ANTIMONY SULPHIDE GOLDEN Extra Pure |
| Synonyms : Antimony pentasulphide |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
|||
|---|---|---|---|
1.1 Product identifier |
|||
| Chemical Name : | ANTIMONY SULPHIDE GOLDEN | ||
| Catalogue No. : | AL0482 | Product form : | Substance |
| CAS Number : | 1315-04-4 | EC Number : | 215-255-5 |
| Grade : | EC Index Number : | ||
| Chemical Formula : | S5Sb2 | HSN Code : | 28309010 |
| Synonyms : | Antimony(V) sulfide / Antimony Pentasulfide | ||
| Chemical Structure : |
|
||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
|||
| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
|||
| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
||
1.4 Emergency Contact Details |
|||
| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
||
SECTION 2: Hazards identification |
|
|---|---|
2.1 Classification of the substance or mixture |
|
| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
|
Flammable solids, Category 1 H228 Acute toxicity (oral), Category 4 H302 Acute toxicity (inhalation:gas) Category 4 H332 Hazardous to the aquatic environment Chronic Hazard, Category 2 H411 Full text of classification categories and H statements : see section 16 |
|
| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| F; R11 Full text of R-phrases: see section 16 |
|
| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
|
| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS02
 GHS07
 GHS09
|
| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H228 - Flammable solid H302+H332 - Harmful if swallowed or if inhaled H411 - Toxic to aquatic life with long lasting effects |
| Precautionary statements (CLP) : | P210 - Keep away from heat, hot surfaces, sparks. - No smoking P273 - Avoid release to the environment |
2.3 Other hazards |
|
| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
|||
|---|---|---|---|
3.1. Substance |
|||
| Name : | ANTIMONY SULPHIDE GOLDEN Extra Pure | ||
| CAS No. : | 1315-04-4 | ||
| EC No. : | 215-255-5 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
|||
| Not applicable | |||
SECTION 4: First aid measures |
|
|---|---|
4.1 Description of first aid measures |
|
| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. |
| First-aid measures after skin contact : | Wash with plenty of water/…. |
| First-aid measures after eye contact : | Rinse immediately with plenty of water. |
| First-aid measures after ingestion : | Rinse mouth. |
4.2 Most important symptoms and effects, both acute and delayed |
|
| Symptoms relating to use : | No additional information available |
4.3 Indication of any immediate medical attention and special treatment needed |
|
| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
|
|---|---|
5.1 Extinguishing media |
|
| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
|
| Fire hazard : | Flammable solid. |
| Explosion hazard : | May form flammable/explosive vapour-air mixture. |
5.3 Advice for firefighters |
|
| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
|
|---|---|
6.1 Personal precautions, protective equipment and emergency procedures |
|
| General measures : | Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking. |
6.1.1. For non-emergency personnel |
|
| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
|
| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
|
| Toxic to aquatic life with long lasting effects. | |
6.3 Methods and material for containment and cleaning up |
|
| Methods for cleaning up : | Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers. |
6.4 Reference to other sections |
|
| Reference : | No additional information available |
SECTION 7: Handling and storage |
|
|---|---|
7.1 Precautions for safe handling |
|
| Additional hazards when processed : | Handle empty containers with care because residual vapours are flammable. |
| Precautions for safe handling : | Avoid contact with skin and eyes. Keep away from sources of ignition - No smoking. Do not breathe vapours. |
7.2 Conditions for safe storage, including any incompatibilities |
|
| Technical measures : | Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. |
| Storage conditions : | Store in a well-ventilated place. Keep in fireproof place. |
7.3 Specific end use(s) |
|
| No additional information available | |
SECTION 8: Exposure controls/personal protection |
|
|---|---|
8.1 Control parameters |
|
| No additional information available | |
8.2 Exposure controls |
|
| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
|
|---|---|
9.1 Information on basic physical and chemical properties |
|
| Physical state : | Solid Colour |
| Colour : | Yellow orange powder. |
| Odour : | odourless. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | No data available |
| Freezing point : | No data available |
| Boiling point : | No data available |
| Flash point : | No data available |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | Flammable solid |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | No data available |
| Solubility : | No data available |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
|
| No additional information available | |
SECTION 10: Stability and reactivity |
|
|---|---|
10.1 Reactivity |
|
| Flammable solid. | |
10.2 Chemical stability |
|
| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
|
| Reacts violently with water. | |
10.4 Conditions to avoid |
|
| Open flame. Heat. Sparks. | |
10.5 Incompatible materials |
|
| No additional information available | |
10.6 Hazardous decomposition products |
|
| May release flammable gases. |
SECTION 11: Toxicological information |
|
|---|---|
11.1 Information on toxicological effects |
|
| Acute toxicity : | Oral: Harmful if swallowed. Inhalation:gas: Harmful if inhaled. |
| Skin corrosion/irritation : | Not classified |
| Serious eye damage/irritation : | Not classified |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| Reproductive toxicity : | Not classified |
| Specific target organ toxicity (single exposure) : | Not classified |
| Specific target organ toxicity (repeated exposure) : | Not classified |
SECTION 12: Ecological information |
|
|---|---|
12.1 Toxicity |
|
| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
|
| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
|
| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
|
| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
|
| No additional information available | |
12.6 Other adverse effects |
|
| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
|
|---|---|
13.1 Waste treatment methods |
|
| Product/Packaging disposal recommendations : | |
| Additional information : | Handle empty containers with care because residual vapours are flammable. |
SECTION 14: Transport information |
|
|---|---|
| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
|
| UN-No. (ADR) : | 3178 |
| UN-No. (IMDG) : | 3178 |
| UN-No. (IATA) : | 3178 |
| UN-No. (ADN) : | 3178 |
| UN-No. (RID) : | 3178 |
14.2. UN proper shipping name |
|
| Proper Shipping Name (ADR) : | FLAMMABLE SOLID, INORGANIC, N.O.S. |
| Proper Shipping Name (IMDG) : | FLAMMABLE SOLID, INORGANIC, N.O.S. |
| Proper Shipping Name (IATA) : | FLAMMABLE SOLID, INORGANIC, N.O.S. |
| Proper Shipping Name (ADN) : | FLAMMABLE SOLID, INORGANIC, N.O.S. |
| Proper Shipping Name (RID) : | FLAMMABLE SOLID, INORGANIC, N.O.S. |
| Transport document description (ADR) : | UN 3178, FLAMMABLE SOLID, INORGANIC, N.O.S., 4.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 3178, FLAMMABLE SOLID, INORGANIC, N.O.S., 4.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 3178, FLAMMABLE SOLID, INORGANIC, N.O.S., 4.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 3178, FLAMMABLE SOLID, INORGANIC, N.O.S., 4.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 3178, FLAMMABLE SOLID, INORGANIC, N.O.S., 4.1, II ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
|
| ADR | |
| Transport hazard class(es) : | 4.1 |
| Danger labels : | 4.1 
|
| IMDG | |
| Transport hazard class(es) : | 4.1 |
| Danger labels : | 4.1
|
| IATA | |
| Transport hazard class(es) : | 4.1 |
| Danger labels : | 4.1
|
| ADN | |
| Transport hazard class(es) : | 4.1 |
| Danger labels : | 4.1
|
| RID | |
| Transport hazard class(es) : | 4.1 |
| Danger labels : | 4.1
|
14.4. Packing group |
|
| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
|
| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
|
| - Overland transport | |
|
Classification code (ADR) : F3 Special provision (ADR) : 274 Limited quantities (ADR) : 1kg Excepted quantities (ADR) : E2 Packing instructions (ADR) : P002, IBC08 Special packing provisions (ADR) : B4 Mixed packing provisions (ADR) : MP11 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAN Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V11 Hazard identification number (Kemler No.) : 40 Orange plates : Tunnel restriction code (ADR) : E EAC code : 1Z |
|
| - Transport by sea | |
|
Special provision (IMDG) : 274, 915 Limited quantities (IMDG) : 1 kg Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B2, B4 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-G Stowage category (IMDG) : B MFAG-No : 133 |
|
| - Air transport | |
|
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y441 PCA limited quantity max net quantity (IATA) : 5kg PCA packing instructions (IATA) : 445 PCA max net quantity (IATA) : 15kg CAO packing instructions (IATA) : 448 CAO max net quantity (IATA) : 50kg Special provision (IATA) : A3 ERG code (IATA) : 3L |
|
| - Inland waterway transport | |
|
Classification code (ADN) : F3 Special provisions (ADN) : 274 Limited quantities (ADN) : 1 kg Excepted quantities (ADN) : E2 Equipment required (ADN) : PP Number of blue cones/lights (ADN) : 1 |
|
| - Rail transport | |
|
Classification code (RID) : F3 Special provision (RID) : 274 Limited quantities (RID) : 1kg Excepted quantities (RID) : E2 Packing instructions (RID) : P002, IBC08 Special packing provisions (RID) : B4 Mixed packing provisions (RID) : MP11 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAN Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W1 Colis express (express parcels) (RID) : CE10 Hazard identification number (RID) : 40 |
|
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
|
| Not applicable | |
SECTION 15: Regulatory information |
|---|
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions Antimony Sulphide Golden Extra Pure is not on the REACH Candidate List Antimony Sulphide Golden Extra Pure is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
||||||||||||