SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	PROPYLENE CARBONATE (for synthesis)
Catalogue No. :	AL3843	Product form :	Substance
CAS Number :	108-32-7	EC Number :	203-572-1
Grade :		EC Index Number :
Chemical Formula :	C4H6O3	HSN Code :	29209099
Synonyms :	1,2-Propanediol cyclic carbonate / 4-Methyl-1,3-dioxolan-2-one
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 2 H225 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Reproductive toxicity, Category 1B H360FD Specific target organ toxicity Single exposure, Category 3, Narcosis H336 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Specific target organ toxicity Repeated H373 exposure, Category 2 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Repr.Cat.2; R60 Repr.Cat.3; R63 F; R11 Xn; R48/20 Xi; R36/37/38 R67 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS07 GHS08
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H225 - Highly flammable liquid and vapour H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H360FD - May damage fertility. May damage the unborn child H373 - May cause damage to organs through prolonged or repeated exposure
Precautionary statements (CLP) :	P201 - Obtain special instructions before use P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - IF exposed or concerned: Get medical advice/attention P261 - Avoid breathing vapours, dust, fume, gas
2.3 Other hazards
Other hazards :	This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		1-BROMOPROPANE FOR SYNTHESIS
CAS No. :		108-32-7
EC No. :		203-572-1
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact :	Wash with plenty of soap and water. Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Do not induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : May damage fertility. Causes damage to organs. Symptoms/injuries after inhalation : May cause respiratory irritation. May cause drowsiness or dizziness. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	No additional information available

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Highly flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	Avoid contact with skin and eyes. Use only non-sparking tools. Keep away from sources of ignition - No smoking. Do not handle until all safety precautions have been read and understood. Do not breathe vapours. Use only outdoors or in a wellventilated ar
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Where exposure through inhalation may occur from use, respiratory protection equipment is recommended

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	No data available
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-110 °C
Freezing point :	No data available
Boiling point :	71 °C
Flash point :	22 °C
Auto-ignition temperature :	490 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable Highly flammable liquid and vapour
Vapour pressure :	100 mm Hg at 18°C
Relative vapour density at 20°C :	4.25
Density :	1.354 g/cm3
Solubility :	Water: 0.25 g/100ml @ 20°C
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.046 - 0.078 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye irritation.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	May damage fertility. May damage the unborn child.
Specific target organ toxicity (single exposure) :	May cause drowsiness or dizziness. May cause respiratory irritation.
Specific target organ toxicity (repeated exposure) :	May cause damage to organs through prolonged or repeated exposure.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
1-BROMOPROPANE FOR SYNTHESIS (106-94-5) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2344
UN-No. (IMDG) :	2344
UN-No. (IATA) :	2344
UN-No. (ADN) :	2344
UN-No. (RID) :	2344
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	BROMOPROPANES
Proper Shipping Name (IMDG) :	BROMOPROPANES
Proper Shipping Name (IATA) :	BROMOPROPANES
Proper Shipping Name (ADN) :	BROMOPROPANES
Proper Shipping Name (RID) :	BROMOPROPANES
Transport document description (ADR) :	UN 2344, BROMOPROPANES, 3, III
Transport document description (IMDG) :	UN 2344, BROMOPROPANES, 3, III
Transport document description (IATA) :	UN 2344, BROMOPROPANES, 3, III
Transport document description (ADN) :	UN 2344, BROMOPROPANES, 3, III
Transport document description (RID) :	UN 2344, BROMOPROPANES, 3, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	3
Danger labels :	3
IMDG
Transport hazard class(es) :	3
Danger labels :	3
IATA
Transport hazard class(es) :	3
Danger labels :	3
ADN
Transport hazard class(es) :	3
Danger labels :	3
RID
Transport hazard class(es) :	3
Danger labels :	3
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F1 Limited quantities (ADR) : 5L Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T2 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : LGBF Vehicle for tank carriage : FL Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Operation (ADR) : S2 Hazard identification number (Kemler No.) : 30 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 2YE
- Transport by sea
Special provision (IMDG) : 223 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T2 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : A MFAG-No : 129
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y344 PCA limited quantity max net quantity (IATA) : 10L PCA packing instructions (IATA) : 355 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 366 CAO max net quantity (IATA) : 220L Special provision (IATA) : A3 ERG code (IATA) : 3L
- Inland waterway transport
Not regulated
- Rail transport
Not regulated
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions 1-bromopropane (n-propyl bromide) is on the REACH Candidate List 1-BROMOPROPANE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (KBwS-Beschluss; WGK No 7315) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Repr. 1B Reproductive toxicity, Category 1B Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Narcosis STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H225 Highly flammable liquid and vapour H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H360FD May damage fertility. May damage the unborn child H373 May cause damage to organs through prolonged or repeated exposure R11 Highly flammable R36/37/38 Irritating to eyes, respiratory system and skin R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation R60 May impair fertility R63 Possible risk of harm to the unborn child R67 Vapours may cause drowsiness and dizziness F Highly flammable Xi Irritant Xn Harmful