SODIUM NITRITE Extra Pure

SODIUM NITRITE Extra Pure

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : SODIUM NITRITE Extra Pure
Catalogue No. : AL4215 Product form : Substance
CAS Number : 7632-00-0 EC Number : 231-555-9
Grade : EC Index Number : 007-010-00-4
Chemical Formula : HSN Code : 28342990
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids,
Category 2
H272
Acute toxicity (oral),
Category 3
H301
Hazardous to the aquatic
environment Acute
Hazard, Category 1
H400
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
O; R8
T; R25
N; R50
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS03GHS03 GHS06GHS06 GHS09GHS09
Signal word (CLP) : Danger
Hazard statements (CLP) : H272 - May intensify fire; oxidiser
H301 - Toxic if swallowed
H400 - Very toxic to aquatic life
Precautionary statements (CLP) : P220 - Keep/Store away from clothing/¦/combustible materials
P273 - Avoid release to the environment
P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or
doctor/physician
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : SODIUM NITRITE EXTRA PURE
CAS No. : 7632-00-0
EC Index No. : 007-010-00-4
EC No. : 231-555-9
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of
water before removing clothes.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Obtain emergency medical attention. Immediately call a POISON
CENTER or doctor/physician. Specific treatment (see ... on this label).
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard : May cause fire or explosion; strong oxidiser.
Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing
risk of burns and injuries.
5.3 Advice for firefighters
Protection during firefighting : No additional information available

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Very toxic to aquatic life.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Hazardous waste due to potential risk of explosion.
Precautions for safe handling : Take any precaution to avoid mixing with combustibles/...
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Storage conditions : Keep in fireproof place. Store in original container. Store in a dry place. Protect from
moisture.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 69 g/mol
Colour : Pale yellow crystals.
Odour : odourless.
Odour threshold : No data available
pH value : 9
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 271 °C
Freezing point : No data available
Boiling point : 320 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 2.168 g/cm3
Solubility : Water: 820 g/l at 20 °C
Log Pow : 3.7
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : The substance or mixture is classified as oxidizin
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
May cause fire or explosion; strong oxidiser.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Heat. Sparks. Overheating. Open flame.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Toxic if swallowed.
Skin corrosion/irritation : Not classified
pH: 9
Serious eye damage/irritation : Not classified
pH: 9
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Toxic if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : SODIUM NITRITE EXTRA PURE (7632-00-0) Log Pow 3.7
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...
Additional information : Hazardous waste due to potential risk of explosion.
Ecology - waste materials : Hazardous waste due to toxicity.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1500
UN-No. (IMDG) : 1500
UN-No. (IATA) : 1500
UN-No. (ADN) : 1500
UN-No. (RID) : 1500
14.2. UN proper shipping name
Proper Shipping Name (ADR) : SODIUM NITRITE
Proper Shipping Name (IMDG) : SODIUM NITRITE
Proper Shipping Name (IATA) : SODIUM NITRITE
Proper Shipping Name (ADN) : SODIUM NITRITE
Proper Shipping Name (RID) : SODIUM NITRITE
Transport document description (ADR) : UN 1500, SODIUM NITRITE, 5.1 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 1500, SODIUM NITRITE, 5.1 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 1500, SODIUM NITRITE, 5.1 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 1500, SODIUM NITRITE, 5.1 (6.1), III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 1500, SODIUM NITRITE, 5.1 (6.1), III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 5.1 (6.1)
Danger labels : 5.1, 6.1
IMDG
Transport hazard class(es) : 5.1 (6.1)
Danger labels : 5.1, 6.1
IATA
Transport hazard class(es) : 5.1 (6.1)
Danger labels : 5.1, 6.1
ADN
Transport hazard class(es) : 5.1 (6.1)
Danger labels : 5.1, 6.1
RID
Transport hazard class(es) : 5.1 (6.1)
Danger labels : 5.1, 6.1
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : OT2
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, R001
Special packing provisions (ADR) : B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T1
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAN
Tank special provisions (ADR) : TU3
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV24, CV28
Hazard identification number (Kemler No.) : 56
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 1Z
- Transport by sea
Limited quantities (IMDG) : 5 kg
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-Q
Stowage category (IMDG) : A
Segregation (IMDG) : SG38, SG49
MFAG-No : 140
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y546
PCA limited quantity max net quantity
(IATA)
: 10kg
PCA packing instructions (IATA) : 559
PCA max net quantity (IATA) : 25kg
CAO packing instructions (IATA) : 563
CAO max net quantity (IATA) : 100kg
ERG code (IATA) : 5P
- Inland waterway transport
Classification code (ADN) : OT2
Special provisions (ADN) : 802
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : OT2
Limited quantities (RID) : 5kg
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, R001
Special packing provisions (RID) : B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T1
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAN
Special provisions for RID tanks (RID) : TU3
Transport category (RID) : 3
Special provisions for carriage – Loading
and unloading (RID)
: CW24, CW28
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 56
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
SODIUM NITRITE EXTRA PURE is not on the REACH Candidate List
SODIUM NITRITE EXTRA PURE is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to
VwVwS, Annex 2; WGK No 161)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Ox. Sol. 2 Oxidising Solids, Category 2
H272 May intensify fire; oxidiser
H301 Toxic if swallowed
H400 Very toxic to aquatic life
R25 Toxic if swallowed
R50 Very toxic to aquatic organisms
R8 Contact with combustible material may cause fire
N Dangerous for the environment
O Oxidising
T Toxic