POTASSIUM PERMANGANATE Extra Pure |
Synonyms : Potassium manganate(VII), Permanganate of potash |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
|||
---|---|---|---|
1.1 Product identifier |
|||
Chemical Name : | POTASSIUM PERMANGANATE | ||
Catalogue No. : | AL3752 | Product form : | Substance |
CAS Number : | 7722-64-7 | EC Number : | |
Grade : | EC Index Number : | ||
Chemical Formula : | KMnO4 | HSN Code : | 28416100 |
Synonyms : | Potassium manganate(VII) / Permanganate of potash | ||
Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
|||
Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
|||
Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
||
1.4 Emergency Contact Details |
|||
Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
SECTION 2: Hazards identification |
|
---|---|
2.1 Classification of the substance or mixture |
|
Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
Oxidising Solids, Category 1 H271 Acute toxicity (oral), Category 4 H302 Full text of classification categories and H statements : see section 16 |
|
Classification according to Directive 67/548/EEC or 1999/45/EC | |
O; R9 Xn; R22 Full text of R-phrases: see section 16 |
|
Adverse physicochemical, human health and environmental effects | |
No additional information available | |
2.2 Label elements |
|
Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
Hazard pictograms (CLP) : | GHS03 GHS07 |
Signal word (CLP) : | - |
Hazard statements (CLP) : | H271 - May cause fire or explosion; strong oxidiser H302 - Harmful if swallowed |
Precautionary statements (CLP) : | P220 - Keep/Store away from clothing/¦/combustible materials |
2.3 Other hazards |
|
Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
|||
---|---|---|---|
3.1. Substance |
|||
Name : | POTASSIUM PERCHLORATE AR/ACS | ||
CAS No. : | 7722-64-7 | ||
Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
|||
Not applicable |
SECTION 4: First aid measures |
|
---|---|
4.1 Description of first aid measures |
|
First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. |
First-aid measures after skin contact : | Take off contaminated clothing. Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention. |
First-aid measures after eye contact : | Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. |
First-aid measures after ingestion : | Rinse mouth out with water. If you feel unwell, seek medical advice. |
4.2 Most important symptoms and effects, both acute and delayed |
|
Symptoms relating to use : | Symptoms/injuries after ingestion : Harmful if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
|
General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
|
---|---|
5.1 Extinguishing media |
|
Suitable extinguishing media : | Foam. Dry powder. Carbon dioxide. Water spray. Sand. |
Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
|
Fire hazard : | May cause fire or explosion; strong oxidiser. |
Explosion hazard : | Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. |
5.3 Advice for firefighters |
|
Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
|
---|---|
6.1 Personal precautions, protective equipment and emergency procedures |
|
General measures : | No naked lights. No smoking. |
6.1.1. For non-emergency personnel |
|
Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
|
Protective equipment | Use personal protective equipment as required |
Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
|
Do not allow to enter drains or water courses. Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
|
Methods for cleaning up : | On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. |
6.4 Reference to other sections |
|
Reference : | See Heading 8. Exposure controls and personal protection. |
SECTION 7: Handling and storage |
|
---|---|
7.1 Precautions for safe handling |
|
Additional hazards when processed : | Hazardous waste due to potential risk of explosion. |
Precautions for safe handling : | Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Take any precaution to avoid mixing with combustibles/... |
Hygiene measures : | Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. |
7.2 Conditions for safe storage, including any incompatibilities |
|
Technical measures : | Proper grounding procedures to avoid static electricity should be followed. |
Storage conditions : | Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Keep in fireproof place. Incompatible products : Strong bases. Strong acids. |
