SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	CYCLOHEXANE HPLC & SPECTROSCOPY
Catalogue No. :	AL1589	Product form :	Substance
CAS Number :	110-82-7	EC Number :	203-806-2
Grade :		EC Index Number :	601-017-00-1
Chemical Formula :	C6H12	HSN Code :	29021100
Synonyms :	Hexahydrobenzene;Hexamethylene; Hexanaphthalene.
Chemical Structure :
Laboratory chemicals :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 2 H225 Aspiration hazard, Category 1 H304 Skin corrosion/irritation, Category 2 H315 Specific target organ toxicity Single exposure, Category 3, Narcosis H336 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; R11 Xn; R65 Xi; R38 N; R50/53 R67 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS08 GHS07 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H225 - Highly flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H336 - May cause drowsiness or dizziness. H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) :	P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor P331 - Do NOT induce vomiting. P501 - Dispose of contents/container to hazardous or special waste collection p
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		CYCLOHEXANE FOR HPLC & SPECTROSCOPY
CAS No. :		110-82-7
EC Index No. :		601-017-00-1
EC No. :		203-806-2
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact :	Rinse skin with water/shower. Take off immediately all contaminated clothing. Wash with plenty of water/…. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label).
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after inhalation : May cause drowsiness or dizziness. Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after ingestion : May be fatal if swallowed and enters airways.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Highly flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Avoid contact with skin and eyes.
6.1.2. For emergency responders
Protective equipment	Avoid breathing dust/fume/gas/mist/vapours/spray
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Clean contaminated surfaces with an excess of water. Clean up immediately by sweeping or vacuum.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	No open flames. No smoking. Use only non-sparking tools. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area.
Hygiene measures :	Wash hands, forearms and face thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	84.16 g/mol
Colour :	Clear Colorless.
Odour :	characteristic ether like odour.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	2.6
Melting point :	4 - 7
Freezing point :	No data available
Boiling point :	80.7 °C
Flash point :	-18 °C
Auto-ignition temperature :	260 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Extremely flammable Highly flammable liquid and v
Vapour pressure :	102.7 hPa at 20°C
Relative vapour density at 20°C :	No data available
Density :	0.779 g/cm3
Solubility :	Water: Insoluble in water
Log Pow :	3.44
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.01 - 0.09 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Direct sunlight.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Not classified
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	May cause drowsiness or dizziness.
STOT-repeated exposure :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	CYCLOHEXANE FOR HPLC & SPECTROSCOPY (110-82-7) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	CYCLOHEXANE FOR HPLC & SPECTROSCOPY (110-82-7) Log Pow 3.44
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1145
UN-No. (IMDG) :	1145
UN-No. (IATA) :	1145
UN-No. (ADN) :	1145
UN-No. (RID) :	1145
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	CYCLOHEXANE
Proper Shipping Name (IMDG) :	CYCLOHEXANE
Proper Shipping Name (IATA) :	CYCLOHEXANE
Proper Shipping Name (ADN) :	CYCLOHEXANE
Proper Shipping Name (RID) :	CYCLOHEXANE
Transport document description (ADR) :	UN 1145, CYCLOHEXANE, 3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1145, CYCLOHEXANE, 3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1145, CYCLOHEXANE, 3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1145, CYCLOHEXANE, 3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1145, CYCLOHEXANE, 3, II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	3
Danger labels :	3
IMDG
Transport hazard class(es) :	3
Danger labels :	3
IATA
Transport hazard class(es) :	3
Danger labels :	3
ADN
Transport hazard class(es) :	3
Danger labels :	3
RID
Transport hazard class(es) :	3
Danger labels :	3
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F1 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : LGBF Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Operation (ADR) : S2, S20 Hazard identification number (Kemler No.) : 33 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 3YE
- Transport by sea
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : E Flash point (IMDG) : -18°C c.c. Properties and observations (IMDG) : Colourless, mobile liquid with a sweet aromatic odour. Flashpoint: -18°C c.c. Explosive limits: 1.2% to 8.4% Immiscible with water. Slightly irritating to skin, eyes and mucous membranes. Narcotic in high concentrations. MFAG-No : 128
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y341 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 353 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) : 60L ERG code (IATA) : 3H
- Inland waterway transport
Classification code (ADN) : F1 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : F1 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1 Tank codes for RID tanks (RID) : LGBF Transport category (RID) : 2 Colis express (express parcels) (RID) : CE7 Hazard identification number (RID) : 33
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions CYCLOHEXANE FOR HPLC & SPECTROSCOPY is not on the REACH Candidate List CYCLOHEXANE FOR HPLC & SPECTROSCOPY is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to AwSV; ID No. 63) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1 Asp. Tox. 1 Aspiration hazard, Category 1 Flam. Liq. 2 Flammable liquids, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Narcosis H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. R11 Highly flammable R38 Irritating to skin R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R65 Harmful: may cause lung damage if swallowed R67 Vapours may cause drowsiness and dizziness F Highly flammable N Dangerous for the environment Xi Irritant Xn Harmful