SODIUM METAPERIODATE AR/ACS

SODIUM METAPERIODATE AR/ACS

Synonyms : Sodium periodate

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : SODIUM METAPERIODATE AR
Catalogue No. : AL4199 Product form : Substance
CAS Number : 7990-28-5 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 28299030
Synonyms : Sodium periodate
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids,
Category 1
H271
Skin corrosion/irritation,
Category 1
H314
Specific target organ
toxicity Repeated
exposure, Category 1
H372
Hazardous to the aquatic
environment Acute
Hazard, Category 1
H400
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
O; R8
Xn; R22
Xi; R36/37/38
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS03GHS03 GHS05GHS05 GHS08GHS08 GHS09GHS09
Signal word (CLP) : Danger
Hazard statements (CLP) : H271 - May cause fire or explosion; strong oxidiser.
H314 - Causes severe skin burns and eye damage.
H372 - Causes damage to organs through prolonged or repeated exposure.
H400 - Very toxic to aquatic life.
Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P371+P380+P375 - In case of major fire and large quantities: Evacuate area. Fight
fire remotely due to the risk of explosion.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : SODIUM (META) PERIODATE AR/ACS
CAS No. : 7990-28-5
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER/doctor if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : Causes severe skin burns and eye damage. Causes damage to organs through
prolonged or repeated exposure.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Dry powder.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard : May cause fire or explosion; strong oxidiser.
Explosion hazard : Heating may cause a fire or explosion.
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Very toxic to aquatic life.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Do not breathe dust. Avoid contact with skin and eyes.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 213.89 g/mol
Colour : White crystalline.
Odour : odourless.
Odour threshold : No data available
pH value : 3.5 - 5.5
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 300 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 3.8 g/cm3
Solubility : Water: 107 g/l at 20 °C - completely soluble
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : The substance or mixture is classified as oxidizin
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
May cause fire or explosion; strong oxidiser.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Moisture. Air contact. Overheating. Open flame. Heat.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 3.5 - 5.5
Serious eye damage/irritation : Serious eye damage, category 1, implicit
pH: 3.5 - 5.5
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3085
UN-No. (IMDG) : 3085
UN-No. (IATA) : 3085
UN-No. (ADN) : 3085
UN-No. (RID) : 3085
14.2. UN proper shipping name
Proper Shipping Name (ADR) : OXIDIZING SOLID, CORROSIVE, N.O.S.
Proper Shipping Name (IMDG) : OXIDIZING SOLID, CORROSIVE, N.O.S.
Proper Shipping Name (IATA) : OXIDIZING SOLID, CORROSIVE, N.O.S.
Proper Shipping Name (ADN) : OXIDIZING SOLID, CORROSIVE, N.O.S.
Proper Shipping Name (RID) : OXIDIZING SOLID, CORROSIVE, N.O.S.
Transport document description (ADR) : UN 3085, OXIDIZING SOLID, CORROSIVE, N.O.S., 5.1 (8), I ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 3085, OXIDIZING SOLID, CORROSIVE, N.O.S., 5.1 (8), I ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 3085, OXIDIZING SOLID, CORROSIVE, N.O.S., 5.1 (8), I ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 3085, OXIDIZING SOLID, CORROSIVE, N.O.S., 5.1 (8), I ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 3085, OXIDIZING SOLID, CORROSIVE, N.O.S., 5.1 (8), I ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 5.1 (8)
Danger labels : 5.1, 8
IMDG
Transport hazard class(es) : 5.1 (8)
Danger labels : 5.1, 8
IATA
Transport hazard class(es) : 5.1 (8)
Danger labels : 5.1, 8
ADN
Transport hazard class(es) : 5.1 (8)
Danger labels : 5.1, 8
RID
Transport hazard class(es) : 5.1 (8)
Danger labels : 5.1, 8
14.4. Packing group
Packing group (ADR) : I
Packing group (IMDG) : I
Packing group (IATA) : I
Packing group (ADN) : I
Packing group (RID) : I
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : OC2
Special provisions (ADR) : 274
Limited quantities (ADR) : 0
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P503
Mixed packing provisions (ADR) : MP2
Transport category (ADR) : 1
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV24
Special provisions for carriage - Operation
(ADR)
: S20
Tunnel restriction code (ADR) : E
EAC code : 1W
- Transport by sea
Special provisions (IMDG) : 274
Packing instructions (IMDG) : P503
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-Q
Stowage category (IMDG) : D
Stowage and handling (IMDG) : H1
Segregation (IMDG) : SG38, SG49, SG60
Properties and observations (IMDG) : Causes burns to skin, eyes and mucous membranes.Particular care in handling
should be exercised if packages have become wetted.
MFAG-No : 141
- Air transport
PCA Excepted quantities (IATA) : E0
PCA Limited quantities (IATA) : Forbidden
PCA limited quantity max net quantity
(IATA)
: Forbidden
PCA packing instructions (IATA) : 557
PCA max net quantity (IATA) : 1kg
CAO packing instructions (IATA) : 561
CAO max net quantity (IATA) : 15kg
Special provisions (IATA) : A3, A803
ERG code (IATA) : 5C
- Inland waterway transport
Classification code (ADN) : OC2
Special provisions (ADN) : 274
Limited quantities (ADN) : 0
Excepted quantities (ADN) : E0
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : OC2
Special provisions (RID) : 274
Limited quantities (RID) : 0
Excepted quantities (RID) : E0
Packing instructions (RID) : P503
Mixed packing provisions (RID) : MP2
Transport category (RID) : 1
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW24
Hazard identification number (RID) : 558
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
SODIUM (META) PERIODATE AR/ACS is not on the REACH Candidate List
SODIUM (META) PERIODATE AR/ACS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Ox. Sol. 1 Oxidising Solids, Category 1
Skin Corr. 1 Skin corrosion/irritation, Category 1
STOT RE 1 Specific target organ toxicity — Repeated exposure, Category 1
H271 May cause fire or explosion; strong oxidiser.
H314 Causes severe skin burns and eye damage.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
R22 Harmful if swallowed
R36/37/38 Irritating to eyes, respiratory system and skin
R8 Contact with combustible material may cause fire
O Oxidising
Xi Irritant
Xn Harmful