7.3 Specific end use(s) |
|
No additional information available |
SECTION 8: Exposure controls/personal protection |
|
---|---|
8.1 Control parameters |
|
No additional information available | |
8.2 Exposure controls |
|
Hand protection : | protective gloves |
Eye protection : | Chemical goggles or safety glasses |
Skin and body protection : | Wear suitable protective clothing |
Respiratory protection : | Wear appropriate mask Other information : Do not eat, drink or smoke during use. |
SECTION 9: Physical and chemical properties |
|
---|---|
9.1 Information on basic physical and chemical properties |
|
Physical state : | Solid Colour |
Colour : | White crystalline. |
Odour : | odourless. |
Odour threshold : | No data available |
pH value : | 5.0 - 6.5 |
Relative evaporation rate (butylacetate=1) : | No data available |
Melting point : | 400 °C |
Freezing point : | No data available |
Boiling point : | 4000 °C |
Flash point : | No data available |
Auto-ignition temperature : | No data available |
Decomposition temperature : | No data available |
Flammability (solid, gas) : | Non flammable. |
Vapour pressure : | No data available |
Relative vapour density at 20°C : | 4.8 |
Density : | 2.52 g/cm3 |
Solubility : | Water: 13.9 g/l at 20 °C |
Log Pow : | No data available |
Viscosity, kinematic : | No data available |
Viscosity, dynamic : | No data available |
Explosive properties : | No data available |
Oxidising properties : | May cause fire or explosion; strong oxidiser. |
Explosive limits : | No data available |
9.2 Other information |
|
No additional information available |
SECTION 10: Stability and reactivity |
|
---|---|
10.1 Reactivity |
|
No additional information available | |
10.2 Chemical stability |
|
May cause fire or explosion; strong oxidiser. | |
10.3 Possibility of hazardous reactions |
|
Not established. | |
10.4 Conditions to avoid |
|
Do not allow contact with water. Moisture. Direct sunlight. | |
10.5 Incompatible materials |
|
Strong acids. Strong bases. | |
10.6 Hazardous decomposition products |
|
fume. Carbon monoxide. Carbon dioxide. |
SECTION 11: Toxicological information |
|
---|---|
11.1 Information on toxicological effects |
|
Acute toxicity : | Oral: Harmful if swallowed. |
Skin corrosion/irritation : | Not classified pH: 5.0 - 6.5 |
Additional information : | Based on available data, the classification criteria are not met |
Serious eye damage/irritation : | Not classified pH: 5.0 - 6.5 Additional information : Based on available data, the classification criteria are not met |
Respiratory or skin sensitisation : | Not classified Additional information : Based on available data, the classification criteria are not met |
Germ cell mutagenicity : | Not classified Based on available data, the classification criteria are not met |
Carcinogenicity : | Not classified Additional information : Based on available data, the classification criteria are not met |
Reproductive toxicity : | Not classified Additional information : Based on available data, the classification criteria are not met |
Specific target organ toxicity (single exposure) : | Not classified Additional information |
Specific target organ toxicity (repeated exposure) : | Not classified Additional information |
Aspiration hazard : | Not classified Additional information : Based on available data, the classification criteria are not met |
Potential adverse human health effects and symptoms : | Harmful if swallowed. |
SECTION 12: Ecological information |
|
---|---|
12.1 Toxicity |
|
Toxicity information : | No additional information available |
12.2 Persistence - degradability |
|
Persistence - degradability : | Potassium perchlorate (7778-74-7) Persistence and degradability Not established. |
12.3 Bioaccumulative potential |
|
Bioaccumulative potential : | Potassium perchlorate (7778-74-7) Bioaccumulative potential Not established. |
12.4 Mobility in soil |
|
Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
|
No additional information available | |
12.6 Other adverse effects |
|
Environmental precautions : | Additional information : Avoid release to the environment |
SECTION 13: Disposal considerations |
|
---|---|
13.1 Waste treatment methods |
|
Product/Packaging disposal recommendations : | Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to ... |
Additional information : | Hazardous waste due to potential risk of explosion. |
Ecology - waste materials : | Avoid release to the environment. |
