SODIUM SULPHIDE FLAKES (IRON FREE) Extra Pure |
| Synonyms : |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | SODIUM SULPHIDE flakes | ||
| Catalogue No. : | AL4279 | Product form : | Substance |
| CAS Number : | 27610-45-3 | EC Number : | |
| Grade : | EC Index Number : | ||
| Chemical Formula : | HSN Code : | 28301000 | |
| Synonyms : | |||
| Chemical Structure : |
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| Laboratory chemicals : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Industrial For professional use only | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Corrosive to metals, Category 1 H290 Acute toxicity (oral), Category 3 H301 Skin corrosion/irritation, Category 1B H314 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Xn; R22 C; R34 N; R50 R31 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS05
 GHS06
 GHS09
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H290 - May be corrosive to metals. H301 - Toxic if swallowed. H314 - Causes severe skin burns and eye damage. H400 - Very toxic to aquatic life. |
| Precautionary statements (CLP) : | P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | SODIUM SULPHIDE FLAKES (IRON FREE) EXTRA PURE | ||
| CAS No. : | 27610-45-3 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. |
| First-aid measures after skin contact : | Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
| First-aid measures after ingestion : | Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after ingestion : Toxic if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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| Very toxic to aquatic life. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Clear up rapidly by scoop or vacuum. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Do not breathe dust/fume/gas/mist/vapours/spray. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing before reuse. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Technical measures : | Comply with applicable regulations. |
| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or face shield |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Solid |
| Molecular mass : | 78.04 g/mol |
| Colour : | Yellow. |
| Odour : | No data available |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | No data available |
| Freezing point : | No data available |
| Boiling point : | No data available |
| Flash point : | No data available |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | No data available |
| Density : | 1.86 g/cm3 |
| Solubility : | Water: Soluble in water |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| May be corrosive to metals. | |
10.2 Chemical stability |
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| Stable under normal conditions of use. | |
10.3 Possibility of hazardous reactions |
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| Highly reactive material. Contact with acids liberates toxic gas. | |
10.4 Conditions to avoid |
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| Direct sunlight. Air contact. Finely divided metals. Sparks. Heat. Open flame. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| Thermal decomposition generates : Corrosive vapours. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Oral: Toxic if swallowed. |
| Skin corrosion/irritation : | Causes severe skin burns and eye damage. |
| Serious eye damage/irritation : | Serious eye damage, category 1, implicit |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| STOT-single exposure : | Not classified |
| STOT-repeated exposure : | Not classified |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | Ecology - water : Very toxic to aquatic life. |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1849 |
| UN-No. (IMDG) : | 1849 |
| UN-No. (IATA) : | 1849 |
| UN-No. (ADN) : | 1849 |
| UN-No. (RID) : | 1849 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | SODIUM SULPHIDE, HYDRATED |
| Proper Shipping Name (IMDG) : | SODIUM SULPHIDE, HYDRATED |
| Proper Shipping Name (IATA) : | SODIUM SULPHIDE, HYDRATED |
| Proper Shipping Name (ADN) : | SODIUM SULPHIDE, HYDRATED |
| Proper Shipping Name (RID) : | SODIUM SULPHIDE, HYDRATED |
| Transport document description (ADR) : | UN 1849, SODIUM SULPHIDE, HYDRATED, 8, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 1849, SODIUM SULPHIDE, HYDRATED, 8, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 1849, SODIUM SULPHIDE, HYDRATED, 8, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 1849, SODIUM SULPHIDE, HYDRATED, 8, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 1849, SODIUM SULPHIDE, HYDRATED, 8, II ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8 
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| IMDG | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| IATA | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| ADN | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| RID | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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14.4. Packing group |
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| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
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| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : C6 Special provisions (ADR) : 523 Limited quantities (ADR) : 1kg Excepted quantities (ADR) : E2 Packing instructions (ADR) : P002, IBC08 Special packing provisions (ADR) : B4 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAN, L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V11 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X |
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| - Transport by sea | |
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Limited quantities (IMDG) : 1 kg Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B2, B4 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : A Segregation (IMDG) : SG35 MFAG-No : 153 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y844 PCA limited quantity max net quantity (IATA) : 5kg PCA packing instructions (IATA) : 859 PCA max net quantity (IATA) : 15kg CAO packing instructions (IATA) : 863 CAO max net quantity (IATA) : 50kg ERG code (IATA) : 8L |
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| - Inland waterway transport | |
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Classification code (ADN) : C6 Special provisions (ADN) : 523 Limited quantities (ADN) : 1 kg Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : C6 Special provisions (RID) : 523 Limited quantities (RID) : 1kg Excepted quantities (RID) : E2 Packing instructions (RID) : P002, IBC08 Special packing provisions (RID) : B4 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAN, L4BN Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W11 Colis express (express parcels) (RID) : CE10 Hazard identification number (RID) : 80 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions SODIUM SULPHIDE FLAKES (IRON FREE) EXTRA PURE is not on the REACH Candidate List SODIUM SULPHIDE FLAKES (IRON FREE) EXTRA PURE is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen-Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen-Ontwikkeling : The substance is not listed |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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