SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	ETHER PETROLEUM 40°-60°C HPLC & SPECTROSCOPY
Catalogue No. :	AL2027	Product form :	Substance
CAS Number :	8032-32-4	EC Number :	232-453-7
Grade :		EC Index Number :	649-263-00-9
Chemical Formula :		HSN Code :	27101213
Synonyms :	Petroleum Benzine, Petroleum Ether
Chemical Structure :
Laboratory chemicals :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 2 H225 Skin corrosion/irritation, Category 2 H315 Reproductive toxicity, Category 2 H361 Specific target organ toxicity Single exposure, Category 3, Narcosis H336 Specific target organ toxicity Repeated exposure, Category 2 H373 Aspiration hazard, Category 1 H304 Hazardous to the aquatic environment Chronic Hazard, Category 2 H411 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; N; Xn; Carc.Cat.2; Muta.Cat.2; R11-38-48/20-51/53-62-65-67 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS07 GHS08 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H225 - Highly flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H336 - May cause drowsiness or dizziness. H361 - Suspected of damaging fertility or the unborn child. H373 - May cause damage to organs through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) :	P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing vapours, dust, fume, gas. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, face protection, eye protection. P301+P310 - IF SWALLOWED: Immediately call a doctor. P331 - Do NOT induce vomiting.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		PETROLEUM ETHER 40-60°C for HPLC & UV Spectroscopy
CAS No. :		8032-32-4
EC Index No. :		649-263-00-9
EC No. :		232-453-7
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact :	Wash with plenty of water/…. Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion :	Immediately call a POISON CENTER/doctor. Rinse mouth.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Symptoms/effects after inhalation : May cause drowsiness or dizziness. Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after ingestion : May be fatal if swallowed and enters airways.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Highly flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	Avoid contact with skin and eyes. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use only outdoors or in a well-ventilated area. Keep away from sources of ignition - No smoking. Do not
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	gasoline or kerosene.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	10
Melting point :	< -73 °C
Freezing point :	No data available
Boiling point :	40 - 60 °C
Flash point :	-40 °C
Auto-ignition temperature :	288 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable Highly flammable liquid and vapour.
Vapour pressure :	40 mm Hg at 20°C
Relative vapour density at 20°C :	2.5
Density :	0.60 - 0.75
Solubility :	Water: Insoluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.011 - 0.059 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Heating may cause a fire.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Not classified
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	May cause drowsiness or dizziness.
STOT-repeated exposure :	May cause damage to organs through prolonged or repeated exposure.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	PETROLEUM ETHER 40-60°C for HPLC & UV Spectroscopy (8032-32-4) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1268
UN-No. (IMDG) :	1268
UN-No. (IATA) :	1268
UN-No. (ADN) :	1268
UN-No. (RID) :	1268
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	PETROLEUM DISTILLATES, N.O.S.
Proper Shipping Name (IMDG) :	PETROLEUM DISTILLATES, N.O.S.
Proper Shipping Name (IATA) :	PETROLEUM DISTILLATES, N.O.S.
Proper Shipping Name (ADN) :	PETROLEUM DISTILLATES, N.O.S.
Proper Shipping Name (RID) :	PETROLEUM DISTILLATES, N.O.S.
Transport document description (ADR) :	UN 1268, PETROLEUM DISTILLATES, N.O.S., 3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1268, PETROLEUM DISTILLATES, N.O.S., 3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1268, PETROLEUM DISTILLATES, N.O.S., 3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1268, PETROLEUM DISTILLATES, N.O.S., 3, II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1268, PETROLEUM DISTILLATES, N.O.S., 3, II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	3
Danger labels :	3
IMDG
Transport hazard class(es) :	3
Danger labels :	3
IATA
Transport hazard class(es) :	3
Danger labels :	3
ADN
Transport hazard class(es) :	3
Danger labels :	3
RID
Transport hazard class(es) :	3
Danger labels :	3
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F1 Special provisions (ADR) : 640C, 664 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP1, TP8, TP28 Tank code (ADR) : L1.5BN Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Operation (ADR) : S2, S20 Hazard identification number (Kemler No.) : 33 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 3YE
- Transport by sea
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP1, TP8, TP28 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-E Stowage category (IMDG) : B Properties and observations (IMDG) : Immiscible with water. MFAG-No : 128
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y341 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 353 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) : 60L Special provisions (IATA) : A3 ERG code (IATA) : 3H
- Inland waterway transport
Classification code (ADN) : F1 Special provisions (ADN) : 640C Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : F1 Special provisions (RID) : 640C Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP1, TP8, TP28 Tank codes for RID tanks (RID) : L1.5BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE7 Hazard identification number (RID) : 33
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions PETROLEUM ETHER 40-60�C for HPLC & UV Spectroscopy is not on the REACH Candidate List PETROLEUM ETHER 40-60�C for HPLC & UV Spectroscopy is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to AwSV; ID No. 9162) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : PETROLEUM ETHER 40-60°C for HPLC & UV Spectroscopy is listed SZW-lijst van mutagene stoffen : PETROLEUM ETHER 40-60°C for HPLC & UV Spectroscopy is listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2 Asp. Tox. 1 Aspiration hazard, Category 1 Flam. Liq. 2 Flammable liquids, Category 2 Repr. 2 Reproductive toxicity, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Narcosis H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H361 Suspected of damaging fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. F Highly flammable