SELENIUM DIOXIDE (SUBLIMED) Extra Pure |
| Synonyms : Selenium oxide |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
|||
|---|---|---|---|
1.1 Product identifier |
|||
| Chemical Name : | SELENIUM DIOXIDE (sublimed) | ||
| Catalogue No. : | AL3967 | Product form : | Substance |
| CAS Number : | 7446-08-4 | EC Number : | |
| Grade : | EC Index Number : | ||
| Chemical Formula : | HSN Code : | 28112990 | |
| Synonyms : | Selenium oxide | ||
| Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
|||
| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
|||
| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
||
1.4 Emergency Contact Details |
|||
| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
||
SECTION 2: Hazards identification |
|
|---|---|
2.1 Classification of the substance or mixture |
|
| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
|
Acute toxicity (oral), Category 3 H301 Acute toxicity (inhal.), Category 3 H331 Specific target organ toxicity Repeated exposure, Category 2 H373 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of classification categories and H statements : see section 16 |
|
| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| T; R23/25 N; R50/53 R33 Full text of R-phrases: see section 16 |
|
| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
|
| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS06
 GHS08
 GHS09
|
| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H301+H331 - Toxic if swallowed or if inhaled H373 - May cause damage to organs through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects |
| Precautionary statements (CLP) : | P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P311 - Call a POISON CENTER or doctor/physician |
2.3 Other hazards |
|
| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
|||
|---|---|---|---|
3.1. Substance |
|||
| Name : | SELENIUM DIOXIDE (SUBLIMED) Extra Pure | ||
| CAS No. : | 7446-08-4 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
|||
| Not applicable | |||
SECTION 4: First aid measures |
|
|---|---|
4.1 Description of first aid measures |
|
| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. |
| First-aid measures after skin contact : | Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. |
| First-aid measures after eye contact : | Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Obtain emergency medical attention. Immediately call a POISON CENTER or doctor/physician. Specific treatment (see ... on this label). |
4.2 Most important symptoms and effects, both acute and delayed |
|
| Symptoms relating to use : | Symptoms/injuries : May cause damage to organs. Symptoms/injuries after inhalation : Toxic if inhaled. Symptoms/injuries after ingestion : Toxic if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
|
| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
|
|---|---|
5.1 Extinguishing media |
|
| Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
|
| Special procedures : | No additional information available |
5.3 Advice for firefighters |
|
| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
|
|---|---|
6.1 Personal precautions, protective equipment and emergency procedures |
|
6.1.1. For non-emergency personnel |
|
| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
|
| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Stop release. |
6.2 Environmental precautions |
|
| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
|
| Methods for cleaning up : | Clear up rapidly by scoop or vacuum. |
6.4 Reference to other sections |
|
| Reference : | No additional information available |
SECTION 7: Handling and storage |
|
|---|---|
7.1 Precautions for safe handling |
|
| Precautions for safe handling : | Do not get in eyes, on skin, or on clothing. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. |
7.2 Conditions for safe storage, including any incompatibilities |
|
| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
|
| No additional information available | |
SECTION 8: Exposure controls/personal protection |
|
|---|---|
8.1 Control parameters |
|
| No additional information available | |
8.2 Exposure controls |
|
| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
|
|---|---|
9.1 Information on basic physical and chemical properties |
|
| Physical state : | Solid Colour |
| Colour : | Almost White. |
| Odour : | vapor has a pungent sour smell. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 315 °C |
| Freezing point : | No data available |
| Boiling point : | No data available |
| Flash point : | No data available |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | No data available |
| Density : | 3.95 g/cm3 |
| Solubility : | Water: 28 % in water @ 200C |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
|
| No additional information available | |
SECTION 10: Stability and reactivity |
|
|---|---|
10.1 Reactivity |
|
| No additional information available | |
10.2 Chemical stability |
|
| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
|
| No additional information available | |
10.4 Conditions to avoid |
|
| Direct sunlight. Air contact. Moisture. | |
10.5 Incompatible materials |
|
| No additional information available | |
10.6 Hazardous decomposition products |
|
| No additional information available |
SECTION 11: Toxicological information |
|
|---|---|
11.1 Information on toxicological effects |
