AMMONIUM PERSULPHATE Extra Pure |
| Synonyms : Ammonium peroxodisulfate, Ammonium peroxydisulfate, |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
|||
|---|---|---|---|
1.1 Product identifier |
|||
| Chemical Name : | AMMONIUM PERSULPHATE (ammonium peroxy disulphate) | ||
| Catalogue No. : | AL0378 | Product form : | Substance |
| CAS Number : | 7727-54-0 | EC Number : | 231-786-5 |
| Grade : | EC Index Number : | 016-060-00-6 | |
| Chemical Formula : | HSN Code : | 28334000 | |
| Synonyms : | Ammonium peroxodisulfate, Ammonium peroxydisulfate, | ||
| Chemical Structure : |
|
||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
|||
| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
|||
| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
||
1.4 Emergency Contact Details |
|||
| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
||
SECTION 2: Hazards identification |
|
|---|---|
2.1 Classification of the substance or mixture |
|
| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
|
Oxidising Solids, Category 2 H272 Acute toxicity (oral), Category 4 H302 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation Full text of hazard classes and H-statements : see section 16 |
|
| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| O; R8 Xn; R22 R42 Xi; R36/37/38 R43 Full text of R-phrases: see section 16 |
|
| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
|
| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS03
 GHS07
 GHS08
|
| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H272 - May intensify fire; oxidiser. H302 - Harmful if swallowed. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. |
| Precautionary statements (CLP) : | P220 - Keep/Store away from clothing, combustible materials. P261 - Avoid breathing vapours, dust, fume, gas. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P342+P311 - If experiencing respiratory symptoms: Call a doctor. |
2.3 Other hazards |
|
| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
|||
|---|---|---|---|
3.1. Substance |
|||
| Name : | AMMONIUM PERSULPHATE EXTRA PURE | ||
| CAS No. : | 7727-54-0 | ||
| EC Index No. : | 016-060-00-6 | ||
| EC No. : | 231-786-5 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
|||
| Not applicable | |||
SECTION 4: First aid measures |
|
|---|---|
4.1 Description of first aid measures |
|
| First-aid measures after inhalation : | If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. |
| First-aid measures after skin contact : | Wash with plenty of soap and water. Wash contaminated clothing before reuse. Get medical advice/attention. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. |
4.2 Most important symptoms and effects, both acute and delayed |
|
| Symptoms relating to use : | Symptoms/injuries after inhalation : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. May cause an allergic skin reaction. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Harmful if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
|
| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
|
|---|---|
5.1 Extinguishing media |
|
| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
|
| Fire hazard : | May cause fire or explosion; strong oxidiser. |
| Explosion hazard : | Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. |
5.3 Advice for firefighters |
|
| Protection during firefighting : | No additional information available |
SECTION 6: Accidental release measures |
|
|---|---|
6.1 Personal precautions, protective equipment and emergency procedures |
|
| General measures : | No open flames. No smoking. |
6.1.1. For non-emergency personnel |
|
| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
|
| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
|
| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
|
| Methods for cleaning up : | Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers. |
6.4 Reference to other sections |
|
| Reference : | No additional information available |
SECTION 7: Handling and storage |
|
|---|---|
7.1 Precautions for safe handling |
|
| Additional hazards when processed : | Hazardous waste due to potential risk of explosion. |
| Precautions for safe handling : | Do not breathe vapours. Avoid contact with skin and eyes. Use only outdoors or in a well-ventilated area. Keep away from sources of ignition - No smoking. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
|
| Technical measures : | Proper grounding procedures to avoid static electricity should be followed. |
| Storage conditions : | Keep in fireproof place. Keep container tightly closed. |
7.3 Specific end use(s) |
|
| No additional information available | |
SECTION 8: Exposure controls/personal protection |
|
|---|---|
8.1 Control parameters |
|
| No additional information available | |
8.2 Exposure controls |
|
| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | In case of inadequate ventilation wear respiratory protection. |
SECTION 9: Physical and chemical properties |
|
|---|---|
9.1 Information on basic physical and chemical properties |
|
| Physical state : | Solid Colour |
| Colour : | White crystalline. |
| Odour : | odourless. |
| Odour threshold : | No data available |
| pH value : | 1 - 2 |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 120 °C |
| Freezing point : | No data available |
| Boiling point : | No data available |
| Flash point : | No data available |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | 7.88 |
| Density : | 1.98 g/cm3 |
| Solubility : | Water: 228 g/l at 20 °C |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | The substance or mixture is classified as oxidizin |
| Explosive limits : | No data available |
9.2 Other information |
|
| No additional information available | |
SECTION 10: Stability and reactivity |
|
