SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	PHOSPHOROUS PENTACHLORIDE
Catalogue No. :	AL3547	Product form :	Substance
CAS Number :	10026-13-8	EC Number :	233-060-3
Grade :		EC Index Number :
Chemical Formula :	PCl5	HSN Code :	28129000
Synonyms :	Phosphorus(V) chloride
Chemical Structure :	PCl5
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), Category 4 H302 Acute toxicity (inhal.), Category 1 H330 Skin corrosion/irritation, Category 1B H314 Specific target organ toxicity Repeated H373 exposure, Category 2 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
T+; R26 Xn; R22 Xn; R48/20 C; R34 R14 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS05 GHS06 GHS08
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H302 - Harmful if swallowed. H314 - Causes severe skin burns and eye damage. H330 - Fatal if inhaled. H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary statements (CLP) :	P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P284 - Wear respiratory protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
CAS No. :		10026-13-8
EC No. :		233-060-3
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact :	Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Causes severe skin burns and eye damage. May cause damage to organs through prolonged or repeated exposure. Symptoms/effects after inhalation : Fatal if inhaled. Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Dry powder.
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release. Ventilate area.
6.2 Environmental precautions
Do not allow water (or moist air) contact with this material. Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Large spills: scoop solid spill into closing containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid Colour
Colour :	Yellowish.
Odour :	pungent odour.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	179 - 181 °C
Freezing point :	No data available
Boiling point :	No data available
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	< 1 hPa at 20°C
Relative vapour density at 20°C :	No data available
Density :	1.6 g/cm3
Solubility :	Water: Reacts with water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Reacts violently with water.
10.2 Chemical stability
No additional information available
10.3 Possibility of hazardous reactions
Highly reactive material. Reacts violently with water.
10.4 Conditions to avoid
Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed. Inhalation: Fatal if inhaled.
Skin corrosion/irritation :	Causes severe skin burns and eye damage.
Serious eye damage/irritation :	Serious eye damage, category 1, implicit
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Do not allow water (or moist air) contact with this material.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1806
UN-No. (IMDG) :	1806
UN-No. (IATA) :	1806
UN-No. (ADN) :	1806
UN-No. (RID) :	1806
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	PHOSPHORUS PENTACHLORIDE
Proper Shipping Name (IMDG) :	PHOSPHORUS PENTACHLORIDE
Proper Shipping Name (IATA) :	PHOSPHORUS PENTACHLORIDE
Proper Shipping Name (ADN) :	PHOSPHORUS PENTACHLORIDE
Proper Shipping Name (RID) :	PHOSPHORUS PENTACHLORIDE
Transport document description (ADR) :	UN 1806, PHOSPHORUS PENTACHLORIDE, 8, II
Transport document description (IMDG) :	UN 1806, PHOSPHORUS PENTACHLORIDE, 8, II
Transport document description (IATA) :	UN 1806, PHOSPHORUS PENTACHLORIDE, 8, II
Transport document description (ADN) :	UN 1806, PHOSPHORUS PENTACHLORIDE, 8, II
Transport document description (RID) :	UN 1806, PHOSPHORUS PENTACHLORIDE, 8, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8
Danger labels :	8
IMDG
Transport hazard class(es) :	8
Danger labels :	8
IATA
Transport hazard class(es) :	8
Danger labels :	8
ADN
Transport hazard class(es) :	8
Danger labels :	8
RID
Transport hazard class(es) :	8
Danger labels :	8
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C2 Limited quantities (ADR) : 1kg Excepted quantities (ADR) : E0 Packing instructions (ADR) : P002, IBC08 Special packing provisions (ADR) : B4 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAN Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V11 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 4W
- Transport by sea
Limited quantities (IMDG) : 1 kg Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B2, B4 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : C Stowage and handling (IMDG) : SW2 Segregation (IMDG) : SG6, SG8, SG10, SG12 MFAG-No : 137
- Air transport
PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : 863 CAO max net quantity (IATA) : 50kg Special provisions (IATA) : A1 ERG code (IATA) : 8W
- Inland waterway transport
Classification code (ADN) : C2 Limited quantities (ADN) : 1 kg Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C2 Limited quantities (RID) : 1kg Excepted quantities (RID) : E0 Packing instructions (RID) : P002, IBC08 Special packing provisions (RID) : B4 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAN Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W11 Colis express (express parcels) (RID) : CE10 Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions PHOSPHORUS PENTACHLORIDE FOR SYNTHESIS is not on the REACH Candidate List PHOSPHORUS PENTACHLORIDE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen -Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen -Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 1 (Inhalation) Acute toxicity (inhal.), Category 1 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Skin Corr. 1B Skin corrosion/irritation, Category 1B STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H330 Fatal if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. R14 Reacts violently with water R22 Harmful if swallowed R26 Very toxic by inhalation R34 Causes burns R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation C Corrosive T+ Very toxic Xn Harmful