TRIFLUOROACETIC ACID AR |
| Synonyms : TFA |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | TRIFLUOROACETIC ACID AR | ||
| Catalogue No. : | AL4661 | Product form : | Substance |
| CAS Number : | 76-05-1 | EC Number : | 200-929-3 |
| Grade : | EC Index Number : | 607-091-00-1 | |
| Chemical Formula : | C2HF3O2 | HSN Code : | 29159090 |
| Synonyms : | TFA | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Industrial For professional use only | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Skin corrosion/irritation, Category 1A H314 Acute toxicity (inhal.), Category 4 H332 Hazardous to the aquatic environment Chronic Hazard, Category 3 H412 Full text of H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Xn; R20 C; R35 R52/53 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS05
 GHS07
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H314 - Causes severe skin burns and eye damage. H332 - Harmful if inhaled. H412 - Harmful to aquatic life with long lasting effects. |
| Precautionary statements (CLP) : | P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a doctor. |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Not applicable | |||
| CAS No. : | 76-05-1 | ||
| EC Index No. : | 607-091-00-1 | ||
| EC No. : | 200-929-3 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. |
| First-aid measures after skin contact : | Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
| First-aid measures after ingestion : | Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after inhalation : Harmful if inhaled. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use extinguishing media containing water. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | On land, sweep or shovel into suitable containers. Collect spillage. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Do not breathe vapours. Avoid contact with skin and eyes. |
| Hygiene measures : | Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or face shield |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid |
| Molecular mass : | 114.02 g/mol |
| Colour : | Clear Colorless. |
| Odour : | strong pungent odor. |
| Odour threshold : | No data available |
| pH value : | 1 |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | -15.4 °C |
| Freezing point : | No data available |
| Boiling point : | 72.4 °C |
| Flash point : | No data available |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 130 hPa at 20°C |
| Relative vapour density at 20°C : | No data available |
| Density : | 1.489 g/cm3 |
| Solubility : | Water: Miscible in water |
| Log Pow : | 2.1 |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| Thermal decomposition generates : Corrosive vapours. | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Air contact. Direct sunlight. Moisture. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| Thermal decomposition generates : Corrosive vapours. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Inhalation: Harmful if inhaled. |
| Skin corrosion/irritation : | Causes severe skin burns and eye damage. pH: 1 |
| Serious eye damage/irritation : | Serious eye damage, category 1, implicit pH: 1 |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| STOT-single exposure : | Not classified |
| STOT-repeated exposure : | Not classified |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | Ecology - water : Harmful to aquatic life with long lasting effects. |
12.2 Persistence - degradability |
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| Persistence - degradability : | TRIFLUOROACETIC ACID AR (76-05-1) Persistence and degradability May cause long-term adverse effects in the environment. |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | TRIFLUOROACETIC ACID AR (76-05-1) Log Pow 2.1 |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 2699 |
| UN-No. (IMDG) : | 2699 |
| UN-No. (IATA) : | 2699 |
| UN-No. (ADN) : | 2699 |
| UN-No. (RID) : | 2699 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | TRIFLUOROACETIC ACID |
| Proper Shipping Name (IMDG) : | TRIFLUOROACETIC ACID |
| Proper Shipping Name (IATA) : | TRIFLUOROACETIC ACID |
| Proper Shipping Name (ADN) : | TRIFLUOROACETIC ACID |
| Proper Shipping Name (RID) : | TRIFLUOROACETIC ACID |
| Transport document description (ADR) : | UN 2699, TRIFLUOROACETIC ACID, 8, I |
| Transport document description (IMDG) : | UN 2699, TRIFLUOROACETIC ACID, 8, I |
| Transport document description (IATA) : | UN 2699, TRIFLUOROACETIC ACID, 8, I |
| Transport document description (ADN) : | UN 2699, TRIFLUOROACETIC ACID, 8, I |
| Transport document description (RID) : | UN 2699, TRIFLUOROACETIC ACID, 8, I |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8 
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| IMDG | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| IATA | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| ADN | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| RID | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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14.4. Packing group |
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| Packing group (ADR) : | I |
| Packing group (IMDG) : | I |
| Packing group (IATA) : | I |
| Packing group (ADN) : | I |
| Packing group (RID) : | I |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : C3 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E0 Packing instructions (ADR) : P001 Mixed packing provisions (ADR) : MP8, MP17 Portable tank and bulk container instructions (ADR) : T10 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L10BH Vehicle for tank carriage : AT Transport category (ADR) : 1 Special provisions for carriage - Operation (ADR) : S20 Hazard identification number (Kemler No.) : 88 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X APP code : B |
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| - Transport by sea | |
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Packing instructions (IMDG) : P001 Tank instructions (IMDG) : T10 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : B Stowage and handling (IMDG) : SW1, SW2, H2 Properties and observations (IMDG) : Colourless, fuming, hygroscopic liquid with a pungent odour. Miscible with water. When heated to decomposition or in contact with acids evolves toxic gases. In the presence of moisture, highly corrosive to most metals. Vapours are highly irritating to skin, eyes and mucous membranes. Liquid causes severe burns to skin, eyes and mucous membrane MFAG-No : 154 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : 850 PCA max net quantity (IATA) : 0.5L CAO packing instructions (IATA) : 854 CAO max net quantity (IATA) : 2.5L ERG code (IATA) : 8N |
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| - Inland waterway transport | |
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Classification code (ADN) : C3 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : C3 Limited quantities (RID) : 0 Excepted quantities (RID) : E0 Packing instructions (RID) : P001 Mixed packing provisions (RID) : MP8, MP17 Portable tank and bulk container instructions (RID) : T10 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L10BH Special provisions for RID tanks (RID) : TU38, TE22 Transport category (RID) : 1 Hazard identification number (RID) : 88 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions TRIFLUOROACETIC ACID AR is not on the REACH Candidate List TRIFLUOROACETIC ACID AR is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to AwSV; ID No. 729) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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