BROMOETHANE For Synthesis |
| Synonyms : Ethyl Bromide |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | ETHYL BROMIDE (for synthesis) (bromoethane) | ||
| Catalogue No. : | AL2057 | Product form : | Substance |
| CAS Number : | 74-96-4 | EC Number : | 200-825-8 |
| Grade : | EC Index Number : | 602-055-00-1 | |
| Chemical Formula : | C2H5Br | HSN Code : | 29033990 |
| Synonyms : | Ethyl bromide | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Flammable liquids, Category 2 H225 Acute toxicity (inhal.), Category 4 H332 Acute toxicity (oral), Category 4 H302 Carcinogenicity, Category 2 H351 Full text of H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Carc.Cat.3; R40 F; R11 Xn; R20/22 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS02
 GHS08
 GHS07
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H225 - Highly flammable liquid and vapour. H302+H332 - Harmful if swallowed or if inhaled H351 - Suspected of causing cancer. |
| Precautionary statements (CLP) : | P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P281 - Use personal protective equipment as required. |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | BROMOETHANE FOR SYNTHESIS | ||
| CAS No. : | 74-96-4 | ||
| EC Index No. : | 602-055-00-1 | ||
| EC No. : | 200-825-8 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
| First-aid measures after skin contact : | Get immediate medical advice/attention. Wash with plenty of water/…. |
| First-aid measures after eye contact : | Rinse immediately with plenty of water. Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects after inhalation : Harmful if inhaled. Symptoms/effects after ingestion : Harmful if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Fire hazard : | Highly flammable liquid and vapour. |
| Explosion hazard : | May form flammable/explosive vapour-air mixture. |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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| General measures : | Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. |
6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Additional hazards when processed : | Handle empty containers with care because residual vapours are flammable. |
| Precautions for safe handling : | Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid contact with skin and eyes. Do not breathe vapours. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Technical measures : | Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. |
| Storage conditions : | Keep in fireproof place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid |
| Molecular mass : | 108.97 g/mol |
| Colour : | Clear Colorless. |
| Odour : | ethereal odor. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | -119 °C |
| Freezing point : | No data available |
| Boiling point : | 37 - 40 °C |
| Flash point : | -23 °C |
| Auto-ignition temperature : | 511 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | Flammable Highly flammable liquid and vapour. |
| Vapour pressure : | 519.7 hPa at 20 °C |
| Relative vapour density at 20°C : | 3.76 |
| Density : | 1.45 g/cm3 |
| Solubility : | Water: Slightly soluble |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | 0.379 cP @ 25°C |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Open flame. Direct sunlight. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| May release flammable gases. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Inhalation: Harmful if inhaled. Oral: Harmful if swallowed. |
| Skin corrosion/irritation : | Not classified |
| Serious eye damage/irritation : | Not classified |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Suspected of causing cancer. |
| STOT-single exposure : | Not classified |
| STOT-repeated exposure : | Not classified |
| Aspiration hazard : | Not classified BROMOETHANE FOR SYNTHESIS (74-96-4) Viscosity, kinematic 0.261 mm²/s |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
| Additional information : | Handle empty containers with care because residual vapours are flammable. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1891 |
| UN-No. (IMDG) : | 1891 |
| UN-No. (IATA) : | 1891 |
| UN-No. (ADN) : | 1891 |
| UN-No. (RID) : | 1891 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | ETHYL BROMIDE |
| Proper Shipping Name (IMDG) : | ETHYL BROMIDE |
| Proper Shipping Name (IATA) : | ETHYL BROMIDE |
| Proper Shipping Name (ADN) : | ETHYL BROMIDE |
| Proper Shipping Name (RID) : | ETHYL BROMIDE |
| Transport document description (ADR) : | UN 1891, ETHYL BROMIDE, 6.1, II |
| Transport document description (IMDG) : | UN 1891, ETHYL BROMIDE, 6.1, II |
| Transport document description (IATA) : | UN 1891, ETHYL BROMIDE, 6.1, II |
| Transport document description (ADN) : | UN 1891, ETHYL BROMIDE, 6.1, II |
| Transport document description (RID) : | UN 1891, ETHYL BROMIDE, 6.1, II |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1 
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| IMDG | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| IATA | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| ADN | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| RID | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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14.4. Packing group |
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| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : T1 Limited quantities (ADR) : 100ml Excepted quantities (ADR) : E4 Packing instructions (ADR) : P001, IBC02 Special packing provisions (ADR) : B8 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S19 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 2W |
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| - Transport by sea | |
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Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 IBC special provisions (IMDG) : B8 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2, TP13 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : B Stowage and handling (IMDG) : SW2, SW5 Properties and observations (IMDG) : Colourless volatile liquid evolving irritating vapour with a narcotic effect. Boiling point: 38°C. Vapour can be ignited by an electric spark or similar sources of ignition. Toxic if swallowed, by skin contact or by inhalation. MFAG-No : 131 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y641 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 654 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 662 CAO max net quantity (IATA) : 60L ERG code (IATA) : 6L |
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| - Inland waterway transport | |
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Classification code (ADN) : T1 Special provisions (ADN) : 802 Limited quantities (ADN) : 100 ml Excepted quantities (ADN) : E4 Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 2 |
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| - Rail transport | |
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Classification code (RID) : T1 Excepted quantities (RID) : E4 Packing instructions (RID) : P001, IBC02 Special packing provisions (RID) : B8 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE5 Hazard identification number (RID) : 60 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions BROMOETHANE FOR SYNTHESIS is not on the REACH Candidate List BROMOETHANE FOR SYNTHESIS is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. 2273) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
| Denmark |
| Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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