SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	BRONOPOL (for synthesis) (2-bromo-2-nitropropane-1,3-diol)
Catalogue No. :	AL0901	Product form :	Substance
CAS Number :	52-51-7	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	29053990
Synonyms :	Bronopol
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), Category 4 H302 Acute toxicity (dermal), Category 4 H312 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 1 H318 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R21/22 Xi; R41 Xi; R37/38 N; R50 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS05 GHS07 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H302+H312 - Harmful if swallowed or in contact with skin H315 - Causes skin irritation. H318 - Causes serious eye damage. H335 - May cause respiratory irritation. H400 - Very toxic to aquatic life.
Precautionary statements (CLP) :	P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
CAS No. :		52-51-7
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after inhalation : May cause respiratory irritation. Symptoms/effects after skin contact : Harmful in contact with skin. Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye damage. Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Avoid contact with skin, eyes and clothing.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
6.2 Environmental precautions
Very toxic to aquatic life.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Clean contaminated surfaces with an excess of water.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin and eyes.
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid Appearance : Crystals.
Molecular mass :	199.99 g/mol
Colour :	Almost White.
Odour :	No data available
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	130 - 133 °C
Freezing point :	No data available
Boiling point :	No data available
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Solubility :	Water: 0.1 g/ml
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed. Dermal: Harmful in contact with skin.
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye damage.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	May cause respiratory irritation.
STOT-repeated exposure :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info :	No additional information available

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	3241
UN-No. (IMDG) :	3241
UN-No. (IATA) :	3241
UN-No. (ADN) :	3241
UN-No. (RID) :	3241
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	2-BROMO-2-NITROPROPANE-1,3-DIOL
Proper Shipping Name (IMDG) :	2-BROMO-2-NITROPROPANE-1,3-DIOL
Proper Shipping Name (IATA) :	2-BROMO-2-NITROPROPANE-1,3-DIOL
Proper Shipping Name (ADN) :	2-BROMO-2-NITROPROPANE-1,3-DIOL
Proper Shipping Name (RID) :	2-BROMO-2-NITROPROPANE-1,3-DIOL
Transport document description (ADR) :	UN 3241, 2-BROMO-2-NITROPROPANE-1,3-DIOL, 4.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 3241, 2-BROMO-2-NITROPROPANE-1,3-DIOL, 4.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 3241, 2-BROMO-2-NITROPROPANE-1,3-DIOL, 4.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 3241, 2-BROMO-2-NITROPROPANE-1,3-DIOL, 4.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 3241, 2-BROMO-2-NITROPROPANE-1,3-DIOL, 4.1, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	4.1
Danger labels :	4.1
IMDG
Transport hazard class(es) :	4.1
Danger labels :	4.1
IATA
Transport hazard class(es) :	4.1
Danger labels :	4.1
ADN
Transport hazard class(es) :	4.1
Danger labels :	4.1
RID
Transport hazard class(es) :	4.1
Danger labels :	4.1
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : SR1 Special provisions (ADR) : 638 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P520, IBC08 Special packing provisions (ADR) : PP22, B3 Mixed packing provisions (ADR) : MP2 Transport category (ADR) : 3 Special provisions for carriage - Loading, unloading and handling (ADR) : CV14 Special provisions for carriage - Operation (ADR) : S24 Tunnel restriction code (ADR) : D EAC code : 1Y
- Transport by sea
Packing instructions (IMDG) : P520 Special packing provisions (IMDG) : PP22 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 EmS-No. (Fire) : F-J EmS-No. (Spillage) : S-G Stowage category (IMDG) : C Stowage and handling (IMDG) : SW1, SW2, H2, H3 Properties and observations (IMDG) : White crystals. Soluble in water.Decomposes when heated, evolving toxic gases. Sensitive to strong detonation shock. This substance shall be packed in accordance with packing method OP6 (see applicable packing instruction).
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y457 PCA limited quantity max net quantity (IATA) : 10kg PCA packing instructions (IATA) : 457 PCA max net quantity (IATA) : 25kg CAO packing instructions (IATA) : 457 CAO max net quantity (IATA) : 50kg Special provisions (IATA) : A20, A802 ERG code (IATA) : 3L
- Inland waterway transport
Classification code (ADN) : SR1 Special provisions (ADN) : 638 Limited quantities (ADN) : 5 kg Excepted quantities (ADN) : E1 Equipment required (ADN) : PP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : SR1 Special provisions (RID) : 638 Excepted quantities (RID) : E1 Packing instructions (RID) : P520, IBC08 Special packing provisions (RID) : PP22, B3 Mixed packing provisions (RID) : MP2 Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W1 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 40
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions 2-BROMO-2-NITRO-1,3-PROPANEDIOL Extra Pure is not on the REACH Candidate List 2-BROMO-2-NITRO-1,3-PROPANEDIOL Extra Pure is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, Significantly hazardous to water (Classification according to AwSV; ID No. 5204) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. R21/22 Harmful in contact with skin and if swallowed R37/38 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R50 Very toxic to aquatic organisms N Dangerous for the environment Xi Irritant Xn Harmful