NICKEL (metal) POWDER

NICKEL (metal) POWDER

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : NICKEL (metal) POWDER
Catalogue No. : AL3209 Product form : Substance
CAS Number : 7440-02-0 EC Number : 231-111-4
Grade : EC Index Number : 028-002-00-7
Chemical Formula : HSN Code : 75040000
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Specific target organ
toxicity Repeated
exposure, Category 1
H372
Carcinogenicity, Category
2
H351
Sensitisation Skin,
category 1
H317
Hazardous to the aquatic
environment Chronic
Hazard, Category 3
H412
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.3; R40
T; R48/23
R43
R52/53
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS08GHS08 GHS07GHS07
Signal word (CLP) : Danger
Hazard statements (CLP) : H317 - May cause an allergic skin reaction
H351 - Suspected of causing cancer
H372 - Causes damage to organs through prolonged or repeated exposure
H412 - Harmful to aquatic life with long lasting effects
Precautionary statements (CLP) : P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P314 - Get medical advice/attention if you feel unwell
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : NICKEL (POWDER)
CAS No. : 7440-02-0
EC Index No. : 028-002-00-7
EC No. : 231-111-4
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical
advice/attention. Specific treatment (see ... on this label). Wash contaminated
clothing before reuse.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : Causes damage to organs through prolonged or repeated exposure.
Symptoms/injuries after inhalation : May cause an allergic skin reaction.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clean up immediately by sweeping or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid breathing dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures : Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid Colour
Colour : Greyish black powder.
Odour : odourless.
Odour threshold : No data available
pH value : 9 - 11 at 20 °C
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 1455 °C
Freezing point : No data available
Boiling point : 2730 °C
Flash point : No data available
Auto-ignition temperature : 87 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 8.098 g/cm3
Solubility : Water: Insoluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Not classified
pH: 9 - 11 at 20 °C
Serious eye damage/irritation : Not classified
pH: 9 - 11 at 20 °C
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Causes damage to organs through prolonged or repeated exposure.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Harmful to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability : NICKEL (POWDER) (7440-02-0) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3089
UN-No. (IMDG) : 3089
UN-No. (IATA) : 3089
UN-No. (ADN) : 3089
UN-No. (RID) : 3089
14.2. UN proper shipping name
Proper Shipping Name (ADR) : METAL POWDER, FLAMMABLE, N.O.S.
Proper Shipping Name (IMDG) : METAL POWDER, FLAMMABLE, N.O.S.
Proper Shipping Name (IATA) : METAL POWDER, FLAMMABLE, N.O.S.
Proper Shipping Name (ADN) : METAL POWDER, FLAMMABLE, N.O.S.
Proper Shipping Name (RID) : METAL POWDER, FLAMMABLE, N.O.S.
Transport document description (ADR) : UN 3089, METAL POWDER, FLAMMABLE, N.O.S., 4.1, II
Transport document description (IMDG) : UN 3089, METAL POWDER, FLAMMABLE, N.O.S., 4.1, II
Transport document description (IATA) : UN 3089, METAL POWDER, FLAMMABLE, N.O.S., 4.1, II
Transport document description (ADN) : UN 3089, METAL POWDER, FLAMMABLE, N.O.S., 4.1, II
Transport document description (RID) : UN 3089, METAL POWDER, FLAMMABLE, N.O.S., 4.1, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 4.1
Danger labels : 4.1
IMDG
Transport hazard class(es) : 4.1
Danger labels : 4.1
IATA
Transport hazard class(es) : 4.1
Danger labels : 4.1
ADN
Transport hazard class(es) : 4.1
Danger labels : 4.1
RID
Transport hazard class(es) : 4.1
Danger labels : 4.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F3
Special provision (ADR) : 552
Limited quantities (ADR) : 1kg
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4
Mixed packing provisions (ADR) : MP11
Portable tank and bulk container
instructions (ADR)
: T3
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAN
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR)
: V11
Hazard identification number (Kemler No.) : 40
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 4Y
- Transport by sea
Limited quantities (IMDG) : 1 kg
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B2, B4
Tank instructions (IMDG) : T3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-G
EmS-No. (Spillage) : S-G
Stowage category (IMDG) : B
Stowage and handling (IMDG) : H1
Segregation (IMDG) : SG17, SG25, SG26
MFAG-No : 170
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y441
PCA limited quantity max net quantity
(IATA)
: 5kg
PCA packing instructions (IATA) : 445
PCA max net quantity (IATA) : 15kg
CAO packing instructions (IATA) : 448
CAO max net quantity (IATA) : 50kg
Special provision (IATA) : A3
ERG code (IATA) : 3L
- Inland waterway transport
Classification code (ADN) : F3
Special provisions (ADN) : 552
Limited quantities (ADN) : 1 kg
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP
Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : F3
Special provision (RID) : 552
Limited quantities (RID) : 1kg
Excepted quantities (RID) : E2
Packing instructions (RID) : P002, IBC08
Special packing provisions (RID) : B4
Mixed packing provisions (RID) : MP11
Portable tank and bulk container
instructions (RID)
: T3
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAN
Transport category (RID) : 2
Special provisions for carriage – Packages
(RID)
: W1
Colis express (express parcels) (RID) : CE10
Hazard identification number (RID) : 40
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
NICKEL (POWDER) is not on the REACH Candidate List
NICKEL (POWDER) is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (KBwS-Beschluss; WGK No 7616)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3
Carc. 2 Carcinogenicity, Category 2
Skin Sens. 1 Sensitisation — Skin, category 1
STOT RE 1 Specific target organ toxicity — Repeated exposure, Category 1
H317 May cause an allergic skin reaction
H351 Suspected of causing cancer
H372 Causes damage to organs through prolonged or repeated exposure
H412 Harmful to aquatic life with long lasting effects
R40 Limited evidence of a carcinogenic effect
R43 May cause sensitisation by skin contact
R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
T Toxic