SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	MANGANESE (metal) FLAKES
Catalogue No. :	AL2876	Product form :	Substance
CAS Number :	7439-96-5	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	81110090
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable solids, Category 1 H228 Substances and Mixtures which, in contact with water, emit flammable gases, Category 1 H260 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; R11 F; R15 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H228 - Flammable solid H260 - In contact with water releases flammable gases which may ignite spontaneously
Precautionary statements (CLP) :	P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P223 - Do not allow contact with water P231+P232 - Handle under inert gas. Protect from moisture P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical/ventilating/lighting/¦ equipment P280 - Wear protective gloves/protective clothing/eye protection/face protection P335+P334 - Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages P370+P378 - In case of fire: Use ... to extinguish P402+P404 - Store in a dry place. Store in a closed container P501 - Dispose of contents/container to ...
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		MANGANESE (METAL) FLAKES
CAS No. :		7439-96-5
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	No additional information available
4.3 Indication of any immediate medical attention and special treatment needed
General information :	No additional information available

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Flammable solid.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment. Wear fire/flame resistant/retardant clothing.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable. Keep away from any possible contact with water, because of violent reaction and possible flash fire.
Precautions for safe handling :	No naked lights. No smoking. Protect from moisture. Handle under inert gas.
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/… equipment.
Storage conditions :	Heat sources. Direct sunlight. Keep in fireproof place. Store in a dry place. Protect from moisture.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear appropriate mask

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid
Molecular mass :	54.94 g/mol
Colour :	Bright silver grey.
Odour :	No data available
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	1260 °C
Freezing point :	No data available
Boiling point :	1900 °C
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable solid,In contact with water releases fla
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Density :	7.3 g/cm3
Solubility :	Water: Reacts with water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Flammable solid. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
In contact with water releases flammable gases which may ignite spontaneously.
10.4 Conditions to avoid
Open flame. Overheating. Direct sunlight. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Not classified
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	3208
UN-No. (IMDG) :	3208
UN-No. (IATA) :	3208
UN-No. (ADN) :	3208
UN-No. (RID) :	3208
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S.
Proper Shipping Name (IMDG) :	METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S.
Proper Shipping Name (IATA) :	METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S.
Proper Shipping Name (ADN) :	METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S.
Proper Shipping Name (RID) :	METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S.
Transport document description (ADR) :	UN 3208, METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S., 4.3, III
Transport document description (IMDG) :	UN 3208, METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S., 4.3, III
Transport document description (IATA) :	UN 3208, METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S., 4.3, III
Transport document description (ADN) :	UN 3208, METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S., 4.3, III
Transport document description (RID) :	UN 3208, METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S., 4.3, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	4.3
Danger labels :	4.3
IMDG
Transport hazard class(es) :	4.3
Danger labels :	4.3
IATA
Transport hazard class(es) :	4.3
Danger labels :	4.3
ADN
Transport hazard class(es) :	4.3
Danger labels :	4.3
RID
Transport hazard class(es) :	4.3
Danger labels :	4.3
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : W2 Special provision (ADR) : 274, 557 Limited quantities (ADR) : 1kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P410, IBC08, R001 Special packing provisions (ADR) : B4 Mixed packing provisions (ADR) : MP14 Portable tank and bulk container instructions (ADR) : T1 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAN Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V1 Special provisions for carriage - Bulk (ADR) : VC1, VC2, AP3, AP4, AP5 Special provisions for carriage - Loading, unloading and handling (ADR) : CV23 Hazard identification number (Kemler No.) : 423 Orange plates : Tunnel restriction code (ADR) : E EAC code : 4W
- Transport by sea
Special provision (IMDG) : 223, 274 Limited quantities (IMDG) : 1 kg Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P410 Packing provisions (IMDG) : PP31, PP40 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B4 Tank instructions (IMDG) : T1 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-G EmS-No. (Spillage) : S-N Stowage category (IMDG) : E Stowage and handling (IMDG) : SW2, H1 Segregation (IMDG) : SG26 MFAG-No : 138
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y476 PCA limited quantity max net quantity (IATA) : 10kg PCA packing instructions (IATA) : 485 PCA max net quantity (IATA) : 25kg CAO packing instructions (IATA) : 491 CAO max net quantity (IATA) : 100kg Special provision (IATA) : A3 ERG code (IATA) : 4W
- Inland waterway transport
Classification code (ADN) : W2 Special provisions (ADN) : 274, 557 Limited quantities (ADN) : 1 kg Excepted quantities (ADN) : E1 Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Provisions for handling and stowage of the cargo (ADN) : HA08 Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : W2 Special provision (RID) : 274, 557 Limited quantities (RID) : 1kg Excepted quantities (RID) : E1 Packing instructions (RID) : P410, IBC08, R001 Special packing provisions (RID) : B4 Mixed packing provisions (RID) : MP14 Portable tank and bulk container instructions (RID) : T1 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAN Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W1 Special provisions for carriage – Bulk (RID) : VC1, VC2, AP3, AP4, AP5 Special provisions for carriage – Loading and unloading (RID) : CW23 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 423
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions MANGANESE (METAL) FLAKES is not on the REACH Candidate List MANGANESE (METAL) FLAKES is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) nwg, non-hazardous to water (KBwS-Beschluss; WGK No 1443) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information
Full text of R-, H- and EUH-phrases: Flam. Sol. 1 Flammable solids, Category 1 Water-react. 1 Substances and Mixtures which, in contact with water, emit flammable gases, Category 1 H228 Flammable solid H260 In contact with water releases flammable gases which may ignite spontaneously R11 Highly flammable R15 Contact with water liberates extremely flammable gases F Highly flammable