|---|---|
10.1 Reactivity |
|
| May intensify fire; oxidiser. | |
10.2 Chemical stability |
|
| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
|
| No additional information available | |
10.4 Conditions to avoid |
|
| Heat. Sparks. Open flame. | |
10.5 Incompatible materials |
|
| No additional information available | |
10.6 Hazardous decomposition products |
|
| No additional information available |
SECTION 11: Toxicological information |
|
|---|---|
11.1 Information on toxicological effects |
|
| Acute toxicity : | Oral: Harmful if swallowed. |
| Skin corrosion/irritation : | Causes skin irritation. pH: 1 - 2 |
| Serious eye damage/irritation : | Causes serious eye irritation. pH: 1 - 2 |
| Respiratory or skin sensitisation : | May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| STOT-single exposure : | May cause respiratory irritation. |
| STOT-repeated exposure : | Not classified |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. |
SECTION 12: Ecological information |
|
|---|---|
12.1 Toxicity |
|
| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
|
| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
|
| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
|
| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
|
| No additional information available | |
12.6 Other adverse effects |
|
| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
|
|---|---|
13.1 Waste treatment methods |
|
| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
| Additional information : | Hazardous waste due to potential risk of explosion. |
SECTION 14: Transport information |
|
|---|---|
| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
|
| UN-No. (ADR) : | 1444 |
| UN-No. (IMDG) : | 1444 |
| UN-No. (IATA) : | 1444 |
| UN-No. (ADN) : | 1444 |
| UN-No. (RID) : | 1444 |
14.2. UN proper shipping name |
|
| Proper Shipping Name (ADR) : | AMMONIUM PERSULPHATE |
| Proper Shipping Name (IMDG) : | AMMONIUM PERSULPHATE |
| Proper Shipping Name (IATA) : | AMMONIUM PERSULPHATE |
| Proper Shipping Name (ADN) : | AMMONIUM PERSULPHATE |
| Proper Shipping Name (RID) : | AMMONIUM PERSULPHATE |
| Transport document description (ADR) : | UN 1444, AMMONIUM PERSULPHATE, 5.1, III |
| Transport document description (IMDG) : | UN 1444, AMMONIUM PERSULPHATE, 5.1, III |
| Transport document description (IATA) : | UN 1444, AMMONIUM PERSULPHATE, 5.1, III |
| Transport document description (ADN) : | UN 1444, AMMONIUM PERSULPHATE, 5.1, III |
| Transport document description (RID) : | UN 1444, AMMONIUM PERSULPHATE, 5.1, III |
14.3. Transport hazard class(es) |
|
| ADR | |
| Transport hazard class(es) : | 5.1 |
| Danger labels : | 5.1 
|
| IMDG | |
| Transport hazard class(es) : | 5.1 |
| Danger labels : | 5.1
|
| IATA | |
| Transport hazard class(es) : | 5.1 |
| Danger labels : | 5.1
|
| ADN | |
| Transport hazard class(es) : | 5.1 |
| Danger labels : | 5.1
|
| RID | |
| Transport hazard class(es) : | 5.1 |
| Danger labels : | 5.1
|
14.4. Packing group |
|
| Packing group (ADR) : | III |
| Packing group (IMDG) : | III |
| Packing group (IATA) : | III |
| Packing group (ADN) : | III |
| Packing group (RID) : | III |
14.5. Environmental hazards |
|
| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
|
| - Overland transport | |
|
Classification code (ADR) : O2 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P002, IBC08, LP02, R001 Special packing provisions (ADR) : B3 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T1 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAV Tank special provisions (ADR) : TU3 Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Bulk (ADR) : VC1, VC2, AP6, AP7 Special provisions for carriage - Loading, unloading and handling (ADR) : CV24 Hazard identification number (Kemler No.) : 50 Orange plates : Tunnel restriction code (ADR) : E EAC code : 1Z |
|
| - Transport by sea | |
|
Limited quantities (IMDG) : 5 kg Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P002, LP02 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 Tank instructions (IMDG) : T1 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-Q Stowage category (IMDG) : A Properties and observations (IMDG) : White crystals or powder. Soluble in water.Mixtures with combustible material are sensitive to friction and are liable to ignite. MFAG-No : 140 |
|
| - Air transport | |
|
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y546 PCA limited quantity max net quantity (IATA) : 10kg PCA packing instructions (IATA) : 559 PCA max net quantity (IATA) : 25kg CAO packing instructions (IATA) : 563 CAO max net quantity (IATA) : 100kg Special provisions (IATA) : A803 ERG code (IATA) : 5L |
|
| - Inland waterway transport | |
|
Classification code (ADN) : O2 Limited quantities (ADN) : 5 kg Excepted quantities (ADN) : E1 Equipment required (ADN) : PP Number of blue cones/lights (ADN) : 0 |
|
| - Rail transport | |
|
Classification code (RID) : O2 Excepted quantities (RID) : E1 Packing instructions (RID) : P002, IBC08, LP02, R001 Special packing provisions (RID) : B3 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T1 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAV Special provisions for RID tanks (RID) : TU3 Transport category (RID) : 3 Special provisions for carriage – Bulk (RID) : VC1, VC2, AP6, AP7 Special provisions for carriage - Loading, unloading and handling (RID) : CW24 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 50 |
|
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
|
| Not applicable | |
SECTION 15: Regulatory information |
|---|
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions AMMONIUM PERSULPHATE EXTRA PURE is not on the REACH Candidate List AMMONIUM PERSULPHATE EXTRA PURE is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
||||||||||||||||||||||||