EPICHLOROHYDRIN For Synthesis |
Synonyms : 1-Chloro-2,3-epoxypropane |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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Chemical Name : | EOSINOPHYLLIA DILUTING FLUID(1-chloro-2, 3-epoxypropane) | ||
Catalogue No. : | AL1999 | Product form : | Substance |
CAS Number : | 106-89-8 | EC Number : | 203-439-8 |
Grade : | EC Index Number : | 603-026-00-6 | |
Chemical Formula : | C3H5ClO | HSN Code : | 29103000 |
Synonyms : | 1-Chloro-2,3-epoxypropane | ||
Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
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Use of the substance/mixture : | Industrial For professional use only | ||
Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
Carcinogenicity, Category 1B H350 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Acute toxicity (oral), Category 3 H301 Skin corrosion/irritation, Category 1B H314 Serious eye damage/eye irritation, Category 1 H318 Flammable liquids, Category 3 H226 Skin sensitisation, Category 1 H317 Full text of H statements : see section 16 |
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Classification according to Directive 67/548/EEC or 1999/45/EC | |
Carc.Cat.2; R45 T; R23/24/25 C; R34 R43 R10 Full text of R-phrases: see section 16 |
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Adverse physicochemical, human health and environmental effects | |
No additional information available | |
2.2 Label elements |
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Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
Hazard pictograms (CLP) : | GHS06 GHS05 GHS08 GHS02 |
Signal word (CLP) : | Danger |
Hazard statements (CLP) : | H226 - Flammable liquid and vapour. H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H350 - May cause cancer. |
Precautionary statements (CLP) : | P201 - Obtain special instructions before use. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor |
2.3 Other hazards |
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Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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Name : | EPICHLOROHYDRIN FOR SYNTHESIS | ||
CAS No. : | 106-89-8 | ||
EC Index No. : | 603-026-00-6 | ||
EC No. : | 203-439-8 | ||
Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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Not applicable |
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. |
First-aid measures after skin contact : | Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor. Wash with plenty of water/…. Specific measures (see supplemental first aid instruction on this label). Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label). |
First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
First-aid measures after ingestion : | Rinse mouth. Immediately call a POISON CENTER/doctor. Specific treatment (see supplemental first aid instruction on this label). Do NOT induce vomiting. |
4.2 Most important symptoms and effects, both acute and delayed |
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Symptoms relating to use : | Symptoms/effects : Causes severe skin burns and eye damage. May cause cancer. Symptoms/effects after inhalation : May cause an allergic skin reaction. Symptoms/effects after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Symptoms/effects after eye contact : Causes serious eye damage. Symptoms/effects after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. |
4.3 Indication of any immediate medical attention and special treatment needed |
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General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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Special procedures : | Fire hazard : Flammable liquid and vapour. Explosion hazard : May form flammable/explosive vapour-air mixture. |
5.3 Advice for firefighters |
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Protection during firefighting : | No additional information available |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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General measures : | Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. |
6.1.1. For non-emergency personnel |
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Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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Protective equipment | Use personal protective equipment as required |
Emergency procedures | Stop release. |
6.2 Environmental precautions |
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Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
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Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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Additional hazards when processed : | Handle empty containers with care because residual vapours are flammable. |
Precautions for safe handling : | No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Do |
Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. |
7.2 Conditions for safe storage, including any incompatibilities |
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Technical measures : | Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Comply with applicable regulations. |
Storage conditions : | Keep container tightly closed. Store in original container. Store in a dry place. Protect from moisture. |
7.3 Specific end use(s) |
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No additional information available |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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No additional information available | |
8.2 Exposure controls |
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Hand protection : | protective gloves |
Eye protection : | Chemical goggles or face shield |
Skin and body protection : | Wear suitable protective clothing |
Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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Physical state : | Liquid |
Molecular mass : | 92.53 g/mol |
Colour : | Clear Colorless. |
Odour : | chloroform-like odor. |
Odour threshold : | No data available |
pH value : | No data available |
Relative evaporation rate (butylacetate=1) : | No data available |
Melting point : | -57 °C |
Freezing point : | No data available |
Boiling point : | 115 - 117 |
Flash point : | 32 °C |
Auto-ignition temperature : | 4160 °C |
Decomposition temperature : | No data available |
Flammability (solid, gas) : | Flammable liquid and vapour. |
Vapour pressure : | 12.5 mm Hg at 200C |
Relative vapour density at 20°C : | 3.3 |
Density : | 1.18 g/cm3 |
Solubility : | Water: Moderate (1-10%) |
Log Pow : | No data available |
Viscosity, kinematic : | No data available |
Viscosity, dynamic : | No data available |
Explosive properties : | No data available |
Oxidising properties : | No data available |
