PLATINUM CHLORIDE Extra Pure

PLATINUM CHLORIDE Extra Pure

Synonyms : Hexachloroplatinic acid; Hydrogen hexachloroplatinate(IV); Platinic chloride

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : PLATINUM CHLORIDE (about 40% Pt)
Catalogue No. : AL3600 Product form : Substance
CAS Number : 18497-13-7 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 28439019
Synonyms : Hexachloroplatinic acid; Hydrogen hexachloroplatinate(IV); Platinic chloride
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral),
Category 3
H301
Skin corrosion/irritation,
Category 1B
H314
Sensitisation
Respiratory, category 1
H334
Sensitisation Skin,
category 1
H317
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
T; R25
R42
C; R34
R43
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS06GHS06 GHS05GHS05 GHS08GHS08
Signal word (CLP) : Danger
Hazard statements (CLP) : H301 - Toxic if swallowed
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
Precautionary statements (CLP) : P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or
doctor/physician
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : PLATINUM CHLORIDE Extra Pure
CAS No. : 18497-13-7
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor/physician. If breathing is difficult,
remove victim to fresh air and keep at rest in a position comfortable for breathing. If
experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Immediately call a POISON CENTER or doctor/physician. Wash with
plenty of soap and water. If skin irritation or rash occurs: Get medical
advice/attention. Specific treatment (see ... on this label). Wash contaminated
clothing before reuse.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER or
doctor/physician.
First-aid measures after ingestion : Rinse mouth. Immediately call a POISON CENTER or doctor/physician. Specific
treatment (see ... on this label). Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : Causes severe skin burns and eye damage.
Symptoms/injuries after inhalation : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May
cause an allergic skin reaction.
Symptoms/injuries after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious
health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations.
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : In case of inadequate ventilation wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 409.81 g/mol
Colour : Dark Brown.
Odour : odourless.
Odour threshold : No data available
pH value : 5 - 6
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 581 °C
Freezing point : No data available
Boiling point : 1150 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : 18
Density : 2.43 g/cm3
Solubility : Water: Soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Toxic if swallowed.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 5 - 6
Serious eye damage/irritation : Serious eye damage, category 1, implicit
pH: 5 - 6
Respiratory or skin sensitisation : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May
cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Toxic if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...
Ecology - waste materials : Hazardous waste due to toxicity.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2507
UN-No. (IMDG) : 2507
UN-No. (IATA) : 2507
UN-No. (ADN) : 2507
UN-No. (RID) : 2507
14.2. UN proper shipping name
Proper Shipping Name (ADR) : CHLOROPLATINIC ACID, SOLID
Proper Shipping Name (IMDG) : CHLOROPLATINIC ACID, SOLID
Proper Shipping Name (IATA) : CHLOROPLATINIC ACID, SOLID
Proper Shipping Name (ADN) : CHLOROPLATINIC ACID, SOLID
Proper Shipping Name (RID) : CHLOROPLATINIC ACID, SOLID
Transport document description (ADR) : UN 2507, CHLOROPLATINIC ACID, SOLID, 8, III
Transport document description (IMDG) : UN 2507, CHLOROPLATINIC ACID, SOLID, 8, III
Transport document description (IATA) : UN 2507, CHLOROPLATINIC ACID, SOLID, 8, III
Transport document description (ADN) : UN 2507, CHLOROPLATINIC ACID, SOLID, 8, III
Transport document description (RID) : UN 2507, CHLOROPLATINIC ACID, SOLID, 8, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 8
Danger labels : 8
IMDG
Transport hazard class(es) : 8
Danger labels : 8
IATA
Transport hazard class(es) : 8
Danger labels : 8
ADN
Transport hazard class(es) : 8
Danger labels : 8
RID
Transport hazard class(es) : 8
Danger labels : 8
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C2
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T1
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAV
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Bulk
(ADR)
: VC1, VC2, AP7
Hazard identification number (Kemler No.) : 80
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2X
- Transport by sea
Limited quantities (IMDG) : 5 kg
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P002, LP02
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : A
MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y845
PCA limited quantity max net quantity
(IATA)
: 5kg
PCA packing instructions (IATA) : 860
PCA max net quantity (IATA) : 25kg
CAO packing instructions (IATA) : 864
CAO max net quantity (IATA) : 100kg
ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C2
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C2
Limited quantities (RID) : 5kg
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T1
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAV
Transport category (RID) : 3
Special provisions for carriage – Bulk
(RID)
: VC1, VC2, AP7
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
PLATINUM CHLORIDE Extra Pure is not on the REACH Candidate List
PLATINUM CHLORIDE Extra Pure is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Resp. Sens. 1 Sensitisation — Respiratory, category 1
Skin Corr. 1B Skin corrosion/irritation, Category 1B
Skin Sens. 1 Sensitisation — Skin, category 1
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
R25 Toxic if swallowed
R34 Causes burns
R42 May cause sensitization by inhalation
R43 May cause sensitisation by skin contact
C Corrosive
T Toxic