CADMIUM METAL GRANULAR AR

CADMIUM METAL GRANULAR AR

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : CADMIUM (metal) GRANULATED AR
Catalogue No. : AL1016 Product form : Substance
CAS Number : 7440-43-9 EC Number : 231-152-8
Grade : EC Index Number : 048-002-00-0
Chemical Formula : HSN Code : 81079010
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (inhal.),
Category 2
H330
Germ cell mutagenicity,
Category 2
H341
Carcinogenicity, Category
1B
H350
Reproductive toxicity,
Category 2
H361fd
Specific target organ
toxicity Repeated
exposure, Category 1
H372
Hazardous to the aquatic
environment Chronic
Hazard, Category 1
H410
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.2; R45
Muta.Cat.3; R68
Repr.Cat.3; R62
Repr.Cat.3; R63
T+; R26
T; R48/23/25
N; R50/53
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS06GHS06 GHS08GHS08 GHS09GHS09
Signal word (CLP) : Danger
Hazard statements (CLP) : H330 - Fatal if inhaled
H341 - Suspected of causing genetic defects
H350 - May cause cancer
H361fd - Suspected of damaging fertility. Suspected of damaging the unborn child
H372 - Causes damage to organs through prolonged or repeated exposure
H410 - Very toxic to aquatic life with long lasting effects
Precautionary statements (CLP) : P201 - Obtain special instructions before use
P260 - Do not breathe vapours, dust, gas, fume
P273 - Avoid release to the environment
P281 - Use personal protective equipment as required
P284 - [In case of inadequate ventilation] wear respiratory protection
P310 - Immediately call a POISON CENTER or doctor/physician
2.3 Other hazards
Other hazards : This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : CADMIUM (METAL) GRANULAR 99.9% AR
CAS No. : 7440-43-9
EC Index No. : 048-002-00-0
EC No. : 231-152-8
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
First-aid measures after skin contact : Gently wash with plenty of soap and water. Get immediate medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes.
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : Suspected of causing genetic defects. May cause cancer. Suspected of damaging
fertility. May cause damage to organs. Causes damage to organs through prolonged
or repeated exposure.
4.3 Indication of any immediate medical attention and special treatment needed
General information : No additional information available

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Equip cleanup crew with proper protection
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as
possible. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Obtain special instructions before use. Use personal protective equipment as required. Avoid contact with skin and eyes. Do not breathe vapours.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid Colour
Colour : Silver gray granules.
Odour : odourless.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 320.9 °C
Freezing point : No data available
Boiling point : 765 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 8.64 g/cm3
Solubility : Water: Insoluble
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Inhalation: Fatal if inhaled.
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Suspected of causing genetic defects.
Carcinogenicity : May cause cancer.
Reproductive toxicity : Suspected of damaging fertility. Suspected of damaging the unborn child.
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Causes damage to organs through prolonged or repeated exposure.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability : CADMIUM (METAL) GRANULAR 99.9% AR (7440-43-9) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
CADMIUM (METAL) GRANULAR 99.9% AR (7440-43-9)
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2570
UN-No. (IMDG) : 2570
UN-No. (IATA) : 2570
UN-No. (ADN) : 2570
UN-No. (RID) : 2570
14.2. UN proper shipping name
Proper Shipping Name (ADR) : CADMIUM COMPOUND
Proper Shipping Name (IMDG) : CADMIUM COMPOUND
Proper Shipping Name (IATA) : CADMIUM COMPOUND
Proper Shipping Name (ADN) : CADMIUM COMPOUND
Proper Shipping Name (RID) : CADMIUM COMPOUND
Transport document description (ADR) : UN 2570, CADMIUM COMPOUND, 6.1, I ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 2570, CADMIUM COMPOUND, 6.1, I ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 2570, CADMIUM COMPOUND, 6.1, I ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 2570, CADMIUM COMPOUND, 6.1, I ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 2570, CADMIUM COMPOUND, 6.1, I ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 6.1
Danger labels : 6.1
IMDG
Transport hazard class(es) : 6.1
Danger labels : 6.1
IATA
Transport hazard class(es) : 6.1
Danger labels : 6.1
ADN
Transport hazard class(es) : 6.1
Danger labels : 6.1
RID
Transport hazard class(es) : 6.1
Danger labels : 6.1
14.4. Packing group
Packing group (ADR) : I
Packing group (IMDG) : I
Packing group (IATA) : I
Packing group (ADN) : I
Packing group (RID) : I
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T5
Special provision (ADR) : 274, 596
Limited quantities (ADR) : 0
Excepted quantities (ADR) : E5
Packing instructions (ADR) : P002, IBC07
Mixed packing provisions (ADR) : MP18
Portable tank and bulk container
instructions (ADR)
: T6
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : S10AH, L10CH
Tank special provisions (ADR) : TU14, TU15, TE19, TE21
Vehicle for tank carriage : AT
Transport category (ADR) : 1
Special provisions for carriage - Packages
(ADR)
: V10
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV1, CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S9, S14
Hazard identification number (Kemler No.) : 66
Orange plates :
Tunnel restriction code (ADR) : C/E
EAC code : 2X
- Transport by sea
Special provision (IMDG) : 274
Limited quantities (IMDG) : 0
Excepted quantities (IMDG) : E5
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC07
IBC special provisions (IMDG) : B1
Tank instructions (IMDG) : T6
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-A
Stowage category (IMDG) : A
MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E5
PCA Limited quantities (IATA) : Forbidden
PCA limited quantity max net quantity
(IATA)
: Forbidden
PCA packing instructions (IATA) : 666
PCA max net quantity (IATA) : 5kg
CAO packing instructions (IATA) : 673
CAO max net quantity (IATA) : 50kg
Special provision (IATA) : A3, A5
ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T5
Special provisions (ADN) : 274, 596, 802
Limited quantities (ADN) : 0
Excepted quantities (ADN) : E5
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : T5
Special provision (RID) : 274, 596
Limited quantities (RID) : 0
Excepted quantities (RID) : E5
Packing instructions (RID) : P002, IBC07
Mixed packing provisions (RID) : MP18
Portable tank and bulk container
instructions (RID)
: T6
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : S10AH, L10CH
Special provisions for RID tanks (RID) : TU14, TU15, TU38, TE21, TE22
Transport category (RID) : 1
Special provisions for carriage – Packages
(RID)
: W10
Special provisions for carriage – Loading
and unloading (RID)
: CW13, CW28, CW31
Hazard identification number (RID) : 66
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
Cadmium is on the REACH Candidate List
CADMIUM (METAL) GRANULAR 99.9% AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (KBwS-Beschluss; WGK
No 8659)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
Carc. 1B Carcinogenicity, Category 1B
Muta. 2 Germ cell mutagenicity, Category 2
Repr. 2 Reproductive toxicity, Category 2
STOT RE 1 Specific target organ toxicity — Repeated exposure, Category 1
H330 Fatal if inhaled
H341 Suspected of causing genetic defects
H350 May cause cancer
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
R26 Very toxic by inhalation
R45 May cause cancer
R48/23/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation and if
swallowed
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R62 Possible risk of impaired fertility
R63 Possible risk of harm to the unborn child
R68 Possible risk of irreversible effects
N Dangerous for the environment
T Toxic
T+ Very toxic