea | |
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Special provision (IMDG) : 223, 274 Limited quantities (IMDG) : 5 kg Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P002, LP02 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 Tank instructions (IMDG) : T1 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A MFAG-No : 151 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y645 PCA limited quantity max net quantity (IATA) : 10kg PCA packing instructions (IATA) : 670 PCA max net quantity (IATA) : 100kg CAO packing instructions (IATA) : 677 CAO max net quantity (IATA) : 200kg Special provision (IATA) : A3, A5 ERG code (IATA) : 6L |
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| - Inland waterway transport | |
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Classification code (ADN) : T5 Special provisions (ADN) : 274, 802 Limited quantities (ADN) : 5 kg Excepted quantities (ADN) : E1 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : T5 Special provision (RID) : 274 Limited quantities (RID) : 5kg Excepted quantities (RID) : E1 Packing instructions (RID) : P002, IBC08, LP02, R001 Special packing provisions (RID) : B3 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T1 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAH, L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Bulk (RID) : VC1, VC2, AP7 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 60 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions NICKEL SULPHATE HEXAHYDRATE AR/ACS is not on the REACH Candidate List NICKEL SULPHATE HEXAHYDRATE AR/ACS is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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