ETHYLENE GLYCOL DIMETHYL ETHER Extra Pure |
| Synonyms : 1,2 Dimethoxyethane, Monoglyme |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | 1,2-DIMETHOXYETHANE (ethelene glycol dimethyl ether) | ||
| Catalogue No. : | AL1801 | Product form : | Substance |
| CAS Number : | 110-71-4 | EC Number : | 203-794-9 |
| Grade : | EC Index Number : | 603-031-00-3 | |
| Chemical Formula : | C4H10O2 | HSN Code : | 29094900 |
| Synonyms : | Monoglyme / Dimethylglycol / mono-Glyme | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Industrial For professional use only | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Flammable liquids, Category 2 H225 Acute toxicity (inhal.), Category 4 H332 Reproductive toxicity, Category 1A H360FD Full text of H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Repr.Cat.2; R60 Repr.Cat.2; R61 F; R11 Xn; R20 R19 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS02
 GHS07
 GHS08
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H225 - Highly flammable liquid and vapour. H332 - Harmful if inhaled. H360FD - May damage fertility. May damage the unborn child. |
| Precautionary statements (CLP) : | P201 - Obtain special instructions before use. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P308+P313 - IF exposed or concerned: Get medical advice/attention. |
2.3 Other hazards |
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| Other hazards : | This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | ETHYLENE GLYCOL DIMETHYL ETHER Extra Pure | ||
| CAS No. : | 110-71-4 | ||
| EC Index No. : | 603-031-00-3 | ||
| EC No. : | 203-794-9 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. Get medical advice/attention. |
| First-aid measures after skin contact : | Wash with plenty of water/…. Get medical advice/attention. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Do not induce vomiting. Get medical advice/attention. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects : May damage the unborn child. May damage fertility. Symptoms/effects after skin contact : Causes skin irritation. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Water spray. Foam. Dry powder. Carbon dioxide. |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Fire hazard : | Highly flammable liquid and vapour. |
| Explosion hazard : | May form flammable/explosive vapour-air mixture. Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. May form explosive peroxides. |
5.3 Advice for firefighters |
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| Protection during firefighting : | No additional information available |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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| General measures : | Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. |
6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Additional hazards when processed : | Handle empty containers with care because residual vapours are flammable. Hazardous waste due to potential risk of explosion. |
| Precautions for safe handling : | No open flames. No smoking. Use only non-sparking tools. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from sources of ignition - No smoking. |
| Hygiene measures : | Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Technical measures : | Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. |
| Storage conditions : | Keep in fireproof place. Keep container tightly closed. Incompatible products : Oxidizing agent. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid |
| Molecular mass : | 90.12 g/mol |
| Colour : | Clear Colorless. |
| Odour : | sharp, ethereal odor. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | 5 |
| Melting point : | -58 °C |
| Freezing point : | No data available |
| Boiling point : | 82 - 83 |
| Flash point : | -2 °C |
| Auto-ignition temperature : | 202 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | Flammable Highly flammable liquid and vapour. |
| Vapour pressure : | 64 hPa (at 20°C) |
| Relative vapour density at 20°C : | 3.1 |
| Density : | 0.86 g/cm3 |
| Solubility : | Water: Miscible in water |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | 1.1 mPa·s 20 deg C |
| Explosive properties : | May form explosive peroxides. |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture. | |
10.3 Possibility of hazardous reactions |
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| Reacts vigorously with strong oxidizers and acids. | |
10.4 Conditions to avoid |
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| Open flame. Direct sunlight. Heat. Sparks. Overheating. | |
10.5 Incompatible materials |
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| Oxidizing agent. | |
10.6 Hazardous decomposition products |
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| May release flammable gases. May form explosive peroxides. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Inhalation: Harmful if inhaled. |
| Skin corrosion/irritation : | Not classified |
| Serious eye damage/irritation : | Not classified |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| STOT-single exposure : | Not classified |
| STOT-repeated exposure : | Not classified |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| ETHYLENE GLYCOL DIMETHYL ETHER Extra Pure (110-71-4) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII |
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12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
| Additional information : | Handle empty containers with care because residual vapours are flammable. Hazardous waste due to potential risk of explosion. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 2252 |
| UN-No. (IMDG) : | 2252 |
| UN-No. (IATA) : | 2252 |
| UN-No. (ADN) : | 2252 |
| UN-No. (RID) : | 2252 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | 1,2-DIMETHOXYETHANE |
| Proper Shipping Name (IMDG) : | 1,2-DIMETHOXYETHANE |
| Proper Shipping Name (IATA) : | 1,2-DIMETHOXYETHANE |
| Proper Shipping Name (ADN) : | 1,2-DIMETHOXYETHANE |
| Proper Shipping Name (RID) : | 1,2-DIMETHOXYETHANE |
| Transport document description (ADR) : | UN 2252, 1,2-DIMETHOXYETHANE, 3, II |
| Transport document description (IMDG) : | UN 2252, 1,2-DIMETHOXYETHANE, 3, II |
| Transport document description (IATA) : | UN 2252, 1,2-DIMETHOXYETHANE, 3, II |
| Transport document description (ADN) : | UN 2252, 1,2-DIMETHOXYETHANE, 3, II |
| Transport document description (RID) : | UN 2252, 1,2-DIMETHOXYETHANE, 3, II |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 3 |
| Danger labels : | 3 
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| IMDG | |
| Transport hazard class(es) : | 3 |
| Danger labels : | 3
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| IATA | |
| Transport hazard class(es) : | 3 |
| Danger labels : | 3
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| ADN | |
| Transport hazard class(es) : | 3 |
| Danger labels : | 3
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| RID | |
| Transport hazard class(es) : | 3 |
| Danger labels : | 3
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14.4. Packing group |
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| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : F1 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : LGBF Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Operation (ADR) : S2, S20 Hazard identification number (Kemler No.) : 33 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •2YE |
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| - Transport by sea | |
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Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : B Flash point (IMDG) : 1°C c.c. Properties and observations (IMDG) : Colourless liquid with an ethereal odour. Flashpoint: 1°C c.c. Miscible with water. MFAG-No : 127 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y341 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 353 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) : 60L ERG code (IATA) : 3L |
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| - Inland waterway transport | |
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Classification code (ADN) : F1 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1 |
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| - Rail transport | |
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Classification code (RID) : F1 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1 Tank codes for RID tanks (RID) : LGBF Transport category (RID) : 2 Colis express (express parcels) (RID) : CE7 Hazard identification number (RID) : 33 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions 1,2-dimethoxyethane; ethylene glycol dimethyl ether (EGDME) is on the REACH Candidate List ETHYLENE GLYCOL DIMETHYL ETHER Extra Pure is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. 5048) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : ETHYLENE GLYCOL DIMETHYL ETHER Extra Pure is listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : ETHYLENE GLYCOL DIMETHYL ETHER Extra Pure is listed |
| Denmark |
| Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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