SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	BENZYL BENZOATE
Catalogue No. :	AL0651	Product form :	Substance
CAS Number :	120-51-4	EC Number :	204-402-9
Grade :		EC Index Number :	607-085-00-9
Chemical Formula :		HSN Code :	29163120
Synonyms :	Benzoic acid benzyl ester
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Serious eye damage/eye irritation, Category 2 H319 Skin corrosion/irritation, Category 2 H315 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xi; R36 Xi; R37 Xi; R38 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS07
Signal word (CLP) :	Warning
Hazard statements (CLP) :	H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation
Precautionary statements (CLP) :	P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		BENZYL BROMIDE FOR SYNTHESIS
CAS No. :		120-51-4
EC Index No. :		607-085-00-9
EC No. :		204-402-9
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Specific measures (see ... on this label). Wash contaminated clothing before reuse.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries after inhalation : Fatal if inhaled. Symptoms/injuries after skin contact : Toxic in contact with skin. Symptoms/injuries after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	No additional information available

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a wellventilated area.
Hygiene measures :	Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear appropriate mask

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Colorless.
Odour :	pleasant.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-4 °C
Freezing point :	No data available
Boiling point :	198
Flash point :	86 °C
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	5.98
Relative vapour density at 20°C :	No data available
Density :	1.438 g/cm3
Solubility :	No data available
Log Pow :	-2.92
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye irritation.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	May cause respiratory irritation.
Specific target organ toxicity (repeated exposure) :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	BENZYL BROMIDE FOR SYNTHESIS (100-39-0) Log Pow -2.92
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info :	No additional information available

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1737
UN-No. (IMDG) :	1737
UN-No. (IATA) :	1737
UN-No. (ADN) :	1737
UN-No. (RID) :	1737
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	BENZYL BROMIDE
Proper Shipping Name (IMDG) :	BENZYL BROMIDE
Proper Shipping Name (IATA) :	BENZYL BROMIDE
Proper Shipping Name (ADN) :	BENZYL BROMIDE
Proper Shipping Name (RID) :	BENZYL BROMIDE
Transport document description (ADR) :	UN 1737, BENZYL BROMIDE, 6.1 (8), II
Transport document description (IMDG) :	UN 1737, BENZYL BROMIDE, 6.1 (8), II
Transport document description (IATA) :	UN 1737, BENZYL BROMIDE, 6.1 (8), II
Transport document description (ADN) :	UN 1737, BENZYL BROMIDE, 6.1 (8), II
Transport document description (RID) :	UN 1737, BENZYL BROMIDE, 6.1 (8), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
IMDG
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
IATA
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
ADN
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
RID
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TC1 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E4 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T8 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S19 Hazard identification number (Kemler No.) : 68 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 2X
- Transport by sea
Limited quantities (IMDG) : 0 Excepted quantities (IMDG) : E4 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 IBC special provisions (IMDG) : B20 Tank instructions (IMDG) : T8 Tank special provisions (IMDG) : TP2, TP13 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : D Stowage and handling (IMDG) : SW2, H1 MFAG-No : 156
- Air transport
PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : 653 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 660 CAO max net quantity (IATA) : 30L ERG code (IATA) : 6C
- Inland waterway transport
Classification code (ADN) : TC1 Special provisions (ADN) : 802 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E4 Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : TC1 Limited quantities (RID) : 0 Excepted quantities (RID) : E4 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T8 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE5 Hazard identification number (RID) : 68
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions BENZYL BROMIDE FOR SYNTHESIS is not on the REACH Candidate List BENZYL BROMIDE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 3; WGK No 5565) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation R36 Irritating to eyes R37 Irritating to respiratory system R38 Irritating to skin Xi Irritant