SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	TRICHLOROETHYLENE
Catalogue No. :	AL4637	Product form :	Substance
CAS Number :	79-01-6	EC Number :	201-167-4
Grade :		EC Index Number :	602-027-00-9
Chemical Formula :	C2HCl3 / ClCH=CCl2	HSN Code :	29032200
Synonyms :	TCE / Trichloroethene
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Carcinogenicity, Category 1B H350 Germ cell mutagenicity, Category 2 H341 Serious eye damage/eye irritation, Category 2 H319 Skin corrosion/irritation, Category 2 H315 Specific target organ H336 toxicity Single exposure, Category 3, Narcosis Hazardous to the aquatic environment Chronic Hazard, Category 3 H412 Full text of hazard classes and H-statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
T; Carc.Cat.2; Muta.Cat.3; R36/38-45-52/53-67 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS07 GHS08
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H315 - Causes skin irritation. H319 - Causes serious eye irritation. H336 - May cause drowsiness or dizziness. H341 - Suspected of causing genetic defects. H350 - May cause cancer. H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) :	P201 - Obtain special instructions before use. P261 - Avoid breathing vapours, dust, fume, gas. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - IF exposed or concerned: Get medical advice/attention.
2.3 Other hazards
Other hazards :	This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		TRICHLOROETHYLENE Extra Pure
CAS No. :		79-01-6
EC Index No. :		602-027-00-9
EC No. :		201-167-4
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact :	Wash with plenty of water/…. Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Do not induce vomiting. Get medical advice/attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Suspected of causing genetic defects. May cause cancer. Symptoms/effects after inhalation : May cause drowsiness or dizziness. Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	No additional information available

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Obtain special instructions before use. Use personal protective equipment as required. Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes. Do not breathe vapours.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear appropriate mask

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	No data available
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-84 °C
Freezing point :	No data available
Boiling point :	86.7 °C
Flash point :	No data available
Auto-ignition temperature :	410 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	81.3 hPa at 20°C
Relative vapour density at 20°C :	No data available
Density :	1.463 g/cm3
Solubility :	No data available
Log Pow :	2.29
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.08 - 0.105 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye irritation.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Suspected of causing genetic defects.
Carcinogenicity :	May cause cancer.
STOT-single exposure :	May cause drowsiness or dizziness.
STOT-repeated exposure :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Harmful to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	TRICHLOROETHYLENE Extra Pure (79-01-6) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	TRICHLOROETHYLENE Extra Pure (79-01-6) Log Pow 2.29
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
TRICHLOROETHYLENE Extra Pure (79-01-6) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1710
UN-No. (IMDG) :	1710
UN-No. (IATA) :	1710
UN-No. (ADN) :	1710
UN-No. (RID) :	1710
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	TRICHLOROETHYLENE
Proper Shipping Name (IMDG) :	TRICHLOROETHYLENE
Proper Shipping Name (IATA) :	TRICHLOROETHYLENE
Proper Shipping Name (ADN) :	TRICHLOROETHYLENE
Proper Shipping Name (RID) :	TRICHLOROETHYLENE
Transport document description (ADR) :	UN 1710, TRICHLOROETHYLENE, 6.1, III
Transport document description (IMDG) :	UN 1710, TRICHLOROETHYLENE, 6.1, III
Transport document description (IATA) :	UN 1710, TRICHLOROETHYLENE, 6.1, III
Transport document description (ADN) :	UN 1710, TRICHLOROETHYLENE, 6.1, III
Transport document description (RID) :	UN 1710, TRICHLOROETHYLENE, 6.1, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1
Danger labels :	6.1
IMDG
Transport hazard class(es) :	6.1
Danger labels :	6.1
IATA
Transport hazard class(es) :	6.1
Danger labels :	6.1
ADN
Transport hazard class(es) :	6.1
Danger labels :	6.1
RID
Transport hazard class(es) :	6.1
Danger labels :	6.1
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T1 Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2Z
- Transport by sea
Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A Stowage and handling (IMDG) : SW2 Properties and observations (IMDG) : Colourless liquid with a chloroform-like odour. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. MFAG-No : 160
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y642 PCA limited quantity max net quantity (IATA) : 2L PCA packing instructions (IATA) : 655 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 663 CAO max net quantity (IATA) : 220L ERG code (IATA) : 6A
- Inland waterway transport
Classification code (ADN) : T1 Special provisions (ADN) : 802 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : T1 Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W12 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE8 Hazard identification number (RID) : 60
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Trichloroethylene is on the REACH Candidate List Trichloroethylene is on the REACH Annex XIV List: Authorisation number Sunset date REACH authorisation exemptions 21/04/2016
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : TRICHLOROETHYLENE Extra Pure is listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : TRICHLOROETHYLENE Extra Pure is listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3 Carc. 1B Carcinogenicity, Category 1B Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Muta. 2 Germ cell mutagenicity, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Narcosis H315 Causes skin irritation. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H341 Suspected of causing genetic defects. H350 May cause cancer. H412 Harmful to aquatic life with long lasting effects. T Toxic