1,4 - DIAZABICYCLO (2.2.2) OCTANE For Synthesis

1,4 - DIAZABICYCLO (2.2.2) OCTANE For Synthesis

Synonyms : DABCO, TED, Triethylenediamine

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : 1,4-DIAZABICYCLO (2.2.2) OCTANE (DABCO, TED, Triethylenediamine)
Catalogue No. : AL1663 Product form : Substance
CAS Number : 280-57-9 EC Number : 205-999-9
Grade : EC Index Number :
Chemical Formula : C6H12N2 HSN Code : 29335990
Synonyms : DABCO,TED,Triethylenediamine
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable solids,
Category 1
H228
Acute toxicity (oral),
Category 4
H302
Serious eye damage/eye
irritation, Category 2
H319
Skin corrosion/irritation,
Category 2
H315
Specific target organ
toxicity Single
exposure, Category 3,
Respiratory tract irritation
H335
Hazardous to the aquatic
environment Chronic
Hazard, Category 3
H412
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; R11
Xn; R22
Xi; R36/37/38
R52/53
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02 GHS07GHS07
Signal word (CLP) : Danger
Hazard statements (CLP) : H228 - Flammable solid.
H302 - Harmful if swallowed.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H335 - May cause respiratory irritation.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P261 - Avoid breathing vapours, spray, dust, fume, gas.
P273 - Avoid release to the environment.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : 1,4 - DIAZABICYCLO (2.2.2) OCTANE For Synthesis
CAS No. : 280-57-9
EC No. : 205-999-9
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Wash with plenty of water/…. Wash contaminated clothing before reuse. Get
medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER/doctor if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard : Flammable solid.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open
flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as
possible. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Avoid contact with skin and eyes. Keep away from sources of ignition - No smoking. Use only outdoors or in a well-ventilated area. Do not breathe vapours. Take precautionary measures against static discharge.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment.
Storage conditions : Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 112.17 g/mol
Colour : White.
Odour : ammonia like.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 155 - 160 °C
Freezing point : No data available
Boiling point : 174 °C
Flash point : 62 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable solid.
Vapour pressure : 3.9 hPa at 50°C
Relative vapour density at 20°C : 3.86
Density : 1.02 g/cm3 at 25°C
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed.
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : May cause respiratory irritation.
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Harmful to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability : 1,4 - DIAZABICYCLO (2.2.2) OCTANE For Synthesis (280-57-9) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1325
UN-No. (IMDG) : 1325
UN-No. (IATA) : 1325
UN-No. (ADN) : 1325
UN-No. (RID) : 1325
14.2. UN proper shipping name
Proper Shipping Name (ADR) : FLAMMABLE SOLID, ORGANIC, N.O.S.
Proper Shipping Name (IMDG) : FLAMMABLE SOLID, ORGANIC, N.O.S.
Proper Shipping Name (IATA) : FLAMMABLE SOLID, ORGANIC, N.O.S.
Proper Shipping Name (ADN) : FLAMMABLE SOLID, ORGANIC, N.O.S.
Proper Shipping Name (RID) : FLAMMABLE SOLID, ORGANIC, N.O.S.
Transport document description (ADR) : UN 1325, FLAMMABLE SOLID, ORGANIC, N.O.S., 4.1, II
Transport document description (IMDG) : UN 1325, FLAMMABLE SOLID, ORGANIC, N.O.S., 4.1, II
Transport document description (IATA) : UN 1325, FLAMMABLE SOLID, ORGANIC, N.O.S., 4.1, II
Transport document description (ADN) : UN 1325, FLAMMABLE SOLID, ORGANIC, N.O.S., 4.1, II
Transport document description (RID) : UN 1325, FLAMMABLE SOLID, ORGANIC, N.O.S., 4.1, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 4.1
Danger labels : 4.1
IMDG
Transport hazard class(es) : 4.1
Danger labels : 4.1
IATA
Transport hazard class(es) : 4.1
Danger labels : 4.1
ADN
Transport hazard class(es) : 4.1
Danger labels : 4.1
RID
Transport hazard class(es) : 4.1
Danger labels : 4.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F1
Special provisions (ADR) : 274
Limited quantities (ADR) : 1kg
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T3
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAN
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR)
: V11
Hazard identification number (Kemler No.) : 40
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 1Z
- Transport by sea
Special provisions (IMDG) : 274, 915
Limited quantities (IMDG) : 1 kg
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B21, B4
Tank instructions (IMDG) : T3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-G
Stowage category (IMDG) : B
MFAG-No : 133
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y441
PCA limited quantity max net quantity
(IATA)
: 5kg
PCA packing instructions (IATA) : 445
PCA max net quantity (IATA) : 15kg
CAO packing instructions (IATA) : 448
CAO max net quantity (IATA) : 50kg
Special provisions (IATA) : A3, A803
ERG code (IATA) : 3L
- Inland waterway transport
Classification code (ADN) : F1
Special provisions (ADN) : 274
Limited quantities (ADN) : 1 kg
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP
Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : F1
Special provisions (RID) : 274
Excepted quantities (RID) : E2
Packing instructions (RID) : P002, IBC08
Special packing provisions (RID) : B4
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T3
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAN
Transport category (RID) : 2
Special provisions for carriage – Packages
(RID)
: W1
Colis express (express parcels) (RID) : CE10
Hazard identification number (RID) : 40
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
1,4 - DIAZABICYCLO (2.2.2) OCTANE For Synthesis is not on the REACH Candidate List
1,4 - DIAZABICYCLO (2.2.2) OCTANE For Synthesis is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV;
ID No. 4678)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Class for fire hazard : Class III-1
Store unit : 50 liter
Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management
guidelines for the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Flam. Sol. 1 Flammable solids, Category 1
Skin Irrit. 2 Skin corrosion/irritation, Category 2
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation
H228 Flammable solid.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.
R11 Highly flammable
R22 Harmful if swallowed
R36/37/38 Irritating to eyes, respiratory system and skin
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
F Highly flammable
Xi Irritant
Xn Harmful