AMMONIUM SULPHAMATE Extra Pure

AMMONIUM SULPHAMATE Extra Pure

Synonyms : Ammonium Amidosulfonate; Ammonium Amidosulphate; Ammate.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : AMMONIUM SULPHAMATE
Catalogue No. : AL0394 Product form : Substance
CAS Number : 7773-06-0 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 28429090
Synonyms : Ammonium Amidosulfonate; Ammonium Amidosulphate; Ammate.
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral),
Category 4
H302
Hazardous to the aquatic
environment Acute
Hazard, Category 1
H400
Full text of hazard classes and H-statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R22
N; R50
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS07GHS07 GHS09GHS09
Signal word (CLP) : Warning
Hazard statements (CLP) : H302 - Harmful if swallowed.
H400 - Very toxic to aquatic life.
Precautionary statements (CLP) : P273 - Avoid release to the environment.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : AMMONIUM SULPHAMATE Extra Pure
CAS No. : 7773-06-0
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact : Wash with plenty of water/….
First-aid measures after eye contact : Rinse immediately with plenty of water.
First-aid measures after ingestion : Rinse mouth.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : No additional information available
4.3 Indication of any immediate medical attention and special treatment needed
General information : No additional information available

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
6.2 Environmental precautions
Very toxic to aquatic life.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as
possible. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours. Avoid dust formation.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid Colour
Colour : White crystalline.
Odour : slight amine odor.
Odour threshold : No data available
pH value : 4.5 - 6
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 131 °C
Freezing point : No data available
Boiling point : 160 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 1.769 g/cm3
Solubility : Water: 114.1 g/l at 20 °C
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed.
Skin corrosion/irritation : Not classified
pH: 4.5 - 6
Serious eye damage/irritation : Not classified
pH: 4.5 - 6
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3077
UN-No. (IMDG) : 3077
UN-No. (IATA) : 3077
UN-No. (ADN) : 3077
UN-No. (RID) : 3077
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IMDG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IATA) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (ADN) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (RID) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Transport document description (ADR) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 9
Danger labels : 9
IMDG
Transport hazard class(es) : 9
Danger labels : 9
IATA
Transport hazard class(es) : 9
Danger labels : 9
ADN
Transport hazard class(es) : 9
Danger labels : 9
RID
Transport hazard class(es) : 9
Danger labels : 9
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : M7
Special provisions (ADR) : 274, 335, 375, 601
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : PP12, B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T1, BK1, BK2, BK3
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAV, LGBV
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Packages
(ADR)
: V13
Special provisions for carriage - Bulk
(ADR)
: VC1, VC2
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13
Hazard identification number (Kemler No.) : 90
Orange plates :
Tunnel restriction code (ADR) : -
EAC code : 2Z
- Transport by sea
Special provisions (IMDG) : 274, 335, 966, 967, 969
Limited quantities (IMDG) : 5 kg
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : LP02, P002
Special packing provisions (IMDG) : PP12
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : BK1, BK2, BK3, T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-F
Stowage category (IMDG) : A
Stowage and handling (IMDG) : SW23
MFAG-No : 171
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y956
PCA limited quantity max net quantity
(IATA)
: 30kgG
PCA packing instructions (IATA) : 956
PCA max net quantity (IATA) : 400kg
CAO packing instructions (IATA) : 956
CAO max net quantity (IATA) : 400kg
Special provisions (IATA) : A97, A158, A179, A197
ERG code (IATA) : 9L
- Inland waterway transport
Classification code (ADN) : M7
Special provisions (ADN) : 274, 335, 375, 601
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, A
Number of blue cones/lights (ADN) : 0
Additional requirements/Remarks (ADN) : * Only in the molten state. ** For carriage in bulk see also 7.1.4.1. ** * Only in the
case of transport in bulk.
- Rail transport
Classification code (RID) : M7
Special provisions (RID) : 274, 335, 375, 601
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : PP12, B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T1, BK1, BK2, BK3
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAV, LGBV
Transport category (RID) : 3
Special provisions for carriage – Packages
(RID)
: W13
Special provisions for carriage – Bulk
(RID)
: VC1, VC2
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW13, CW31
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 90
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
AMMONIUM SULPHAMATE Extra Pure is not on the REACH Candidate List
AMMONIUM SULPHAMATE Extra Pure is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
H302 Harmful if swallowed.
H400 Very toxic to aquatic life.
R22 Harmful if swallowed
R50 Very toxic to aquatic organisms
N Dangerous for the environment
Xn Harmful