N,N,DIMETHYLACETAMIDE AR

N,N,DIMETHYLACETAMIDE AR

Synonyms : Acid dimethylamide

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : N,N-DIMETHYL ACETAMIDE AR
Catalogue No. : AL1807 Product form : Substance
CAS Number : 127-19-5 EC Number : 204-826-4
Grade : EC Index Number : 616-011-00-4
Chemical Formula : C4H9NO HSN Code : 29241900
Synonyms : Acid dimethylamide
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Reproductive toxicity,
Category 1B
H360D
Acute toxicity (dermal),
Category 4
H312
Acute toxicity (inhal.),
Category 4
H332
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Repr.Cat.2; R61
Xn; R20/21
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS08GHS08 GHS07GHS07
Signal word (CLP) : Danger
Hazard statements (CLP) : H312+H332 - Harmful in contact with skin or if inhaled
H360D - May damage the unborn child
Precautionary statements (CLP) : P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray
P271 - Use only outdoors or in a well-ventilated area
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P302+P352 - IF ON SKIN: Wash with plenty of water/¦
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for
breathing
P308+P313 - IF exposed or concerned: Get medical advice/attention
P312 - Call a POISON CENTER/doctor/¦ if you feel unwell
P321 - Specific treatment (see ... on this label)
P362+P364 - Take off contaminated clothing and wash it before reuse
P405 - Store locked up
P501 - Dispose of contents/container to ...
2.3 Other hazards
Other hazards : This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : N,N-DIMETHYL ACETAMIDE AR
CAS No. : 127-19-5
EC Index No. : 616-011-00-4
EC No. : 204-826-4
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Immediately call a POISON CENTER or doctor/physician. Specific measures (see ...
on this label). Wash with plenty of soap and water. Wash contaminated clothing
before reuse.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : May damage the unborn child.
Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing
significant health hazard. Harmful in contact with skin.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills
with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Clear Colorless.
Odour : faint ammonia odor.
Odour threshold : No data available
pH value : 4 at 200 g/l at 20 °C
Relative evaporation rate (butylacetate=1) : < 0.17
Melting point : -20 °C
Freezing point : No data available
Boiling point : 164.5 - 166
Flash point : 70 °C
Auto-ignition temperature : 4900 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 1.5 mm Hg at 20 °C
Relative vapour density at 20°C : 3.01
Density : 0.94 g/cm3
Solubility : Water: Completely miscible
Log Pow : 0.77
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.018 - 0.115 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Dermal: Harmful in contact with skin. Inhalation: Harmful if inhaled.
Skin corrosion/irritation : Not classified
pH: 4 at 200 g/l at 20 °C
Serious eye damage/irritation : Not classified
pH: 4 at 200 g/l at 20 °C
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : May damage the unborn child.
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : N,N-DIMETHYL ACETAMIDE AR (127-19-5) Log Pow 0.77
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
N,N-DIMETHYL ACETAMIDE AR (127-19-5)
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : Not applicable
UN-No. (IMDG) : Not applicable
UN-No. (IATA) : Not applicable
UN-No. (ADN) : Not applicable
UN-No. (RID) : Not applicable
14.2. UN proper shipping name
Proper Shipping Name (ADR) : Not applicable
Proper Shipping Name (IMDG) : Not applicable
Proper Shipping Name (IATA) : Not applicable
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable
Transport document description (ADR) : Not applicable
Transport document description (IMDG) : Not applicable
Transport document description (IATA) : Not applicable
Transport document description (ADN) : Not applicable
Transport document description (RID) : Not applicable
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : Not applicable
IMDG
Transport hazard class(es) : Not applicable
IATA
Transport hazard class(es) : Not applicable
ADN
Transport hazard class(es) : Not applicable
RID
Transport hazard class(es) : Not applicable
14.4. Packing group
Packing group (ADR) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
No data available
- Transport by sea
No data available
- Air transport
No data available
- Inland waterway transport
No data available
- Rail transport
No data available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
N,N-dimethylacetamide is on the REACH Candidate List
N,N-DIMETHYL ACETAMIDE AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (KBwS-Beschluss; WGK No 1289)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class III-1
Store unit : 50 liter
Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management
guidelines for the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/b
Denmark
Class for fire hazard : Class III-1
Store unit : 50 liter
Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management
guidelines for the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Repr. 1B Reproductive toxicity, Category 1B
H312 Harmful in contact with skin
H332 Harmful if inhaled
H360D May damage the unborn child
R20/21 Harmful by inhalation and in contact with skin
R61 May cause harm to the unborn child
Xn Harmful