CARBON TETRACHLORIDE For HPLC & Spectroscopy

CARBON TETRACHLORIDE For HPLC & Spectroscopy

Synonyms : Tetrachloromethane

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : CARBON TETRA CHLORIDE HPLC & SPECTROSCOPY
Catalogue No. : AL1144 Product form : Mixture
CAS Number : 56-23-5 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 29031400
Synonyms : Tetrachloromethane
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.3; R40
T; R23/24/25
T; R48/23
N; R59
R52/53
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
No labelling applicable
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
CAS No. : 56-23-5
3.2. Mixture
This mixture does not contain any substances to be mentioned according to the criteria of section 3.2 of REACH annex II

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : If you feel unwell, seek medical advice. Rinse mouth out with water.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : Causes damage to organs through prolonged or repeated exposure.
Symptoms/injuries after inhalation : Toxic if inhaled.
Symptoms/injuries after skin contact : Toxic in contact with skin.
Symptoms/injuries after ingestion : Toxic if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Harmful to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills
with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Do not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid
Molecular mass : 153.82 g/mol
Colour : Clear Colorless.
Odour : chloroform-like.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : 12.8
Melting point : -23 °C
Freezing point : No data available
Boiling point : 76 - 77
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : 100 °C
Flammability (solid, gas) : No data available
Vapour pressure : 121.3 hPa at 20°C
Relative vapour density at 20°C : 5.31
Density : 1.59 g/cm3
Solubility : Water: Insoluble
Log Pow : 2.83
Viscosity, kinematic : No data available
Viscosity, dynamic : 0.97 Pa.s 20 °C
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Toxic by inhalation, in contact with skin and if swallowed.
Irritation : Not classified
Corrosivity : Not classified
Sensitisation : Not classified
Repeated dose toxicity : Toxic: danger of serious damage to health by prolonged exposure through
inhalation.
Carcinogenicity : Limited evidence of a carcinogenic effect.
Mutagenicity : Not classified
Toxicity for reproduction : Not classified
Potential adverse human health effects
and symptoms
: Toxic if swallowed.
Skin corrosion/irritation :
Serious eye damage/irritation :
Respiratory or skin sensitisation :
Germ cell mutagenicity :
Carcinogenicity :
Potential adverse human health effects and symptoms : Toxic if swallowed. Toxic in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - air : Dangerous for the ozone layer. Ecology - water : Harmful to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability : CARBON TETRA CHLORIDE FOR HPLC & SPECTROSCOPY (56-23-5) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential : CARBON TETRA CHLORIDE FOR HPLC & SPECTROSCOPY (56-23-5) Log Pow 2.83
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...
Ecology - waste materials : Hazardous waste due to toxicity.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1846
UN-No. (IMDG) : 1846
UN-No. (IATA) : 1846
UN-No. (ADN) : 1846
UN-No. (RID) : 1846
14.2. UN proper shipping name
Proper Shipping Name (ADR) : CARBON TETRACHLORIDE
Proper Shipping Name (IMDG) : CARBON TETRACHLORIDE
Proper Shipping Name (IATA) : CARBON TETRACHLORIDE
Proper Shipping Name (ADN) : CARBON TETRACHLORIDE
Proper Shipping Name (RID) : CARBON TETRACHLORIDE
Transport document description (ADR) : UN 1846, CARBON TETRACHLORIDE, 6.1, II
Transport document description (IMDG) : UN 1846, CARBON TETRACHLORIDE, 6.1, II
Transport document description (IATA) : UN 1846, CARBON TETRACHLORIDE, 6.1, II
Transport document description (ADN) : UN 1846, CARBON TETRACHLORIDE, 6.1, II
Transport document description (RID) : UN 1846, CARBON TETRACHLORIDE, 6.1, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 6.1
Danger labels : 6.1
IMDG
Transport hazard class(es) : 6.1
Danger labels : 6.1
IATA
Transport hazard class(es) : 6.1
Danger labels : 6.1
ADN
Transport hazard class(es) : 6.1
Danger labels : 6.1
RID
Transport hazard class(es) : 6.1
Danger labels : 6.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : Yes (IMDG only)
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T1
Limited quantities (ADR) : 100ml
Excepted quantities (ADR) : E4
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container
instructions (ADR)
: T7
Portable tank and bulk container special
provisions (ADR)
: TP2
Tank code (ADR) : L4BH
Tank special provisions (ADR) : TU15, TE19
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S9, S19
Hazard identification number (Kemler No.) : 60
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : 2Z
- Transport by sea
Limited quantities (IMDG) : 100 ml
Excepted quantities (IMDG) : E4
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-A
Stowage category (IMDG) : A
Stowage and handling (IMDG) : SW2
MFAG-No : 151
- Air transport
PCA Excepted quantities (IATA) : E4
PCA Limited quantities (IATA) : Y641
PCA limited quantity max net quantity
(IATA)
: 1L
PCA packing instructions (IATA) : 654
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 661
CAO max net quantity (IATA) : 60L
ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T1
Special provisions (ADN) : 802
Limited quantities (ADN) : 100 ml
Excepted quantities (ADN) : E4
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP, TOX, A
Ventilation (ADN) : VE02
Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : T1
Limited quantities (RID) : 100ml
Excepted quantities (RID) : E4
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP15
Portable tank and bulk container
instructions (RID)
: T7
Portable tank and bulk container special
provisions (RID)
: TP2
Tank codes for RID tanks (RID) : L4BH
Special provisions for RID tanks (RID) : TU15
Transport category (RID) : 2
Special provisions for carriage – Loading
and unloading (RID)
: CW13, CW28, CW31
Colis express (express parcels) (RID) : CE5
Hazard identification number (RID) : 60
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no substances with Annex XVII restrictions
Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according
to AwSV, Annex 1)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding wome
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed
R40 Limited evidence of a carcinogenic effect
R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R59 Dangerous for the ozone layer
N Dangerous for the environment
T Toxic