POTASSIUM PERMANGANATE Extra Pure

POTASSIUM PERMANGANATE Extra Pure

Synonyms : Potassium manganate(VII), Permanganate of potash

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : POTASSIUM PERMANGANATE
Catalogue No. : AL3752 Product form : Substance
CAS Number : 7722-64-7 EC Number :
Grade : EC Index Number :
Chemical Formula : KMnO4 HSN Code : 28416100
Synonyms : Potassium manganate(VII) / Permanganate of potash
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids,
Category 1
H271
Acute toxicity (oral),
Category 4
H302
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
O; R9
Xn; R22
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS03GHS03 GHS07GHS07
Signal word (CLP) : -
Hazard statements (CLP) : H271 - May cause fire or explosion; strong oxidiser
H302 - Harmful if swallowed
Precautionary statements (CLP) : P220 - Keep/Store away from clothing/¦/combustible materials
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : POTASSIUM PERCHLORATE AR/ACS
CAS No. : 7722-64-7
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Take off contaminated clothing. Wash skin with plenty of water. If skin irritation
occurs: Get medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard : May cause fire or explosion; strong oxidiser.
Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing
risk of burns and injuries.
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Do not allow to enter drains or water courses. Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store
away from other materials.
6.4 Reference to other sections
Reference : See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Hazardous waste due to potential risk of explosion.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Take any precaution to avoid mixing with combustibles/...
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep
container closed when not in use. Keep in fireproof place.
Incompatible products : Strong bases. Strong acids.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid Colour
Colour : White crystalline.
Odour : odourless.
Odour threshold : No data available
pH value : 5.0 - 6.5
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 400 °C
Freezing point : No data available
Boiling point : 4000 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Non flammable.
Vapour pressure : No data available
Relative vapour density at 20°C : 4.8
Density : 2.52 g/cm3
Solubility : Water: 13.9 g/l at 20 °C
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : May cause fire or explosion; strong oxidiser.
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
May cause fire or explosion; strong oxidiser.
10.3 Possibility of hazardous reactions
Not established.
10.4 Conditions to avoid
Do not allow contact with water. Moisture. Direct sunlight.
10.5 Incompatible materials
Strong acids. Strong bases.
10.6 Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed.
Skin corrosion/irritation : Not classified
pH: 5.0 - 6.5
Additional information : Based on available data, the classification criteria are not met
Serious eye damage/irritation : Not classified
pH: 5.0 - 6.5
Additional information : Based on available data, the classification criteria are not met
Respiratory or skin sensitisation : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : Not classified
Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Reproductive toxicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : Not classified Additional information
Specific target organ toxicity (repeated exposure) : Not classified Additional information
Aspiration hazard : Not classified
Additional information : Based on available data, the classification criteria are not met
Potential adverse human health effects and symptoms : Harmful if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : Potassium perchlorate (7778-74-7) Persistence and degradability Not established.
12.3 Bioaccumulative potential
Bioaccumulative potential : Potassium perchlorate (7778-74-7) Bioaccumulative potential Not established.
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : Additional information : Avoid release to the environment

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to ...
Additional information : Hazardous waste due to potential risk of explosion.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1489
UN-No. (IMDG) : 1489
UN-No. (IATA) : 1489
UN-No. (ADN) : 1489
UN-No. (RID) : 1489
14.2. UN proper shipping name
Proper Shipping Name (ADR) : POTASSIUM PERCHLORATE
Proper Shipping Name (IMDG) : POTASSIUM PERCHLORATE
Proper Shipping Name (IATA) : POTASSIUM PERCHLORATE
Proper Shipping Name (ADN) : POTASSIUM PERCHLORATE
Proper Shipping Name (RID) : POTASSIUM PERCHLORATE
Transport document description (ADR) : UN 1489, POTASSIUM PERCHLORATE, 5.1, II
Transport document description (IMDG) : UN 1489, POTASSIUM PERCHLORATE, 5.1, II
Transport document description (IATA) : UN 1489, POTASSIUM PERCHLORATE, 5.1, II
Transport document description (ADN) : UN 1489, POTASSIUM PERCHLORATE, 5.1, II
Transport document description (RID) : UN 1489, POTASSIUM PERCHLORATE, 5.1, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 5.1
Danger labels : 5.1
IMDG
Transport hazard class(es) : 5.1
Danger labels : 5.1
IATA
Transport hazard class(es) : 5.1
Danger labels : 5.1
ADN
Transport hazard class(es) : 5.1
Danger labels : 5.1
RID
Transport hazard class(es) : 5.1
Danger labels : 5.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : O2
Limited quantities (ADR) : 1kg
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P002, IBC06
Mixed packing provisions (ADR) : MP2
Portable tank and bulk container
instructions (ADR)
: T3
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAV
Tank special provisions (ADR) : TU3
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR)
: V11
Special provisions for carriage - Bulk
(ADR)
: VC1, VC2, AP6, AP7
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV24
Special provisions for carriage - Operation
(ADR)
: S23
Hazard identification number (Kemler No.) : 50
Orange plates :
Tunnel restriction code (ADR)
:
E
EAC code
: 1Y
- Transport by sea
Limited quantities (IMDG)
:
1 kg
Excepted quantities (IMDG)
: E2
Packing instructions (IMDG)
: P002
IBC packing instructions (IMDG)
: IBC06
IBC special provisions (IMDG)
: B2
Tank instructions (IMDG)
: T3
Tank special provisions (IMDG)
: TP33
EmS-No. (Fire)
: F-H
EmS-No. (Spillage)
: S-Q
Stowage category (IMDG)
:
A
Segregation (IMDG)
: SG38, SG49
MFAG-No
: 140
- Air transport
PCA Excepted quantities (IATA)
: E2
PCA Limited quantities (IATA)
: Y544
PCA limited quantity max net quantity
(IATA)
: 2.5kg
PCA packing instructions (IATA)
: 558
PCA max net quantity (IATA)
: 5kg
CAO packing instructions (IATA)
: 562
CAO max net quantity (IATA)
: 25kg
ERG code (IATA)
: 5L
- Inland waterway transport
Classification code (ADN)
: O2
Limited quantities (ADN)
:
1 kg
Excepted quantities (ADN)
: E2
Equipment required (ADN)
: PP
Number of blue cones/lights (ADN)
:
0
- Rail transport
Classification code (RID)
: O2
Limited quantities (RID)
: 1kg
Excepted quantities (RID)
: E2
Packing instructions (RID)
: P002, IBC06
Mixed packing provisions (RID)
: MP2
Portable tank and bulk container
instructions (RID)
: T3
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID)
: SGAV
Special provisions for RID tanks (RID)
: TU3
Transport category (RID)
:
2
Special provisions for carriage
– Packages
(RID)
: W11
Special provisions for carriage
– Bulk
(RID)
: VC1, VC2, AP6, AP7
Special provisions for carriage
– Loading
and unloading (RID)
: CW24
Colis express (express parcels) (RID)
: CE10
Hazard identification number (RID)
: 50
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
Potassium perchlorate is not on the REACH Candidate List
Potassium perchlorate is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to
VwVwS, Annex 2; WGK No 169)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No chemical safety assessment has been carried out

SECTION 16: Other Information

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF
THE COUNCIL of 16 December 2008 on classification, labelling and packaging of
substances and mixturejs, am