SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	1,4-DIOXAN AR
Catalogue No. :	AL1911	Product form :	Substance
CAS Number :	123-91-1	EC Number :	204-661-8
Grade :		EC Index Number :	603-024-00-5
Chemical Formula :	C4H8O2	HSN Code :	29329900
Synonyms :	Dioxane / Diethylene oxide
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 2 H225 Serious eye damage/eye irritation, Category 2 H319 Carcinogenicity, Category 2 H351 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.3; R40 F; R11 Xi; R36/37 R19 R66 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS07 GHS08
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H225 - Highly flammable liquid and vapour. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer.
Precautionary statements (CLP) :	P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		1,4,-DIOXANE AR
CAS No. :		123-91-1
EC Index No. :		603-024-00-5
EC No. :		204-661-8
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact :	Rinse skin with water/shower. Take off immediately all contaminated clothing. Repeated exposure may cause skin dryness or cracking.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after inhalation : May cause respiratory irritation. Symptoms/effects after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Highly flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture. Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. May form explosive peroxides.
5.3 Advice for firefighters
Protection during firefighting :	No additional information available

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable. Hazardous waste due to potential risk of explosion.
Precautions for safe handling :	No open flames. No smoking. Use only non-sparking tools. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-
Hygiene measures :	Wash hands, forearms and face thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment.
Storage conditions :	Keep in fireproof place. Keep container tightly closed. Incompatible products : Oxidizing agent.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear fire/flame resistant/retardant clothing.
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	faint ether-like odor.
Odour threshold :	No data available
pH value :	6 - 8
Relative evaporation rate (butylacetate=1) :	2.7
Melting point :	10 - 12 °C
Freezing point :	No data available
Boiling point :	100 - 102 °C
Flash point :	12 °C
Auto-ignition temperature :	180 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable Highly flammable liquid and vapour.
Vapour pressure :	36 hPa at 20 °C
Relative vapour density at 20°C :	3.03
Relative density :	No data available Density : 1.03 g/cm3
Density :	1.03 g/cm3 Relative gas density : 3.04
Relative gas density :	3.04
Solubility :	No data available
Log Pow :	-0.27
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	May form explosive peroxides.
Oxidising properties :	No data available
Explosive limits :	0.02 - 0.22 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
Reacts vigorously with strong oxidizers and acids.
10.4 Conditions to avoid
Open flame. Direct sunlight. Heat. Sparks. Overheating.
10.5 Incompatible materials
Oxidizing agent.
10.6 Hazardous decomposition products
May release flammable gases. May form explosive peroxides.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Not classified pH: 6 - 8
Additional information :	Repeated exposure may cause skin dryness or cracking.
Serious eye damage/irritation :	Causes serious eye irritation. pH: 6 - 8
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Suspected of causing cancer.
STOT-single exposure :	May cause respiratory irritation.
STOT-repeated exposure :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	1,4,-DIOXANE AR (123-91-1) Log Pow -0.27
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Handle empty containers with care because residual vapours are flammable. Hazardous waste due to potential risk of explosion.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1165
UN-No. (IMDG) :	1165
UN-No. (IATA) :	1165
UN-No. (ADN) :	1165
UN-No. (RID) :	1165
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	DIOXANE
Proper Shipping Name (IMDG) :	DIOXANE
Proper Shipping Name (IATA) :	DIOXANE
Proper Shipping Name (ADN) :	DIOXANE
Proper Shipping Name (RID) :	DIOXANE
Transport document description (ADR) :	UN 1165, DIOXANE, 3, II
Transport document description (IMDG) :	UN 1165, DIOXANE, 3, II
Transport document description (IATA) :	UN 1165, DIOXANE, 3, II
Transport document description (ADN) :	UN 1165, DIOXANE, 3, II
Transport document description (RID) :	UN 1165, DIOXANE, 3, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	3
Danger labels :	3
IMDG
Transport hazard class(es) :	3
Danger labels :	3
IATA
Transport hazard class(es) :	3
Danger labels :	3
ADN
Transport hazard class(es) :	3
Danger labels :	3
RID
Transport hazard class(es) :	3
Danger labels :	3
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F1 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : LGBF Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Operation (ADR) : S2, S20 Hazard identification number (Kemler No.) : 33 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •2YE
- Transport by sea
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : B Flash point (IMDG) : 12°C c.c. MFAG-No : 127
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y341 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 353 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) : 60L ERG code (IATA) : 3L
- Inland waterway transport
Classification code (ADN) : F1 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : F1 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1 Tank codes for RID tanks (RID) : LGBF Transport category (RID) : 2 Colis express (express parcels) (RID) : CE7 Hazard identification number (RID) : 33
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions 1,4,-DIOXANE AR is not on the REACH Candidate List 1,4,-DIOXANE AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to AwSV; ID No. 86) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : 1,4,-DIOXANE AR is listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Class for fire hazard : Class I-1 Store unit : 1 liter Classification remarks : F ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Carc. 2 Carcinogenicity, Category 2 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H351 Suspected of causing cancer. R11 Highly flammable R19 May form explosive peroxides R36/37 Irritating to eyes and respiratory system R40 Limited evidence of a carcinogenic effect R66 Repeated exposure may cause skin dryness or cracking F Highly flammable Xi Irritant