SECTION 14: Transport information |
|
---|---|
In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
|
UN-No. (ADR) : | 1489 |
UN-No. (IMDG) : | 1489 |
UN-No. (IATA) : | 1489 |
UN-No. (ADN) : | 1489 |
UN-No. (RID) : | 1489 |
14.2. UN proper shipping name |
|
Proper Shipping Name (ADR) : | POTASSIUM PERCHLORATE |
Proper Shipping Name (IMDG) : | POTASSIUM PERCHLORATE |
Proper Shipping Name (IATA) : | POTASSIUM PERCHLORATE |
Proper Shipping Name (ADN) : | POTASSIUM PERCHLORATE |
Proper Shipping Name (RID) : | POTASSIUM PERCHLORATE |
Transport document description (ADR) : | UN 1489, POTASSIUM PERCHLORATE, 5.1, II |
Transport document description (IMDG) : | UN 1489, POTASSIUM PERCHLORATE, 5.1, II |
Transport document description (IATA) : | UN 1489, POTASSIUM PERCHLORATE, 5.1, II |
Transport document description (ADN) : | UN 1489, POTASSIUM PERCHLORATE, 5.1, II |
Transport document description (RID) : | UN 1489, POTASSIUM PERCHLORATE, 5.1, II |
14.3. Transport hazard class(es) |
|
ADR | |
Transport hazard class(es) : | 5.1 |
Danger labels : | 5.1 |
IMDG | |
Transport hazard class(es) : | 5.1 |
Danger labels : | 5.1 |
IATA | |
Transport hazard class(es) : | 5.1 |
Danger labels : | 5.1 |
ADN | |
Transport hazard class(es) : | 5.1 |
Danger labels : | 5.1 |
RID | |
Transport hazard class(es) : | 5.1 |
Danger labels : | 5.1 |
14.4. Packing group |
|
Packing group (ADR) : | II |
Packing group (IMDG) : | II |
Packing group (IATA) : | II |
Packing group (ADN) : | II |
Packing group (RID) : | II |
14.5. Environmental hazards |
|
Dangerous for the environment : | No |
Marine pollutant : | No |
Other information : | No supplementary information available |
14.6. Special precautions for user |
|
- Overland transport | |
Classification code (ADR) : O2 Limited quantities (ADR) : 1kg Excepted quantities (ADR) : E2 Packing instructions (ADR) : P002, IBC06 Mixed packing provisions (ADR) : MP2 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAV Tank special provisions (ADR) : TU3 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V11 Special provisions for carriage - Bulk (ADR) : VC1, VC2, AP6, AP7 Special provisions for carriage - Loading, unloading and handling (ADR) : CV24 Special provisions for carriage - Operation (ADR) : S23 Hazard identification number (Kemler No.) : 50 Orange plates : Tunnel restriction code (ADR) : E EAC code : 1Y |
|
- Transport by sea | |
Limited quantities (IMDG) : 1 kg Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC06 IBC special provisions (IMDG) : B2 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-H EmS-No. (Spillage) : S-Q Stowage category (IMDG) : A Segregation (IMDG) : SG38, SG49 MFAG-No : 140 |
|
- Air transport | |
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y544 PCA limited quantity max net quantity (IATA) : 2.5kg PCA packing instructions (IATA) : 558 PCA max net quantity (IATA) : 5kg CAO packing instructions (IATA) : 562 CAO max net quantity (IATA) : 25kg ERG code (IATA) : 5L |
|
- Inland waterway transport | |
Classification code (ADN) : O2 Limited quantities (ADN) : 1 kg Excepted quantities (ADN) : E2 Equipment required (ADN) : PP Number of blue cones/lights (ADN) : 0 |
|
- Rail transport | |
Classification code (RID) : O2 Limited quantities (RID) : 1kg Excepted quantities (RID) : E2 Packing instructions (RID) : P002, IBC06 Mixed packing provisions (RID) : MP2 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAV Special provisions for RID tanks (RID) : TU3 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W11 Special provisions for carriage – Bulk (RID) : VC1, VC2, AP6, AP7 Special provisions for carriage – Loading and unloading (RID) : CW24 Colis express (express parcels) (RID) : CE10 Hazard identification number (RID) : 50 |
|
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
|
Not applicable |
SECTION 15: Regulatory information |
---|
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
15.1.1 EU-Regulations : |
No REACH Annex XVII restrictions Potassium perchlorate is not on the REACH Candidate List Potassium perchlorate is not on the REACH Annex XIV List |
15.1.2. National regulations |
Germany |
AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 2; WGK No 169) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
Denmark |
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product |
15.2 Chemical Safety Assessment |
No chemical safety assessment has been carried out |
SECTION 16: Other Information |
||||
---|---|---|---|---|
|