Explosive limits : | 0.038 - 0.21 vol % |
9.2 Other information |
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No additional information available |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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Thermal decomposition generates : Corrosive vapours. | |
10.2 Chemical stability |
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Flammable liquid and vapour. May form flammable/explosive vapour-air mixture. | |
10.3 Possibility of hazardous reactions |
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No additional information available | |
10.4 Conditions to avoid |
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Open flame. Overheating. Direct sunlight. Heat. Sparks. | |
10.5 Incompatible materials |
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No additional information available | |
10.6 Hazardous decomposition products |
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May release flammable gases. Thermal decomposition generates : Corrosive vapours. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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Acute toxicity : | Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. Oral: Toxic if swallowed. |
Skin corrosion/irritation : | Causes severe skin burns and eye damage. |
Serious eye damage/irritation : | Causes serious eye damage. |
Respiratory or skin sensitisation : | May cause an allergic skin reaction. |
Germ cell mutagenicity : | Not classified |
Carcinogenicity : | May cause cancer. |
STOT-single exposure : | Not classified |
STOT-repeated exposure : | Not classified |
Aspiration hazard : | Not classified |
Potential adverse human health effects and symptoms : | Toxic if swallowed. Toxic in contact with skin. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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No additional information available | |
12.6 Other adverse effects |
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Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
Additional information : | Handle empty containers with care because residual vapours are flammable. |
Ecology - waste materials : | Hazardous waste due to toxicity. |
SECTION 14: Transport information |
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In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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UN-No. (ADR) : | 2023 |
UN-No. (IMDG) : | 2023 |
UN-No. (IATA) : | 2023 |
UN-No. (ADN) : | 2023 |
UN-No. (RID) : | 2023 |
14.2. UN proper shipping name |
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Proper Shipping Name (ADR) : | EPICHLOROHYDRIN |
Proper Shipping Name (IMDG) : | EPICHLOROHYDRIN |
Proper Shipping Name (IATA) : | EPICHLOROHYDRIN |
Proper Shipping Name (ADN) : | EPICHLOROHYDRIN |
Proper Shipping Name (RID) : | EPICHLOROHYDRIN |
Transport document description (ADR) : | UN 2023, EPICHLOROHYDRIN, 6.1 (3), II |
Transport document description (IMDG) : | UN 2023, EPICHLOROHYDRIN, 6.1 (3), II |
Transport document description (IATA) : | UN 2023, EPICHLOROHYDRIN, 6.1 (3), II |
Transport document description (ADN) : | UN 2023, EPICHLOROHYDRIN, 6.1 (3), II |
Transport document description (RID) : | UN 2023, EPICHLOROHYDRIN, 6.1 (3), II |
14.3. Transport hazard class(es) |
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ADR | |
Transport hazard class(es) : | 6.1 (3) |
Danger labels : | 6.1, 3 |
IMDG | |
Transport hazard class(es) : | 6.1 (3) |
Danger labels : | 6.1, 3 |
IATA | |
Transport hazard class(es) : | 6.1 (3) |
Danger labels : | 6.1, 3 |
ADN | |
Transport hazard class(es) : | 6.1 (3) |
Danger labels : | 6.1, 3 |
RID | |
Transport hazard class(es) : | 6.1 (3) |
Danger labels : | 6.1, 3 |
14.4. Packing group |
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Packing group (ADR) : | II |
Packing group (IMDG) : | II |
Packing group (IATA) : | II |
Packing group (ADN) : | II |
Packing group (RID) : | II |
14.5. Environmental hazards |
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Dangerous for the environment : | No |
Marine pollutant : | Yes (IMDG only) |
Other information : | No supplementary information available |
14.6. Special precautions for user |
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- Overland transport | |
Classification code (ADR) : TF1 Special provisions (ADR) : 279 Limited quantities (ADR) : 100ml Excepted quantities (ADR) : E4 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2, S9, S19 Hazard identification number (Kemler No.) : 63 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •3W APP code : A(fl) |
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- Transport by sea | |
Special provisions (IMDG) : 279 Limited quantities (IMDG) : 100 ml Excepted quantities (IMDG) : E4 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2, TP13 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : A Stowage and handling (IMDG) : SW2 Flash point (IMDG) : approximately 32°C c.c. MFAG-No : 131P |
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- Air transport | |
PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y641 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 654 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 662 CAO max net quantity (IATA) : 60L Special provisions (IATA) : A113 ERG code (IATA) : 6F |
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- Inland waterway transport | |
Classification code (ADN) : TF1 Special provisions (ADN) : 279, 802 Limited quantities (ADN) : 100 ml Excepted quantities (ADN) : E4 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, TOX, A Ventilation (ADN) : VE01, VE02 Number of blue cones/lights (ADN) : 2 |
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- Rail transport | |
Classification code (RID) : TF1 Special provisions (RID) : 279 Limited quantities (RID) : 100ml Excepted quantities (RID) : E4 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE5 Hazard identification number (RID) : 63 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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Not applicable |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
15.1.1 EU-Regulations : |
No REACH Annex XVII restrictions EPICHLOROHYDRIN FOR SYNTHESIS is not on the REACH Candidate List EPICHLOROHYDRIN FOR SYNTHESIS is not on the REACH Annex XIV List |
15.1.2. National regulations |
Germany |
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to AwSV; ID No. 92) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
Netherlands |
SZW-lijst van kankerverwekkende stoffen : EPICHLOROHYDRIN FOR SYNTHESIS is listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
Denmark |
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
No additional information available |
SECTION 16: Other Information |
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