SODIUM CHROMATE TETRAHYDRATE Extra Pure |
| Synonyms : Chromic acid disodium salt; Chromium disodium oxide; Rachromate |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | SODIUM CHROMATE (tetrahydrate) | ||
| Catalogue No. : | AL4114 | Product form : | Substance |
| CAS Number : | 10034-82-9 | EC Number : | 231-889-5 |
| Grade : | EC Index Number : | ||
| Chemical Formula : | HSN Code : | 28415010 | |
| Synonyms : | Chromic acid disodium salt; Chromium disodium oxide; Rachromate | ||
| Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Acute toxicity (oral), Category 3 H301 Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhal.), Category 2 H330 Skin corrosion/irritation, Category 1B H314 Sensitisation Respiratory, category 1 H334 Sensitisation Skin, category 1 H317 Germ cell mutagenicity, Category 1A H340 Carcinogenicity, Category 1A H350 Reproductive toxicity, H360FD Category 1B Specific target organ toxicity Repeated exposure, Category 1 H372 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of classification categories and H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Carc.Cat.1; R45 Muta.Cat.1; R46 Repr.Cat.1; R60 Repr.Cat.1; R61 T+; R26 T; R25 T; R48/23 Xn; R21 R42 C; R34 R43 N; R50/53 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS05
 GHS06
 GHS08
 GHS09
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H301 - Toxic if swallowed H312 - Harmful in contact with skin H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction H330 - Fatal if inhaled H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H340 - May cause genetic defects H350 - May cause cancer H360FD - May damage fertility. May damage the unborn child H372 - Causes damage to organs through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects |
| Precautionary statements (CLP) : | P201 - Obtain special instructions before use P260 - Do not breathe dust/fume/gas/mist/vapours/spray P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P284 - [In case of inadequate ventilation] wear respiratory protection P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician |
2.3 Other hazards |
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| Other hazards : | This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | SODIUM CHROMATE TETRAHYDRATE EXTRA PURE | ||
| CAS No. : | 10034-82-9 | ||
| EC No. : | 231-889-5 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. |
| First-aid measures after skin contact : | Immediately call a POISON CENTER or doctor/physician. Specific measures (see ... on this label). Wash with plenty of soap and water. Wash contaminated clothing before reuse. Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see ... on this label). |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. |
| First-aid measures after ingestion : | Rinse mouth. Immediately call a POISON CENTER or doctor/physician. Specific treatment (see ... on this label). Do NOT induce vomiting. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/injuries : Causes severe skin burns and eye damage. May cause genetic defects. May cause cancer. May damage fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. Symptoms/injuries after inhalation : Fatal if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/injuries after skin contact : Harmful in contact with skin. May cause an allergic skin reaction. Symptoms/injuries after ingestion : Toxic if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | No additional information available |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Stop release. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Clear up rapidly by scoop or vacuum. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Technical measures : | Comply with applicable regulations. |
| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or face shield |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | In case of inadequate ventilation wear respiratory protection |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Solid Colour |
| Colour : | Lemon yellow. |
| Odour : | odourless. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | No data available |
| Freezing point : | No data available |
| Boiling point : | No data available |
| Flash point : | No data available |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | No data available |
| Density : | 2.723 g/cm3 |
| Solubility : | Water: Soluble in cold water |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| Thermal decomposition generates : Corrosive vapours. | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Direct sunlight. Air contact. Moisture. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| Thermal decomposition generates : Corrosive vapours. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Oral: Toxic if swallowed. Dermal: Harmful in contact with skin. Inhalation: Fatal if inhaled. |
| Skin corrosion/irritation : | Causes severe skin burns and eye damage. |
| Serious eye damage/irritation : | Serious eye damage, category 1, implicit |
| Respiratory or skin sensitisation : | May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. |
| Germ cell mutagenicity : | May cause genetic defects. |
| Carcinogenicity : | May cause cancer. |
| Reproductive toxicity : | May damage fertility. May damage the unborn child. |
| Specific target organ toxicity (single exposure) : | Not classified |
| Specific target organ toxicity (repeated exposure) : | Causes damage to organs through prolonged or repeated exposure. |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Harmful in contact with skin. Toxic if swallowed. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | Ecology - water : Very toxic to aquatic life with long lasting effects. |
12.2 Persistence - degradability |
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| Persistence - degradability : | SODIUM CHROMATE TETRAHYDRATE EXTRA PURE (10034-82-9) Persistence and degradability May cause long-term adverse effects in the environment. |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| SODIUM CHROMATE TETRAHYDRATE EXTRA PURE (10034-82-9) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII |
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12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
| Ecology - waste materials : | Hazardous waste due to toxicity. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 3288 |
| UN-No. (IMDG) : | 3288 |
| UN-No. (IATA) : | 3288 |
| UN-No. (ADN) : | 3288 |
| UN-No. (RID) : | 3288 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | TOXIC SOLID, INORGANIC, N.O.S. |
| Proper Shipping Name (IMDG) : | TOXIC SOLID, INORGANIC, N.O.S. |
| Proper Shipping Name (IATA) : | TOXIC SOLID, INORGANIC, N.O.S. |
| Proper Shipping Name (ADN) : | TOXIC SOLID, INORGANIC, N.O.S. |
| Proper Shipping Name (RID) : | TOXIC SOLID, INORGANIC, N.O.S. |
| Transport document description (ADR) : | UN 3288, TOXIC SOLID, INORGANIC, N.O.S., 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 3288, TOXIC SOLID, INORGANIC, N.O.S., 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 3288, TOXIC SOLID, INORGANIC, N.O.S., 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 3288, TOXIC SOLID, INORGANIC, N.O.S., 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 3288, TOXIC SOLID, INORGANIC, N.O.S., 6.1, II ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1 
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| IMDG | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| IATA | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| ADN | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| RID | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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14.4. Packing group |
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| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
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| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : T5 Special provision (ADR) : 274 Limited quantities (ADR) : 500g Excepted quantities (ADR) : E4 Packing instructions (ADR) : P002, IBC08 Special packing provisions (ADR) : B4 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAH, L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V11 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S19 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 2X |
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| - Transport by sea | |
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Special provision (IMDG) : 274 Limited quantities (IMDG) : 500 g Excepted quantities (IMDG) : E4 Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B2, B4 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : B MFAG-No : 151 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y644 PCA limited quantity max net quantity (IATA) : 1kg PCA packing instructions (IATA) : 669 PCA max net quantity (IATA) : 25kg CAO packing instructions (IATA) : 676 CAO max net quantity (IATA) : 100kg Special provision (IATA) : A3, A5 ERG code (IATA) : 6L |
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| - Inland waterway transport | |
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Classification code (ADN) : T5 Special provisions (ADN) : 274, 802 Limited quantities (ADN) : 500 g Excepted quantities (ADN) : E4 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 2 |
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| - Rail transport | |
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Classification code (RID) : T5 Special provision (RID) : 274 Limited quantities (RID) : 500g Excepted quantities (RID) : E4 Packing instructions (RID) : P002, IBC08 Special packing provisions (RID) : B4 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAH, L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W11 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE9 Hazard identification number (RID) : 60 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions Sodium chromate is on the REACH Candidate List Sodium chromate is on the REACH Annex XIV List: Authorisation number Sunset date REACH authorization exemptions 21/09/2017 |
| 15.1.2. National regulations |
| Germany |
| AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (KBwS-Beschluss; WGK No 1032) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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