|
| Acute toxicity : | Oral: Toxic if swallowed. Inhalation: Toxic if inhaled. |
| Skin corrosion/irritation : | Not classified |
| Serious eye damage/irritation : | Not classified |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| Reproductive toxicity : | Not classified |
| Specific target organ toxicity (single exposure) : | Not classified |
| Specific target organ toxicity (repeated exposure) : | May cause damage to organs through prolonged or repeated exposure. Additional information |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Toxic if swallowed. |
SECTION 12: Ecological information |
|
|---|---|
12.1 Toxicity |
|
| Toxicity information : | Ecology - water : Very toxic to aquatic life with long lasting effects. |
12.2 Persistence - degradability |
|
| Persistence - degradability : | SELENIUM DIOXIDE (SUBLIMED) Extra Pure (7446-08-4) Persistence and degradability May cause long-term adverse effects in the environment. |
12.3 Bioaccumulative potential |
|
| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
|
| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
|
| No additional information available | |
12.6 Other adverse effects |
|
| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
|
|---|---|
13.1 Waste treatment methods |
|
| Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
| Ecology - waste materials : | Hazardous waste due to toxicity. |
SECTION 14: Transport information |
|
|---|---|
| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
|
| UN-No. (ADR) : | 3283 |
| UN-No. (IMDG) : | 3283 |
| UN-No. (IATA) : | 3283 |
| UN-No. (ADN) : | 3283 |
| UN-No. (RID) : | 3283 |
14.2. UN proper shipping name |
|
| Proper Shipping Name (ADR) : | SELENIUM COMPOUND, SOLID, N.O.S. |
| Proper Shipping Name (IMDG) : | SELENIUM COMPOUND, SOLID, N.O.S. |
| Proper Shipping Name (IATA) : | SELENIUM COMPOUND, SOLID, N.O.S. |
| Proper Shipping Name (ADN) : | SELENIUM COMPOUND, SOLID, N.O.S. |
| Proper Shipping Name (RID) : | SELENIUM COMPOUND, SOLID, N.O.S. |
| Transport document description (ADR) : | UN 3283, SELENIUM COMPOUND, SOLID, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 3283, SELENIUM COMPOUND, SOLID, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 3283, SELENIUM COMPOUND, SOLID, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 3283, SELENIUM COMPOUND, SOLID, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 3283, SELENIUM COMPOUND, SOLID, N.O.S., 6.1, III ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
|
| ADR | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1 
|
| IMDG | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
|
| IATA | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
|
| ADN | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
|
| RID | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
|
14.4. Packing group |
|
| Packing group (ADR) : | III |
| Packing group (IMDG) : | III |
| Packing group (IATA) : | III |
| Packing group (ADN) : | III |
| Packing group (RID) : | III |
14.5. Environmental hazards |
|
| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
|
| - Overland transport | |
|
Classification code (ADR) : T5 Special provision (ADR) : 274, 563 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P002, IBC08, LP02, R001 Special packing provisions (ADR) : B3 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T1 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAH, L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Bulk (ADR) : VC1, VC2, AP7 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X |
|
| - Transport by sea | |
|
Special provision (IMDG) : 223, 274 Limited quantities (IMDG) : 5 kg Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P002, LP02 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 Tank instructions (IMDG) : T1 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A MFAG-No : 151 |
|
| - Air transport | |
|
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y645 PCA limited quantity max net quantity (IATA) : 10kg PCA packing instructions (IATA) : 670 PCA max net quantity (IATA) : 100kg CAO packing instructions (IATA) : 677 CAO max net quantity (IATA) : 200kg Special provision (IATA) : A3, A5 ERG code (IATA) : 6L |
|
| - Inland waterway transport | |
|
Classification code (ADN) : T5 Special provisions (ADN) : 274, 563, 802 Limited quantities (ADN) : 5 kg Excepted quantities (ADN) : E1 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 |
|
| - Rail transport | |
|
Classification code (RID) : T5 Special provision (RID) : 274, 563 Limited quantities (RID) : 5kg Excepted quantities (RID) : E1 Packing instructions (RID) : P002, IBC08, LP02, R001 Special packing provisions (RID) : B3 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T1 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAH, L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Bulk (RID) : VC1, VC2, AP7 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 60 |
|
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
|
| Not applicable | |
SECTION 15: Regulatory information |
|---|
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions SELENIUM DIOXIDE (SUBLIMED) Extra Pure is not on the REACH Candidate List SELENIUM DIOXIDE (SUBLIMED) Extra Pure is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 2; WGK No 419) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
||||||||||||||||