SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	DIMETHYL FORMAMIDE HPLC & SPECTROSCOPY
Catalogue No. :	AL1838	Product form :	Substance
CAS Number :	68-12-2	EC Number :	200-679-5
Grade :		EC Index Number :	616-001-00-X
Chemical Formula :	C3H7NO	HSN Code :	29241900
Synonyms :	DMF
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial. For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 3 H226 Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhal.), Category 4 H332 Serious eye damage/eye irritation, Category 2 H319 Reproductive toxicity, Category 1B H360D Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Repr.Cat.2; R61 Xn; R20/21 Xi; R36 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS07 GHS08
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H226 - Flammable liquid and vapour H312+H332 - Harmful in contact with skin or if inhaled H319 - Causes serious eye irritation H360D - May damage the unborn child
Precautionary statements (CLP) :	P201 - Obtain special instructions before use P280 - Wear protective gloves, protective clothing, eye protection, face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - IF exposed or concerned: Get medical advice/attention
2.3 Other hazards
Other hazards :	This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		DIMETHYLFORMAMIDE FOR HPLC & SPECTROSCOPY
CAS No. :		68-12-2
EC Index No. :		616-001-00-X
EC No. :		200-679-5
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
First-aid measures after skin contact :	Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap and water. Wash contaminated clothing before reuse.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Do not induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : May damage the unborn child. Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Harmful in contact with skin. Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	No additional information available

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. No naked lights. No smoking. Use special care to avoid static electric charges.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Obtain special instructions before use. Avoid contact with skin and eyes. Do not breathe vapours. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharge.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	fishy pungent & amine like.
Odour threshold :	No data available
pH value :	6.7
Relative evaporation rate (butylacetate=1) :	0.17
Melting point :	-61 °C
Freezing point :	No data available
Boiling point :	153 °C
Flash point :	58 °C
Auto-ignition temperature :	445 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable
Vapour pressure :	2.7 at 20°C
Relative vapour density at 20°C :	2.52
Density :	0.949 g/cm3
Solubility :	Water: Complete
Log Pow :	1.01
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.022 - 0.152 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Dermal: Harmful in contact with skin. Inhalation: Harmful if inhaled.
Skin corrosion/irritation :	Not classified pH: 6.7
Serious eye damage/irritation :	Causes serious eye irritation. pH: 6.7
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	May damage the unborn child.
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	DIMETHYLFORMAMIDE FOR HPLC & SPECTROSCOPY (68-12-2) Log Pow 1.01
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
DIMETHYLFORMAMIDE FOR HPLC & SPECTROSCOPY (68-12-2) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2265
UN-No. (IMDG) :	2265
UN-No. (IATA) :	2265
UN-No. (ADN) :	2265
UN-No. (RID) :	2265
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	N,N-DIMETHYLFORMAMIDE
Proper Shipping Name (IMDG) :	N,N-DIMETHYLFORMAMIDE
Proper Shipping Name (IATA) :	N,N-DIMETHYLFORMAMIDE
Proper Shipping Name (ADN) :	N,N-DIMETHYLFORMAMIDE
Proper Shipping Name (RID) :	N,N-DIMETHYLFORMAMIDE
Transport document description (ADR) :	UN 2265, N,N-DIMETHYLFORMAMIDE, 3, III
Transport document description (IMDG) :	UN 2265, N,N-DIMETHYLFORMAMIDE, 3, III
Transport document description (IATA) :	UN 2265, N,N-DIMETHYLFORMAMIDE, 3, III
Transport document description (ADN) :	UN 2265, N,N-DIMETHYLFORMAMIDE, 3, III
Transport document description (RID) :	UN 2265, N,N-DIMETHYLFORMAMIDE, 3, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	3
Danger labels :	3
IMDG
Transport hazard class(es) :	3
Danger labels :	3
IATA
Transport hazard class(es) :	3
Danger labels :	3
ADN
Transport hazard class(es) :	3
Danger labels :	3
RID
Transport hazard class(es) :	3
Danger labels :	3
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F1 Limited quantities (ADR) : 5L Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T2 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : LGBF Vehicle for tank carriage : FL Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Operation (ADR) : S2 Hazard identification number (Kemler No.) : 30 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •2Y
- Transport by sea
Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T2 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : A Flash point (IMDG) : 58°C c.c. MFAG-No : 129
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y344 PCA limited quantity max net quantity (IATA) : 10L PCA packing instructions (IATA) : 355 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 366 CAO max net quantity (IATA) : 220L ERG code (IATA) : 3L
- Inland waterway transport
Not regulated
- Rail transport
Not regulated
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions N,N-dimethylformamide is on the REACH Candidate List DIMETHYLFORMAMIDE FOR HPLC & SPECTROSCOPY is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (KBwS-Beschluss; WGK No 83) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the produc
Denmark
Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Repr. 1B Reproductive toxicity, Category 1B H226 Flammable liquid and vapour H312 Harmful in contact with skin H319 Causes serious eye irritation H332 Harmful if inhaled H360D May damage the unborn child R20/21 Harmful by inhalation and in contact with skin R36 Irritating to eyes R61 May cause harm to the unborn child Xi Irritant Xn Harmful