SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	CARBON DI SULPHIDE AR
Catalogue No. :	AL1139	Product form :	Substance
CAS Number :	75-15-0	EC Number :	200-843-6
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	28131000
Synonyms :	Carbon bisulfide; Carbon silfide; Dithiocarbonic anhydride
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 2 H225 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Reproductive toxicity, Category 2 H361fd Specific target organ toxicity Repeated exposure, Category 1 H372 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Repr.Cat.3; R62 Repr.Cat.3; R63 F; R11 T; R23 Xi; R36 Xi; R38 R48 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS07 GHS08
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H225 - Highly flammable liquid and vapour H315 - Causes skin irritation H319 - Causes serious eye irritation H361fd - Suspected of damaging fertility. Suspected of damaging the unborn child H372 - Causes damage to organs through prolonged or repeated exposure
Precautionary statements (CLP) :	P201 - Obtain special instructions before use P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P314 - Get medical advice/attention if you feel unwell
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		CARBON DISULPHIDE AR
CAS No. :		75-15-0
EC No. :		200-843-6
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label).
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : Causes damage to organs through prolonged or repeated exposure. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	Fire hazard : Highly flammable liquid and vapour. Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	No additional information available

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	No naked lights. No smoking. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures :	Wash ... thoroughly after handling. Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/… equipment.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	76.13 g/mol
Colour :	Clear Colorless.
Odour :	stench.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	22.6
Melting point :	-100 °C
Freezing point :	No data available
Boiling point :	46 °C
Flash point :	-30 °C
Auto-ignition temperature :	100 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Extremely flammable Highly flammable liquid and v
Vapour pressure :	300 mm Hg at 20°C (68F)
Relative vapour density at 20°C :	2.6
Relative density :	No data available Density : 1.26 g/cm3
Density :	1.26 g/cm3 Relative gas density : 2.63
Relative gas density :	2.63
Solubility :	Water: 0.2 g/100ml
Log Pow :	2.16
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.013 - 0.5 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Direct sunlight.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye irritation.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	Suspected of damaging fertility. Suspected of damaging the unborn child.
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Causes damage to organs through prolonged or repeated exposure.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	CARBON DISULPHIDE AR (75-15-0) Log Pow 2.16
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1131
UN-No. (IMDG) :	1131
UN-No. (IATA) :	1131
UN-No. (ADN) :	1131
UN-No. (RID) :	1131
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	CARBON DISULPHIDE
Proper Shipping Name (IMDG) :	CARBON DISULPHIDE
Proper Shipping Name (IATA) :	CARBON DISULPHIDE
Proper Shipping Name (ADN) :	CARBON DISULPHIDE
Proper Shipping Name (RID) :	CARBON DISULPHIDE
Transport document description (ADR) :	UN 1131, CARBON DISULPHIDE, 3 (6.1), I
Transport document description (IMDG) :	UN 1131, CARBON DISULPHIDE, 3 (6.1), I
Transport document description (IATA) :	UN 1131, CARBON DISULPHIDE, 3 (6.1), I
Transport document description (ADN) :	UN 1131, CARBON DISULPHIDE, 3 (6.1), I
Transport document description (RID) :	UN 1131, CARBON DISULPHIDE, 3 (6.1), I
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
IMDG
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
IATA
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
ADN
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
RID
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
14.4. Packing group
Packing group (ADR) :	I
Packing group (IMDG) :	I
Packing group (IATA) :	I
Packing group (ADN) :	I
Packing group (RID) :	I
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : FT1 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E0 Packing instructions (ADR) : P001 Special packing provisions (ADR) : PP31 Mixed packing provisions (ADR) : MP7, MP17 Portable tank and bulk container instructions (ADR) : T14 Portable tank and bulk container special provisions (ADR) : TP2, TP7 Tank code (ADR) : L10CH Tank special provisions (ADR) : TU14, TU15, TE21 Vehicle for tank carriage : FL Transport category (ADR) : 1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2, S22 Hazard identification number (Kemler No.) : 336 Orange plates : Tunnel restriction code (ADR) : C/E EAC code : 2WE APP code : A(fl)
- Transport by sea
Limited quantities (IMDG) : 0 Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P001 Packing provisions (IMDG) : PP31 Tank instructions (IMDG) : T14 Tank special provisions (IMDG) : TP2, TP7, TP13 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : D Stowage and handling (IMDG) : SW2 Flash point (IMDG) : -30°C c.c. MFAG-No : 131
- Air transport
PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : Forbidden CAO max net quantity (IATA) : Forbidden ERG code (IATA) : 3HP
- Inland waterway transport
Classification code (ADN) : FT1 Special provisions (ADN) : 802 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E0 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, TOX, A Ventilation (ADN) : VE01, VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : FT1 Limited quantities (RID) : 0 Excepted quantities (RID) : E0 Packing instructions (RID) : P001 Special packing provisions (RID) : PP31 Mixed packing provisions (RID) : MP7, MP17 Portable tank and bulk container instructions (RID) : T14 Portable tank and bulk container special provisions (RID) : TP2, TP7 Tank codes for RID tanks (RID) : L10CH Special provisions for RID tanks (RID) : TU2, TU14, TU15, TU38, TE21, TE22 Transport category (RID) : 1 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28 Hazard identification number (RID) : 336
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions CARBON DISULPHIDE AR is not on the REACH Candidate List CARBON DISULPHIDE AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 2; WGK No 183) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/brea
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Repr. 2 Reproductive toxicity, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 1 Specific target organ toxicity — Repeated exposure, Category 1 H225 Highly flammable liquid and vapour H315 Causes skin irritation H319 Causes serious eye irritation H361fd Suspected of damaging fertility. Suspected of damaging the unborn child H372 Causes damage to organs through prolonged or repeated exposure R11 Highly flammable R23 Toxic by inhalation R36 Irritating to eyes R38 Irritating to skin R48 Danger of serious damage to health by prolonged exposure R62 Possible risk of impaired fertility R63 Possible risk of harm to the unborn child F Highly flammable T Toxic Xi Irritant