CALCIUM METAL Extra Pure

CALCIUM METAL Extra Pure

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : CALCIUM (metal) LUMPS
Catalogue No. : AL1053 Product form : Substance
CAS Number : 7440-70-2 EC Number : 231-179-5
Grade : EC Index Number : 020-001-00-X
Chemical Formula : HSN Code : 28051200
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Substances and Mixtures
which, in contact with
water, emit flammable
gases, Category 2
H261
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; R15
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02
Signal word (CLP) : Danger
Hazard statements (CLP) : H261 - In contact with water releases flammable gases.
Precautionary statements (CLP) : P231+P232 - Handle under inert gas. Protect from moisture.
P422 - Store contents under inert gas
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : CALCIUM (METAL) Extra Pure
CAS No. : 7440-70-2
EC Index No. : 020-001-00-X
EC No. : 231-179-5
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep
at rest in a position comfortable for breathing. Get immediate medical
advice/attention.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water,
followed by warm water rinse. Wash with plenty of water/…. Get medical
advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : No additional information available
4.3 Indication of any immediate medical attention and special treatment needed
General information : No additional information available

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Soak up spills with inert solids,
such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Do not allow contact with water.
Precautions for safe handling : Protect from moisture. Handle under inert gas.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a dry place. Protect from moisture.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid Colour
Colour : Silvery grey.
Odour : odourless.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 850 °C
Freezing point : No data available
Boiling point : 1440 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : In contact with water releases flammable gases whi
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 1.54 g/cm3
Solubility : Water: Reacts with water with evolution of hydroge
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
In contact with water releases flammable gases which may ignite spontaneously.
10.4 Conditions to avoid
No additional information available
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1401
UN-No. (IMDG) : 1401
UN-No. (IATA) : 1401
UN-No. (ADN) : 1401
UN-No. (RID) : 1401
14.2. UN proper shipping name
Proper Shipping Name (ADR) : CALCIUM
Proper Shipping Name (IMDG) : CALCIUM
Proper Shipping Name (IATA) : CALCIUM
Proper Shipping Name (ADN) : CALCIUM
Proper Shipping Name (RID) : CALCIUM
Transport document description (ADR) : UN 1401, CALCIUM, 4.3, II
Transport document description (IMDG) : UN 1401, CALCIUM, 4.3, II
Transport document description (IATA) : UN 1401, CALCIUM, 4.3, II
Transport document description (ADN) : UN 1401, CALCIUM, 4.3, II
Transport document description (RID) : UN 1401, CALCIUM, 4.3, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 4.3
Danger labels : 4.3
IMDG
Transport hazard class(es) : 4.3
Danger labels : 4.3
IATA
Transport hazard class(es) : 4.3
Danger labels : 4.3
ADN
Transport hazard class(es) : 4.3
Danger labels : 4.3
RID
Transport hazard class(es) : 4.3
Danger labels : 4.3
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : W2
Limited quantities (ADR) : 500g
Excepted quantities (ADR) : E2
Packing instructions (ADR)
: P410, IBC07
Mixed packing provisions (ADR)
: MP14
Portable tank and bulk container
instructions (ADR)
: T3
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR)
: SGAN
Vehicle for tank carriage
: AT
Transport category (ADR)
:
2
Special provisions for carriage
- Packages
(ADR)
: V1
Special provisions for carriage
- Loading,
unloading and handling (ADR)
: CV23
Hazard identification number (Kemler No.)
: 423
Orange plates
:
Tunnel restriction code (ADR)
: D/E
EAC code
: 4W
- Transport by sea
Limited quantities (IMDG)
: 500
g
Excepted quantities (IMDG)
: E2
Packing instructions (IMDG)
: P410
Special packing provisions (IMDG)
: PP31, PP40
IBC packing instructions (IMDG)
: IBC07
IBC special provisions (IMDG)
: B2
Tank instructions (IMDG)
: T3
Tank special provisions (IMDG)
: TP33
EmS-No. (Fire)
: F-G
EmS-No. (Spillage)
: S-O
Stowage category (IMDG)
:
E
Stowage and handling (IMDG)
: H1
Segregation (IMDG)
: SG35, SG26
MFAG-No
: 138
- Air transport
PCA Excepted quantities (IATA)
: E2
PCA Limited quantities (IATA)
: Y475
PCA limited quantity max net quantity
(IATA)
: 5kg
PCA packing instructions (IATA)
: 484
PCA max net quantity (IATA)
: 15kg
CAO packing instructions (IATA)
: 490
CAO max net quantity (IATA)
: 50kg
ERG code (IATA)
: 4W
- Inland waterway transport
Classification code (ADN)
: W2
Limited quantities (ADN)
: 500
g
Excepted quantities (ADN)
: E2
Equipment required (ADN)
: PP, EX,
A
Ventilation (ADN)
: VE01
Provisions for handling and stowage of the
cargo (ADN)
: HA08
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : W2
Limited quantities (RID) : 500g
Excepted quantities (RID) : E2
Packing instructions (RID) : P410, IBC07
Mixed packing provisions (RID) : MP14
Portable tank and bulk container
instructions (RID)
: T3
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAN
Transport category (RID) : 2
Special provisions for carriage – Packages
(RID)
: W1
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW23
Colis express (express parcels) (RID) : CE10
Hazard identification number (RID) : 423
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
Calcium Metal is not on the REACH Candidate List
Calcium Metal is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV;
ID No. 9286)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Water-react. 2 Substances and Mixtures which, in contact with water, emit flammable gases, Category 2
H261 In contact with water releases flammable gases.
R15 Contact with water liberates extremely flammable gases
F Highly flammable