SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	AMMONIA SOLUTION 32%
Catalogue No. :	AL0314	Product form :	Substance
CAS Number :	1336-21-6	EC Number :	215-647-6
Grade :		EC Index Number :	007-001-01-2
Chemical Formula :		HSN Code :	28142000
Synonyms :	Ammonium Hydroxide / Ammonia aqueous / Ammonia water
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), Category 4 H302 Skin corrosion/irritation, Category 1B H314 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Hazardous to the aquatic environment Acute Hazard, Category 1 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
C; R34 N; R50 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS05 GHS07 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage H335 - May cause respiratory irritation H400 - Very toxic to aquatic life
Precautionary statements (CLP) :	P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P391 - Collect spillage
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		AMMONIA SOLUTION 32% EXTRA PURE
CAS No. :		1336-21-6
EC Index No. :		007-001-01-2
EC No. :		215-647-6
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact :	Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after eye contact : Causes serious eye damage.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Equip cleanup crew with proper protection
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
6.4 Reference to other sections
Reference :	See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Comply with applicable regulations.
Storage conditions :	Keep container tightly closed. Store in a well-ventilated place. Keep cool. Incompatible products : Strong bases. Strong acids.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear appropriate mask Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	35.05 g/mol
Colour :	Clear Colorless.
Odour :	ammonia odour.
Odour threshold :	No data available
pH value :	11.7
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-60 °C
Freezing point :	No data available
Boiling point :	38 - 100
Flash point :	No data available
Auto-ignition temperature :	6510 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Non flammable.
Vapour pressure :	153 hPa at 20 °C
Relative vapour density at 20°C :	1.21
Density :	0.9 g/cm3
Solubility :	Water: Infinitely soluble
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.16 - 0.27 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Not established.
10.3 Possibility of hazardous reactions
Not established.
10.4 Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5 Incompatible materials
Strong acids. Strong bases.
10.6 Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed.
Skin corrosion/irritation :	Causes severe skin burns and eye damage. pH: 11.7
Serious eye damage/irritation :	Serious eye damage, category 1, implicit pH: 11.7
Respiratory or skin sensitisation :	Not classified Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity :	Not classified Based on available data, the classification criteria are not met
Carcinogenicity :	Not classified Additional information : Based on available data, the classification criteria are not met
Reproductive toxicity :	Not classified Additional information : Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) :	May cause respiratory irritation. Additional information
Specific target organ toxicity (repeated exposure) :	Not classified Additional information
Aspiration hazard :	Not classified Additional information : Based on available data, the classification criteria are not met
Potential adverse human health effects and symptoms :	Harmful if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability :	Ammonia Solution 30% Extra Pure (1336-21-6) Persistence and degradability Not established.
12.3 Bioaccumulative potential
Bioaccumulative potential :	Ammonia Solution 30% Extra Pure (1336-21-6) Bioaccumulative potential Not established.
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	Additional information : Avoid release to the environment

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to ...
Ecology - waste materials :	Avoid release to the environment.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2672
UN-No. (IMDG) :	2672
UN-No. (IATA) :	2672
UN-No. (ADN) :	2672
UN-No. (RID) :	2672
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	AMMONIA SOLUTION
Proper Shipping Name (IMDG) :	AMMONIA SOLUTION
Proper Shipping Name (IATA) :	AMMONIA SOLUTION
Proper Shipping Name (ADN) :	AMMONIA SOLUTION
Proper Shipping Name (RID) :	AMMONIA SOLUTION
Transport document description (ADR) :	UN 2672, AMMONIA SOLUTION, 8, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 2672, AMMONIA SOLUTION, 8, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 2672, AMMONIA SOLUTION, 8, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 2672, AMMONIA SOLUTION, 8, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 2672, AMMONIA SOLUTION, 8, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8
Danger labels :	8
IMDG
Transport hazard class(es) :	8
Danger labels :	8
IATA
Transport hazard class(es) :	8
Danger labels :	8
ADN
Transport hazard class(es) :	8
Danger labels :	8
RID
Transport hazard class(es) :	8
Danger labels :	8
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C5 Special provision (ADR) : 543 Limited quantities (ADR) : 5L Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2R
- Transport by sea
Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 IBC special provisions (IMDG) : B11 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : A Stowage and handling (IMDG) : SW2, SW5 Segregation (IMDG) : SG35 MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y841 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 852 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 856 CAO max net quantity (IATA) : 60L Special provision (IATA) : A64 ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C5 Special provisions (ADN) : 543 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C5 Special provision (RID) : 543 Limited quantities (RID) : 5L Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP1 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W12 Colis express (express parcels) (RID) : CE8 Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Ammonia Solution 30% Extra Pure is not on the REACH Candidate List Ammonia Solution 30% Extra Pure is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 2; WGK No 211) 12th Ordinance Implementing
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No chemical safety assessment has been carried out

SECTION 16: Other Information
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixturejs, am