SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	2,2,2-TRIFLUOROETHANOL
Catalogue No. :	AL4665	Product form :	Substance
CAS Number :	75-89-8	EC Number :	200-913-6
Grade :		EC Index Number :
Chemical Formula :	CF3CH2OH	HSN Code :	29055900
Synonyms :	Trifluoroethyl Alcohol
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), Category 3 H301 Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhal.), Category 3 H331 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 1 H318 Specific target organ toxicity Single exposure, Category 3, H335 Respiratory tract irritation Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R20/21/22 Xi; R41 Xi; R37/38 R10 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS05 GHS06
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H301+H331 - Toxic if swallowed or if inhaled H312 - Harmful in contact with skin. H315 - Causes skin irritation. H318 - Causes serious eye damage. H335 - May cause respiratory irritation.
Precautionary statements (CLP) :	P261 - Avoid breathing vapours, dust, fume, gas. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P301+P310 - IF SWALLOWED: Immediately call a doctor. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P311 - Call a doctor.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
CAS No. :		75-89-8
EC No. :		200-913-6
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact :	Wash with plenty of water/…. Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER/doctor if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after inhalation : May cause respiratory irritation. Symptoms/effects after skin contact : Harmful in contact with skin. Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye damage. Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Flammable solid.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	Keep away from sources of ignition - No smoking. Avoid contact with skin and eyes. Use only outdoors or in a well-ventilated area. Do not breathe vapours.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	100.04 g/mol
Colour :	Clear Colorless.
Odour :	alcoholic odour.
Odour threshold :	No data available
pH value :	5 - 7 (10% aq soln)
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-44 °C
Freezing point :	No data available
Boiling point :	73 - 75 °C
Flash point :	29 °C
Auto-ignition temperature :	480 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable Flammable solid.
Vapour pressure :	93 hPa at 20 °C
Relative vapour density at 20°C :	3.45
Density :	1.39 g/cm3
Solubility :	Water: Soluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	1.75 cP @ 20°C
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.055 - 0.42 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Toxic if swallowed. Dermal: Harmful in contact with skin. Inhalation: Toxic if inhaled.
Skin corrosion/irritation :	Causes skin irritation. pH: 5 - 7 (10% aq soln)
Serious eye damage/irritation :	Causes serious eye damage. pH: 5 - 7 (10% aq soln)
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	May cause respiratory irritation.
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified 2,2,2-TRIFLUOROETHANOL FOR SYNTHESIS (75-89-8) Viscosity, kinematic 1.259 mm²/s
Potential adverse human health effects and symptoms :	Harmful if swallowed. Harmful in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1986
UN-No. (IMDG) :	1986
UN-No. (IATA) :	1986
UN-No. (ADN) :	1986
UN-No. (RID) :	1986
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ALCOHOLS, FLAMMABLE, TOXIC, N.O.S.
Proper Shipping Name (IMDG) :	ALCOHOLS, FLAMMABLE, TOXIC, N.O.S.
Proper Shipping Name (IATA) :	ALCOHOLS, FLAMMABLE, TOXIC, N.O.S.
Proper Shipping Name (ADN) :	ALCOHOLS, FLAMMABLE, TOXIC, N.O.S.
Proper Shipping Name (RID) :	ALCOHOLS, FLAMMABLE, TOXIC, N.O.S.
Transport document description (ADR) :	UN 1986, ALCOHOLS, FLAMMABLE, TOXIC, N.O.S., 3 (6.1), III
Transport document description (IMDG) :	UN 1986, ALCOHOLS, FLAMMABLE, TOXIC, N.O.S., 3 (6.1), III
Transport document description (IATA) :	UN 1986, ALCOHOLS, FLAMMABLE, TOXIC, N.O.S., 3 (6.1), III
Transport document description (ADN) :	UN 1986, ALCOHOLS, FLAMMABLE, TOXIC, N.O.S., 3 (6.1), III
Transport document description (RID) :	UN 1986, ALCOHOLS, FLAMMABLE, TOXIC, N.O.S., 3 (6.1), III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
IMDG
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
IATA
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
ADN
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
RID
Transport hazard class(es) :	3 (6.1)
Danger labels :	3, 6.1
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : FT1 Special provisions (ADR) : 274 Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP1, TP28 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15 Vehicle for tank carriage : FL Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2 Hazard identification number (Kemler No.) : 36 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •3WE APP code : A(fl)
- Transport by sea
Special provisions (IMDG) : 223, 274 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP1, TP28 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : A Properties and observations (IMDG) : Toxic if swallowed, by skin contact or by inhalation. MFAG-No : 131
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y343 PCA limited quantity max net quantity (IATA) : 2L PCA packing instructions (IATA) : 355 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 366 CAO max net quantity (IATA) : 220L Special provisions (IATA) : A3 ERG code (IATA) : 3P
- Inland waterway transport
Classification code (ADN) : FT1 Special provisions (ADN) : 274, 802 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, TOX, A Ventilation (ADN) : VE01, VE02 Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : FT1 Special provisions (RID) : 274 Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP1, TP28 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W12 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28 Colis express (express parcels) (RID) : CE4 Hazard identification number (RID) : 36
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions 2,2,2-TRIFLUOROETHANOL FOR SYNTHESIS is not on the REACH Candidate List 2,2,2-TRIFLUOROETHANOL FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. 4105) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H301 Toxic if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H318 Causes serious eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. R10 Flammable R20/21/22 Harmful by inhalation, in contact with skin and if swallowed R37/38 Irritating to respiratory system and skin R41 Risk of serious damage to eyes Xi Irritant Xn Harmful