SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	n-HEXANE HPLC & SPECTROSCOPY
Catalogue No. :	AL2400	Product form :	Substance
CAS Number :	110-54-3	EC Number :	203-777-6
Grade :		EC Index Number :	601-037-00-0
Chemical Formula :	C6H14	HSN Code :	29011000
Synonyms :	Hexyl hydride
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial. For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 2 H225 Aspiration hazard, Category 1 H304 Reproductive toxicity, Category 2 H361f Skin corrosion/irritation, Category 2 H315 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Specific target organ toxicity Repeated exposure, Category 2 H373 Specific target organ toxicity Single exposure, Category 3, Narcosis H336 Hazardous to the aquatic environment Chronic Hazard, Category 2 H411 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Repr.Cat.3; R62 F; R11 Xn; R65 Xn; R48/20 Xi; R38 N; R51/53 R67 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS08 GHS07 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H225 - Highly flammable liquid and vapour H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H336 - May cause drowsiness or dizziness H361f - Suspected of damaging fertility H373 - May cause damage to organs through prolonged or repeated exposure H411 - Toxic to aquatic life with long lasting effects
Precautionary statements (CLP) :	P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P273 - Avoid release to the environment P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P331 - Do NOT induce vomiting P261 - Avoid breathing fume, gas, vapours
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		n-HEXANE FOR HPLC & SPECTROSCOPY
CAS No. :		110-54-3
EC Index No. :		601-037-00-0
EC No. :		203-777-6
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact :	Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention.
First-aid measures after ingestion :	Immediately call a POISON CENTER or doctor/physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : Suspected of damaging fertility. May cause damage to organs. Symptoms/injuries after inhalation : May cause respiratory irritation. May cause drowsiness or dizziness. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	No additional information available

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Water spray. Foam. Dry powder. Carbon dioxide.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Highly flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Avoid breathing dust/fume/gas/mist/vapours/spray
Use personal protective equipment as required	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment. Toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	No naked lights. No smoking. Use only non-sparking tools. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing fume, gas, vapours. Use only outdoors or in a wellventilated area
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/… equipment.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	gasoline-like.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-95 °C
Freezing point :	No data available
Boiling point :	68 - 70 °C
Flash point :	-23 °C
Auto-ignition temperature :	225 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable Highly flammable liquid and vapour
Vapour pressure :	151 mm Hg at 25°C
Relative vapour density at 20°C :	2.97
Density :	0.678 g/cm3
Solubility :	Water: Insoluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	0.31 mPa.s 20°C
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	1.1 - 7.5 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Direct sunlight. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Not classified
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	Suspected of damaging fertility.
Specific target organ toxicity (single exposure) :	May cause respiratory irritation. May cause drowsiness or dizziness.
Specific target organ toxicity (repeated exposure) :	May cause damage to organs through prolonged or repeated exposure.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	n-HEXANE FOR HPLC & SPECTROSCOPY (110-54-3) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1208
UN-No. (IMDG) :	1208
UN-No. (IATA) :	1208
UN-No. (ADN) :	1208
UN-No. (RID) :	1208
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	HEXANES
Proper Shipping Name (IMDG) :	HEXANES
Proper Shipping Name (IATA) :	HEXANES
Proper Shipping Name (ADN) :	HEXANES
Proper Shipping Name (RID) :	HEXANES
Transport document description (ADR) :	UN 1208, HEXANES, 3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1208, HEXANES, 3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1208, HEXANES, 3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1208, HEXANES, 3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1208, HEXANES, 3, II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	3
Danger labels :	3
IMDG
Transport hazard class(es) :	3
Danger labels :	3
IATA
Transport hazard class(es) :	3
Danger labels :	3
ADN
Transport hazard class(es) :	3
Danger labels :	3
RID
Transport hazard class(es) :	3
Danger labels :	3
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F1 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : LGBF Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Operation (ADR) : S2, S20 Hazard identification number (Kemler No.) : 33 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 3YE
- Transport by sea
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : E MFAG-No : 128
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y341 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 353 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) : 60L ERG code (IATA) : 3H
- Inland waterway transport
Classification code (ADN) : F1 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : F1 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1 Tank codes for RID tanks (RID) : LGBF Transport category (RID) : 2 Colis express (express parcels) (RID) : CE7 Hazard identification number (RID) : 33
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions n-HEXANE FOR HPLC & SPECTROSCOPY is not on the REACH Candidate List n-HEXANE FOR HPLC & SPECTROSCOPY is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 2; WGK No 124) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2 Asp. Tox. 1 Aspiration hazard, Category 1 Flam. Liq. 2 Flammable liquids, Category 2 Repr. 2 Reproductive toxicity, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Narcosis H225 Highly flammable liquid and vapour H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H361f Suspected of damaging fertility H373 May cause damage to organs through prolonged or repeated exposure H411 Toxic to aquatic life with long lasting effects R11 Highly flammable R38 Irritating to skin R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R62 Possible risk of impaired fertility R65 Harmful: may cause lung damage if swallowed R67 Vapours may cause drowsiness and dizziness F Highly flammable N Dangerous for the environment Xi Irritant Xn Harmful