MALEIC HYDRAZIDE Extra Pure |
| Synonyms : 1,2-Dihydro-3,6-pyridazinedione; 3,6-Dihydroxypyridazine; 3,6-Pyridazinediol |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | MALEIC HYDRAZIDE | ||
| Catalogue No. : | AL2860 | Product form : | Substance |
| CAS Number : | 123-33-1 | EC Number : | |
| Grade : | EC Index Number : | ||
| Chemical Formula : | HSN Code : | 29339900 | |
| Synonyms : | 1,2-Dihydro-3,6-pyridazinedione; 3,6-Dihydroxypyridazine; 3,6-Pyridazinediol | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Serious eye damage/eye irritation, Category 2 H319 Skin corrosion/irritation, Category 2 H315 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Specific target organ toxicity Single exposure, Category 2 H371 Full text of classification categories and H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Muta.Cat.3; R68 Xi; R36/37/38 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS08
 GHS07
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| Signal word (CLP) : | Warning |
| Hazard statements (CLP) : | H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H371 - May cause damage to organs |
| Precautionary statements (CLP) : | P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P261 - Avoid breathing dust/fume/gas/mist/vapours/spray |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | MALEIC HYDRAZIDE Extra Pure | ||
| CAS No. : | 123-33-1 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. |
| First-aid measures after skin contact : | Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label). Gently wash with plenty of soap and water. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth out with water. If you feel unwell, seek medical advice. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/injuries : May cause damage to organs. Symptoms/injuries after inhalation : May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Avoid breathing dust/fume/gas/mist/vapours/spray |
| Emergency procedures | Stop release. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Clear up rapidly by scoop or vacuum. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a wellventilated area. |
| Hygiene measures : | Wash ... thoroughly after handling. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Where exposure through inhalation may occur from use, respiratory protection equipment is recommended Other information : Do not breathe dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Solid |
| Molecular mass : | 112.09 g/mol |
| Colour : | White crystalline. |
| Odour : | odourless. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 299 - 301 |
| Freezing point : | No data available |
| Boiling point : | No data available |
| Flash point : | 300 °C |
| Auto-ignition temperature : | 375 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | No data available |
| Solubility : | No data available |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Direct sunlight. Air contact. Moisture. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Not classified |
| Skin corrosion/irritation : | Causes skin irritation. |
| Serious eye damage/irritation : | Causes serious eye irritation. |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| Reproductive toxicity : | Not classified |
| Specific target organ toxicity (single exposure) : | May cause respiratory irritation. May cause damage to organs. |
| Specific target organ toxicity (repeated exposure) : | Not classified |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1325 |
| UN-No. (IMDG) : | 1325 |
| UN-No. (IATA) : | 1325 |
| UN-No. (ADN) : | 1325 |
| UN-No. (RID) : | 1325 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | FLAMMABLE SOLID, ORGANIC, N.O.S. |
| Proper Shipping Name (IMDG) : | FLAMMABLE SOLID, ORGANIC, N.O.S. |
| Proper Shipping Name (IATA) : | FLAMMABLE SOLID, ORGANIC, N.O.S. |
| Proper Shipping Name (ADN) : | FLAMMABLE SOLID, ORGANIC, N.O.S. |
| Proper Shipping Name (RID) : | FLAMMABLE SOLID, ORGANIC, N.O.S. |
| Transport document description (ADR) : | UN 1325, FLAMMABLE SOLID, ORGANIC, N.O.S., 4.1 IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : 4.1 ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (R, III |
| Transport document description (IMDG) : | UN 1325, FLAMMABLE SOLID, ORGANIC, N.O.S., 4.1 IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : 4.1 ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (R, III |
| Transport document description (IATA) : | UN 1325, FLAMMABLE SOLID, ORGANIC, N.O.S., 4.1 IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : 4.1 ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (R, III |
| Transport document description (ADN) : | UN 1325, FLAMMABLE SOLID, ORGANIC, N.O.S., 4.1 IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : 4.1 ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (R, III |
| Transport document description (RID) : | UN 1325, FLAMMABLE SOLID, ORGANIC, N.O.S., 4.1 IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : 4.1 ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (R, III |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 4.1 IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : 4.1 ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (R |
| IMDG | |
| Transport hazard class(es) : | 4.1 IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : 4.1 ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (R |
| IATA | |
| Transport hazard class(es) : | 4.1 IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : 4.1 ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (R |
| ADN | |
| Transport hazard class(es) : | 4.1 IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : 4.1 ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (R |
| RID | |
| Transport hazard class(es) : | 4.1 IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : 4.1 ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (R |
14.4. Packing group |
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| Packing group (ADR) : | III |
| Packing group (IMDG) : | III |
| Packing group (IATA) : | III |
| Packing group (ADN) : | III |
| Packing group (RID) : | III |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : F1 Special provision (ADR) : 274 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P002, IBC08, LP02, R001 Special packing provisions (ADR) : B3 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T1 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAV Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Bulk (ADR) : VV1 Hazard identification number (Kemler No.) : 40 Orange plates : Tunnel restriction code (ADR) : E EAC code : 1Z |
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| - Transport by sea | |
| MFAG-No : 133 | |
| - Air transport | |
| No data available | |
| - Inland waterway transport | |
| No data available | |
| - Rail transport | |
| No data available | |
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions MALEIC HYDRAZIDE Extra Pure is not on the REACH Candidate List MALEIC HYDRAZIDE Extra Pure is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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