EPICHLOROHYDRIN For Synthesis

EPICHLOROHYDRIN For Synthesis

Synonyms : 1-Chloro-2,3-epoxypropane

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : EOSINOPHYLLIA DILUTING FLUID(1-chloro-2, 3-epoxypropane)
Catalogue No. : AL1999 Product form : Substance
CAS Number : 106-89-8 EC Number : 203-439-8
Grade : EC Index Number : 603-026-00-6
Chemical Formula : C3H5ClO HSN Code : 29103000
Synonyms : 1-Chloro-2,3-epoxypropane
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Carcinogenicity, Category
1B
H350
Acute toxicity (dermal),
Category 3
H311
Acute toxicity (inhal.),
Category 3
H331
Acute toxicity (oral),
Category 3
H301
Skin corrosion/irritation,
Category 1B
H314
Serious eye damage/eye
irritation, Category 1
H318
Flammable liquids,
Category 3
H226
Skin sensitisation,
Category 1
H317
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.2; R45
T; R23/24/25
C; R34
R43
R10
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS06GHS06 GHS05GHS05 GHS08GHS08 GHS02GHS02
Signal word (CLP) : Danger
Hazard statements (CLP) : H226 - Flammable liquid and vapour.
H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled
H314 - Causes severe skin burns and eye damage.
H317 - May cause an allergic skin reaction.
H350 - May cause cancer.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P260 - Do not breathe dust/fume/gas/mist/vapours/spray.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER/doctor
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : EPICHLOROHYDRIN FOR SYNTHESIS
CAS No. : 106-89-8
EC Index No. : 603-026-00-6
EC No. : 203-439-8
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediately call a POISON CENTER/doctor. Wash with plenty of water/…. Specific
measures (see supplemental first aid instruction on this label). Wash contaminated
clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see supplemental first aid instruction on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Immediately call a POISON CENTER/doctor. Specific treatment (see
supplemental first aid instruction on this label). Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : Causes severe skin burns and eye damage. May cause cancer.
Symptoms/effects after inhalation : May cause an allergic skin reaction.
Symptoms/effects after skin contact : Repeated exposure to this material can result in absorption through skin causing
significant health hazard. Toxic in contact with skin.
Symptoms/effects after eye contact : Causes serious eye damage.
Symptoms/effects after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious
health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : Fire hazard : Flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting : No additional information available

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open
flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills
with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Do
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Comply with applicable regulations.
Storage conditions : Keep container tightly closed. Store in original container. Store in a dry place.
Protect from moisture.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid
Molecular mass : 92.53 g/mol
Colour : Clear Colorless.
Odour : chloroform-like odor.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -57 °C
Freezing point : No data available
Boiling point : 115 - 117
Flash point : 32 °C
Auto-ignition temperature : 4160 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable liquid and vapour.
Vapour pressure : 12.5 mm Hg at 200C
Relative vapour density at 20°C : 3.3
Density : 1.18 g/cm3
Solubility : Water: Moderate (1-10%)
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.038 - 0.21 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Overheating. Direct sunlight. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. Oral: Toxic if
swallowed.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : May cause cancer.
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Toxic if swallowed. Toxic in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Hazardous waste due to toxicity.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2023
UN-No. (IMDG) : 2023
UN-No. (IATA) : 2023
UN-No. (ADN) : 2023
UN-No. (RID) : 2023
14.2. UN proper shipping name
Proper Shipping Name (ADR) : EPICHLOROHYDRIN
Proper Shipping Name (IMDG) : EPICHLOROHYDRIN
Proper Shipping Name (IATA) : EPICHLOROHYDRIN
Proper Shipping Name (ADN) : EPICHLOROHYDRIN
Proper Shipping Name (RID) : EPICHLOROHYDRIN
Transport document description (ADR) : UN 2023, EPICHLOROHYDRIN, 6.1 (3), II
Transport document description (IMDG) : UN 2023, EPICHLOROHYDRIN, 6.1 (3), II
Transport document description (IATA) : UN 2023, EPICHLOROHYDRIN, 6.1 (3), II
Transport document description (ADN) : UN 2023, EPICHLOROHYDRIN, 6.1 (3), II
Transport document description (RID) : UN 2023, EPICHLOROHYDRIN, 6.1 (3), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
IMDG
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
IATA
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
ADN
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
RID
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : Yes (IMDG only)
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TF1
Special provisions (ADR) : 279
Limited quantities (ADR) : 100ml
Excepted quantities (ADR) : E4
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container
instructions (ADR)
: T7
Portable tank and bulk container special
provisions (ADR)
: TP2
Tank code (ADR) : L4BH
Tank special provisions (ADR) : TU15, TE19
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S2, S9, S19
Hazard identification number (Kemler No.) : 63
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : •3W
APP code : A(fl)
- Transport by sea
Special provisions (IMDG) : 279
Limited quantities (IMDG) : 100 ml
Excepted quantities (IMDG) : E4
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP2, TP13
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-D
Stowage category (IMDG) : A
Stowage and handling (IMDG) : SW2
Flash point (IMDG) : approximately 32°C c.c.
MFAG-No : 131P
- Air transport
PCA Excepted quantities (IATA) : E4
PCA Limited quantities (IATA) : Y641
PCA limited quantity max net quantity
(IATA)
: 1L
PCA packing instructions (IATA) : 654
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 662
CAO max net quantity (IATA) : 60L
Special provisions (IATA) : A113
ERG code (IATA) : 6F
- Inland waterway transport
Classification code (ADN) : TF1
Special provisions (ADN) : 279, 802
Limited quantities (ADN) : 100 ml
Excepted quantities (ADN) : E4
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP, EX, TOX, A
Ventilation (ADN) : VE01, VE02
Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : TF1
Special provisions (RID) : 279
Limited quantities (RID) : 100ml
Excepted quantities (RID) : E4
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP15
Portable tank and bulk container
instructions (RID)
: T7
Portable tank and bulk container special
provisions (RID)
: TP2
Tank codes for RID tanks (RID) : L4BH
Special provisions for RID tanks (RID) : TU15
Transport category (RID) : 2
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW13, CW28, CW31
Colis express (express parcels) (RID) : CE5
Hazard identification number (RID) : 63
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
EPICHLOROHYDRIN FOR SYNTHESIS is not on the REACH Candidate List
EPICHLOROHYDRIN FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to
AwSV; ID No. 92)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : EPICHLOROHYDRIN FOR SYNTHESIS is listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Class for fire hazard : Class II-1
Store unit : 5 liter
Classification remarks : R10 ; Emergency management
guidelines for the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3
Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Carc. 1B Carcinogenicity, Category 1B
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Flam. Liq. 3 Flammable liquids, Category 3
Skin Corr. 1B Skin corrosion/irritation, Category 1B
Skin Sens. 1 Skin sensitisation, Category 1
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H350 May cause cancer.
R10 Flammable
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed
R34 Causes burns
R43 May cause sensitisation by skin contact
R45 May cause cancer
C Corrosive
T Toxic