IODINE RESUBLIMED AR

IODINE RESUBLIMED AR

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : IODINE AR (resublimed)
Catalogue No. : AL2571 Product form : Substance
CAS Number : 7553-56-2 EC Number : 231-442-4
Grade : EC Index Number : 053-001-00-3
Chemical Formula : HSN Code : 28012000
Synonyms :
Chemical Structure :
Laboratory chemicals :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (dermal),
Category 4
H312
Acute toxicity (inhal.),
Category 4
H332
Hazardous to the aquatic
environment Acute
Hazard, Category 1
H400
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R20/21
N; R50
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS07GHS07 GHS09GHS09
Signal word (CLP) : Warning
Hazard statements (CLP) : H312+H332 - Harmful in contact with skin or if inhaled
H400 - Very toxic to aquatic life.
Precautionary statements (CLP) : P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : IODINE RESUBLIMED AR
CAS No. : 7553-56-2
EC Index No. : 053-001-00-3
EC No. : 231-442-4
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Gently wash with plenty of soap and water. If skin irritation occurs: Get medical
advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects after inhalation : Harmful if inhaled.
Symptoms/effects after skin contact : Harmful in contact with skin.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Very toxic to aquatic life.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Do not get in eyes, on skin, or on clothing.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 253.81 g/mol
Colour : Bluish-black crystals.
Odour : pungent odor.
Odour threshold : No data available
pH value : 5.4
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 113 °C
Freezing point : No data available
Boiling point : 184 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 0.3 mm Hg at 200C
Relative vapour density at 20°C : 8.8
Density : 4.98 g/cm3
Solubility : Water: 0.03 g/100ml @ 200C
Log Pow : 2.49
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Dermal: Harmful in contact with skin. Inhalation: Harmful if inhaled.
Skin corrosion/irritation : Not classified
pH: 5.4
Serious eye damage/irritation : Not classified
pH: 5.4
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : IODINE RESUBLIMED AR (7553-56-2) Log Pow 2.49
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3495
UN-No. (IMDG) : 3495
UN-No. (IATA) : 3495
UN-No. (ADN) : 3495
UN-No. (RID) : 3495
14.2. UN proper shipping name
Proper Shipping Name (ADR) : IODINE
Proper Shipping Name (IMDG) : IODINE
Proper Shipping Name (IATA) : IODINE
Proper Shipping Name (ADN) : IODINE
Proper Shipping Name (RID) : IODINE
Transport document description (ADR) : UN 3495, IODINE, 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 3495, IODINE, 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 3495, IODINE, 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 3495, IODINE, 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 3495, IODINE, 8 (6.1), III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 8 (6.1)
Danger labels : 8, 6.1
IMDG
Transport hazard class(es) : 8 (6.1)
Danger labels : 8, 6.1
IATA
Transport hazard class(es) : 8 (6.1)
Danger labels : 8, 6.1
ADN
Transport hazard class(es) : 8 (6.1)
Danger labels : 8, 6.1
RID
Transport hazard class(es) : 8 (6.1)
Danger labels : 8, 6.1
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CT2
Special provisions (ADR) : 279
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, R001
Special packing provisions (ADR) : B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T1
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAV, L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Bulk
(ADR)
: VC1, VC2, AP7
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Hazard identification number (Kemler No.) : 86
Orange plates :
Tunnel restriction code (ADR) : E
- Transport by sea
Special provisions (IMDG) : 279
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : B
Stowage and handling (IMDG) : SW2
Segregation (IMDG) : SG37
Properties and observations (IMDG) : Bluish-black solid with a metallic lustre and a pungent odour. Melting point: 114°C.
Below its melting point, may evolve vapours which are irritating to skin, eyes and
mucous membranes. Slightly soluble in water but soluble in most organic solvents.
Corrosive to most metals.
MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y845
PCA limited quantity max net quantity
(IATA)
: 5kg
PCA packing instructions (IATA) : 860
PCA max net quantity (IATA) : 25kg
CAO packing instructions (IATA) : 864
CAO max net quantity (IATA) : 100kg
Special provisions (IATA) : A113, A803
ERG code (IATA) : 8P
- Inland waterway transport
Classification code (ADN) : CT2
Special provisions (ADN) : 279, 802
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, EP, TOX, A
Ventilation (ADN) : VE02
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : CT2
Special provisions (RID) : 279
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, R001
Special packing provisions (RID) : B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T1
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAV, L4BN
Transport category (RID) : 3
Special provisions for carriage – Bulk
(RID)
: VC1, VC2, AP7
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW13, CW28
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 86
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
IODINE RESUBLIMED AR is not on the REACH Candidate List
IODINE RESUBLIMED AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to
AwSV; ID No. 492)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
H312 Harmful in contact with skin.
H332 Harmful if inhaled.
H400 Very toxic to aquatic life.
R20/21 Harmful by inhalation and in contact with skin
R50 Very toxic to aquatic organisms
N Dangerous for the environment
Xn Harmful