DICHLOROMETHANE For HPLC & UV Spectroscopy |
| Synonyms : Methylene chloride |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | DICHLORO METHANE HPLC & SPECTROSCOPY | ||
| Catalogue No. : | AL1715 | Product form : | Substance |
| CAS Number : | 75-09-2 | EC Number : | 200-838-9 |
| Grade : | EC Index Number : | 602-004-00-3 | |
| Chemical Formula : | CH2Cl2 | HSN Code : | 29031200 |
| Synonyms : | Methylene chloride / DCM | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Carcinogenicity, Category 2 H351 Specific target organ toxicity Single exposure, Category 3, Narcosis H336 Specific target organ H335 toxicity Single exposure, Category 3, Respiratory tract irritation Specific target organ toxicity Repeated exposure, Category 2 H373 Full text of hazard classes and H-statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Carc.Cat.3; R40 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS07
 GHS08
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| Signal word (CLP) : | Warning |
| Hazard statements (CLP) : | H315 - Causes skin irritation. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H336 - May cause drowsiness or dizziness. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. |
| Precautionary statements (CLP) : | P261 - Avoid breathing vapours, dust, fume, gas. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | DICHLOROMETHANE FOR HPLC & UV SPECTROSCOPY | ||
| CAS No. : | 75-09-2 | ||
| EC Index No. : | 602-004-00-3 | ||
| EC No. : | 200-838-9 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
| First-aid measures after skin contact : | Wash with plenty of water/…. Get immediate medical advice/attention. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Do not induce vomiting. Get medical advice/attention. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects : May cause damage to organs through prolonged or repeated exposure. Symptoms/effects after inhalation : May cause respiratory irritation. May cause drowsiness or dizziness. Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye irritation. Symptoms/effects after ingestion : Harmful if swallowed. Chronic symptoms : Suspected carcinogen. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use extinguishing media containing water. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | On land, sweep or shovel into suitable containers. Collect spillage. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Obtain special instructions before use. Avoid contact with skin and eyes. Do not breathe vapours. Take precautionary measures against static discharge. |
| Hygiene measures : | Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid Colour |
| Colour : | Clear Colorless. |
| Odour : | chloroform-like odor. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | 0.71 |
| Melting point : | -97 °C |
| Freezing point : | No data available |
| Boiling point : | 39.8 - 40 °C |
| Flash point : | No data available |
| Auto-ignition temperature : | 556 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 470.8 hPa at 20°C |
| Relative vapour density at 20°C : | No data available |
| Density : | 1.325 g/cm3 |
| Solubility : | Water: Slightly soluble |
| Log Pow : | 1.25 |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Direct sunlight. Finely divided metals. Overheating. Sparks. | |
10.5 Incompatible materials |
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| Oxidizing agent. | |
10.6 Hazardous decomposition products |
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| No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Not classified |
| Skin corrosion/irritation : | Causes skin irritation. |
| Serious eye damage/irritation : | Causes serious eye irritation. |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Suspected of causing cancer. |
| STOT-single exposure : | May cause drowsiness or dizziness. May cause respiratory irritation. |
| STOT-repeated exposure : | May cause damage to organs through prolonged or repeated exposure. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | DICHLOROMETHANE FOR HPLC & UV SPECTROSCOPY (75-09-2) Log Pow 1.25 |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1593 |
| UN-No. (IMDG) : | 1593 |
| UN-No. (IATA) : | 1593 |
| UN-No. (ADN) : | 1593 |
| UN-No. (RID) : | 1593 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | DICHLOROMETHANE |
| Proper Shipping Name (IMDG) : | DICHLOROMETHANE |
| Proper Shipping Name (IATA) : | DICHLOROMETHANE |
| Proper Shipping Name (ADN) : | DICHLOROMETHANE |
| Proper Shipping Name (RID) : | DICHLOROMETHANE |
| Transport document description (ADR) : | UN 1593, DICHLOROMETHANE, 6.1, III |
| Transport document description (IMDG) : | UN 1593, DICHLOROMETHANE, 6.1, III |
| Transport document description (IATA) : | UN 1593, DICHLOROMETHANE, 6.1, III |
| Transport document description (ADN) : | UN 1593, DICHLOROMETHANE, 6.1, III |
| Transport document description (RID) : | UN 1593, DICHLOROMETHANE, 6.1, III |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1 
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| IMDG | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| IATA | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| ADN | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| RID | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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14.4. Packing group |
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| Packing group (ADR) : | III |
| Packing group (IMDG) : | III |
| Packing group (IATA) : | III |
| Packing group (ADN) : | III |
| Packing group (RID) : | III |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : T1 Special provisions (ADR) : 516 Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Special packing provisions (ADR) : B8 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2Z |
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| - Transport by sea | |
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Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 IBC special provisions (IMDG) : B8 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A Properties and observations (IMDG) : Colourless, volatile liquid with heavy vapours. Boiling point: 40°C. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. MFAG-No : 160 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y642 PCA limited quantity max net quantity (IATA) : 2L PCA packing instructions (IATA) : 655 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 663 CAO max net quantity (IATA) : 220L ERG code (IATA) : 6L |
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| - Inland waterway transport | |
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Classification code (ADN) : T1 Special provisions (ADN) : 516, 802 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : T1 Special provisions (RID) : 516 Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Special packing provisions (RID) : B8 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W12 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE8 Hazard identification number (RID) : 60 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions DICHLOROMETHANE FOR HPLC & UV SPECTROSCOPY is not on the REACH Candidate List DICHLOROMETHANE FOR HPLC & UV SPECTROSCOPY is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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