2-ETHOXYETHANOL AR

2-ETHOXYETHANOL AR

Synonyms : Cellosolve; Ethyl glycol; Ethylene glycol monoethyl ether

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : CELLOSOLVE AR (2-ethoxy ethanol) (ethyl cellosolve)
Catalogue No. : AL1183 Product form : Substance
CAS Number : 110-80-5 EC Number : 203-804-1
Grade : EC Index Number : 603-012-00-X
Chemical Formula : HSN Code : 29094400
Synonyms : Cellosolve; Ethyl glycol; Ethylene glycol monoethyl ether
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids,
Category 3
H226
Acute toxicity (oral),
Category 4
H302
Acute toxicity (dermal),
Category 4
H312
Acute toxicity (inhal.),
Category 4
H332
Reproductive toxicity,
Category 1A
H360FD
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Repr.Cat.2; R60
Repr.Cat.2; R61
Xn; R20/21/22
R10
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02 GHS07GHS07 GHS08GHS08
Signal word (CLP) : Danger
Hazard statements (CLP) : H226 - Flammable liquid and vapour.
H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled
H360FD - May damage fertility. May damage the unborn child.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P280 - Wear protective gloves, protective clothing, eye protection, face protection.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
2.3 Other hazards
Other hazards : This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : 2-ETHOXYETHANOL AR
CAS No. : 110-80-5
EC Index No. : 603-012-00-X
EC No. : 203-804-1
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep
at rest in a position comfortable for breathing.
First-aid measures after skin contact : Immediately call a POISON CENTER/doctor. Wash with plenty of water/…. Wash
contaminated clothing before reuse.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER/doctor if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : May damage the unborn child. May damage fertility.
Symptoms/effects after skin contact : Repeated exposure to this material can result in absorption through skin causing
significant health hazard. Harmful in contact with skin.
Symptoms/effects after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information : No additional information available

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open
flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Keep away from sources of ignition - No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Avoid contact with skin and eyes. Do not handle until all safety precautions have been read and understood.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Ground/bond container and receiving equipment.
Storage conditions : Keep container tightly closed. Keep in fireproof place.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid
Molecular mass : 90.12 g/mol
Colour : Clear Colorless.
Odour : mild pleasant odor.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : 0.32
Melting point : -90 °C
Freezing point : No data available
Boiling point : 135 °C
Flash point : 42 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable Flammable liquid and vapour.
Vapour pressure : 3.8 at 20°C
Relative vapour density at 20°C : 3.1
Density : 0.93 g/cm3
Solubility : Water: Complete
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.018 - 0.14 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed. Dermal: Harmful in contact with skin. Inhalation: Harmful
if inhaled.
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed. Harmful in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
2-ETHOXYETHANOL AR (110-80-5)
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1171
UN-No. (IMDG) : 1171
UN-No. (IATA) : 1171
UN-No. (ADN) : 1171
UN-No. (RID) : 1171
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ETHYLENE GLYCOL MONOETHYL ETHER
Proper Shipping Name (IMDG) : ETHYLENE GLYCOL MONOETHYL ETHER
Proper Shipping Name (IATA) : ETHYLENE GLYCOL MONOETHYL ETHER
Proper Shipping Name (ADN) : ETHYLENE GLYCOL MONOETHYL ETHER
Proper Shipping Name (RID) : ETHYLENE GLYCOL MONOETHYL ETHER
Transport document description (ADR) : UN 1171, ETHYLENE GLYCOL MONOETHYL ETHER, 3, III
Transport document description (IMDG) : UN 1171, ETHYLENE GLYCOL MONOETHYL ETHER, 3, III
Transport document description (IATA) : UN 1171, ETHYLENE GLYCOL MONOETHYL ETHER, 3, III
Transport document description (ADN) : UN 1171, ETHYLENE GLYCOL MONOETHYL ETHER, 3, III
Transport document description (RID) : UN 1171, ETHYLENE GLYCOL MONOETHYL ETHER, 3, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 3
Danger labels : 3
IMDG
Transport hazard class(es) : 3
Danger labels : 3
IATA
Transport hazard class(es) : 3
Danger labels : 3
ADN
Transport hazard class(es) : 3
Danger labels : 3
RID
Transport hazard class(es) : 3
Danger labels : 3
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F1
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container
instructions (ADR)
: T2
Portable tank and bulk container special
provisions (ADR)
: TP1
Tank code (ADR) : LGBF
Vehicle for tank carriage : FL
Transport category (ADR) : 3
Special provisions for carriage - Packages
(ADR)
: V12
Special provisions for carriage - Operation
(ADR)
: S2
Hazard identification number (Kemler No.) : 30
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : •2Y
- Transport by sea
Limited quantities (IMDG) : 5 L
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P001, LP01
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T2
Tank special provisions (IMDG) : TP1
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-D
Stowage category (IMDG) : A
Flash point (IMDG) : 40°C c.c.
Properties and observations (IMDG) : Colourless liquid. Flashpoint: 40°C c.c. Explosive limits: 1.7% to 15.6% Miscible
with water.
MFAG-No : 127
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y344
PCA limited quantity max net quantity
(IATA)
: 10L
PCA packing instructions (IATA) : 355
PCA max net quantity (IATA) : 60L
CAO packing instructions (IATA) : 366
CAO max net quantity (IATA) : 220L
ERG code (IATA) : 3L
- Inland waterway transport
Classification code (ADN) : F1
Limited quantities (ADN) : 5 L
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : F1
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Mixed packing provisions (RID) : MP19
Portable tank and bulk container
instructions (RID)
: T2
Portable tank and bulk container special
provisions (RID)
: TP1
Tank codes for RID tanks (RID) : LGBF
Transport category (RID) : 3
Special provisions for carriage – Packages
(RID)
: W12
Colis express (express parcels) (RID) : CE4
Hazard identification number (RID) : 30
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
2-Ethoxyethanol is on the REACH Candidate List
2-ETHOXYETHANOL AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to
AwSV; ID No. 5058)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: 2-ETHOXYETHANOL AR is listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: 2-ETHOXYETHANOL AR is listed
Denmark
Class for fire hazard : Class II-1
Store unit : 5 liter
Classification remarks : R10 ; Emergency management guidelines for
the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Flam. Liq. 3 Flammable liquids, Category 3
Repr. 1A Reproductive toxicity, Category 1A
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H332 Harmful if inhaled.
H360FD May damage fertility. May damage the unborn child.
R10 Flammable
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R60 May impair fertility
R61 May cause harm to the unborn child
Xn Harmful