CHLOROFORM For HPLC |
| Synonyms : Trichloromethane |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | CHLOROFORM HPLC & SPECTROSCOPY (trichloromethane) | ||
| Catalogue No. : | AL1298 | Product form : | Substance |
| CAS Number : | 67-66-3 | EC Number : | 200-663-8 |
| Grade : | EC Index Number : | 602-006-00-4 | |
| Chemical Formula : | CHCl3 | HSN Code : | 29031300 |
| Synonyms : | Trichloromethane | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Industrial For professional use only | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Acute toxicity (oral), Category 4 H302 Acute toxicity (inhal.), Category 3 H331 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye H319 irritation, Category 2 Carcinogenicity, Category 2 H351 Reproductive toxicity, Category 2 H361d Specific target organ toxicity Single exposure, Category 3, Narcosis H336 Specific target organ toxicity Repeated exposure, Category 1 H372 Full text of H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Carc.Cat.3; R40 Xn; R22 Xn; R48/20/22 Xi; R38 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS06
 GHS08
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H302 - Harmful if swallowed. H315 - Causes skin irritation. H319 - Causes serious eye irritation. H331 - Toxic if inhaled. H336 - May cause drowsiness or dizziness. H351 - Suspected of causing cancer. H361d - Suspected of damaging the unborn child. H372 - Causes damage to organs through prolonged or repeated exposure. |
| Precautionary statements (CLP) : | P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P311 - Call a POISON CENTER/doctor |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | CHLOROFORM FOR HPLC | ||
| CAS No. : | 67-66-3 | ||
| EC Index No. : | 602-006-00-4 | ||
| EC No. : | 200-663-8 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. |
| First-aid measures after skin contact : | Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. |
| First-aid measures after eye contact : | Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth out with water. If you feel unwell, seek medical advice. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after ingestion : Harmful if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Stop release. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Clean up immediately by sweeping or vacuum. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid |
| Molecular mass : | 119.38 g/mol |
| Colour : | Clear Colorless. |
| Odour : | sweet pleasant. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | 11.6 |
| Melting point : | -63 °C |
| Freezing point : | No data available |
| Boiling point : | 60.5 - 61.5 |
| Flash point : | No data available |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | 290 °C |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 213.3 hPa at 20°C |
| Relative vapour density at 20°C : | 4.12 |
| Density : | 1.492 g/cm3 |
| Solubility : | Water: Slightly soluble |
| Log Pow : | 1.97 |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | 0.58 cP @ 20 °C |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Air contact. Direct sunlight. Overheating. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Oral: Harmful if swallowed. Inhalation: Toxic if inhaled. |
| Skin corrosion/irritation : | Causes skin irritation. |
| Serious eye damage/irritation : | Causes serious eye irritation. |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Suspected of causing cancer. |
| Reproductive toxicity : | S |
| STOT-single exposure : | May cause drowsiness or dizziness. |
| STOT-repeated exposure : | Causes damage to organs through prolonged or repeated exposure. |
| Aspiration hazard : | Not classified CHLOROFORM FOR HPLC (67-66-3) Viscosity, kinematic 0.389 mm²/s |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | CHLOROFORM FOR HPLC (67-66-3) Log Pow 1.97 |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1888 |
| UN-No. (IMDG) : | 1888 |
| UN-No. (IATA) : | 1888 |
| UN-No. (ADN) : | 1888 |
| UN-No. (RID) : | 1888 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | CHLOROFORM |
| Proper Shipping Name (IMDG) : | CHLOROFORM |
| Proper Shipping Name (IATA) : | CHLOROFORM |
| Proper Shipping Name (ADN) : | CHLOROFORM |
| Proper Shipping Name (RID) : | CHLOROFORM |
| Transport document description (ADR) : | UN 1888, CHLOROFORM, 6.1, III |
| Transport document description (IMDG) : | UN 1888, CHLOROFORM, 6.1, III |
| Transport document description (IATA) : | UN 1888, CHLOROFORM, 6.1, III |
| Transport document description (ADN) : | UN 1888, CHLOROFORM, 6.1, III |
| Transport document description (RID) : | UN 1888, CHLOROFORM, 6.1, III |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1 
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| IMDG | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| IATA | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| ADN | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| RID | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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14.4. Packing group |
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| Packing group (ADR) : | III |
| Packing group (IMDG) : | III |
| Packing group (IATA) : | III |
| Packing group (ADN) : | III |
| Packing group (RID) : | III |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : T1 Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2Z |
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| - Transport by sea | |
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Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A Stowage and handling (IMDG) : SW2 Properties and observations (IMDG) : Colourless, volatile liquid.Boiling point: 61°C. Non-flammable. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. Anaesthetic. MFAG-No : 151 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y680 PCA limited quantity max net quantity (IATA) : 2L PCA packing instructions (IATA) : 680 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 680 CAO max net quantity (IATA) : 220L ERG code (IATA) : 6A |
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| - Inland waterway transport | |
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Classification code (ADN) : T1 Special provisions (ADN) : 802 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : T1 Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W12 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE8 Hazard identification number (RID) : 60 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions CHLOROFORM FOR HPLC is not on the REACH Candidate List CHLOROFORM FOR HPLC is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to AwSV; ID No. 54) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : CHLOROFORM FOR HPLC is listed |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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