SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	EPICHLOROHYDRIN AR (1-chloro-2, 3-epoxypropane)
Catalogue No. :	AL2000	Product form :	Substance
CAS Number :	106-89-8	EC Number :	203-439-8
Grade :		EC Index Number :	603-026-00-6
Chemical Formula :	C3H5ClO	HSN Code :	29103000
Synonyms :	1-Chloro-2,3-epoxypropane
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Carcinogenicity, Category 1B H350 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Acute toxicity (oral), Category 3 H301 Skin corrosion/irritation, Category 1B H314 Serious eye damage/eye irritation, Category 1 H318 Flammable liquids, Category 3 H226 Sensitisation Skin, H317 category 1 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.2; R45 T; R23/24/25 C; R34 R43 R10 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS06 GHS05 GHS08 GHS02
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H226 - Flammable liquid and vapour H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction H350 - May cause cancer
Precautionary statements (CLP) :	P201 - Obtain special instructions before use P260 - Do not breathe dust/fume/gas/mist/vapours/spray P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		EPICHLOROHYDRIN AR
CAS No. :		106-89-8
EC Index No. :		603-026-00-6
EC No. :		203-439-8
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact :	Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap and water. Specific measures (see ... on this label). Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see ... on this label).
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after ingestion :	Rinse mouth. Immediately call a POISON CENTER or doctor/physician. Specific treatment (see ... on this label). Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : Causes severe skin burns and eye damage. May cause cancer. Symptoms/injuries after inhalation : May cause an allergic skin reaction. Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms/injuries after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	On land, sweep or shovel into suitable containers. Collect spillage. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	No naked lights. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. D
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/… equipment. Comply with applicable regulations.
Storage conditions :	Keep container tightly closed. Store in original container. Store in a dry place.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	chloroform-like odor.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-57 °C
Freezing point :	No data available
Boiling point :	115 - 117
Flash point :	32 °C
Auto-ignition temperature :	4160 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable liquid and vapour
Vapour pressure :	12.5 mm Hg at 200C
Relative vapour density at 20°C :	3.3
Density :	1.18 g/cm3
Solubility :	Water: Moderate (1-10%)
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.038 - 0.21 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Overheating. Direct sunlight. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. Oral: Toxic if swallowed.
Skin corrosion/irritation :	Causes severe skin burns and eye damage.
Serious eye damage/irritation :	Causes serious eye damage.
Respiratory or skin sensitisation :	May cause an allergic skin reaction.
Germ cell mutagenicity :	Not classified
Carcinogenicity :	May cause cancer.
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Toxic if swallowed. Toxic in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2023
UN-No. (IMDG) :	2023
UN-No. (IATA) :	2023
UN-No. (ADN) :	2023
UN-No. (RID) :	2023
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	EPICHLOROHYDRIN
Proper Shipping Name (IMDG) :	EPICHLOROHYDRIN
Proper Shipping Name (IATA) :	EPICHLOROHYDRIN
Proper Shipping Name (ADN) :	EPICHLOROHYDRIN
Proper Shipping Name (RID) :	EPICHLOROHYDRIN
Transport document description (ADR) :	UN 2023, EPICHLOROHYDRIN, 6.1 (3), II
Transport document description (IMDG) :	UN 2023, EPICHLOROHYDRIN, 6.1 (3), II
Transport document description (IATA) :	UN 2023, EPICHLOROHYDRIN, 6.1 (3), II
Transport document description (ADN) :	UN 2023, EPICHLOROHYDRIN, 6.1 (3), II
Transport document description (RID) :	UN 2023, EPICHLOROHYDRIN, 6.1 (3), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
IMDG
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
IATA
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
ADN
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
RID
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	Yes (IMDG only)
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TF1 Special provision (ADR) : 279 Limited quantities (ADR) : 100ml Excepted quantities (ADR) : E4 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2, S9, S19 Hazard identification number (Kemler No.) : 63 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •3W APP code : A(fl)
- Transport by sea
Special provision (IMDG) : 279 Limited quantities (IMDG) : 100 ml Excepted quantities (IMDG) : E4 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2, TP13 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : A Stowage and handling (IMDG) : SW2 Flash point (IMDG) : approximately 32°C c.c. MFAG-No : 131P
- Air transport
PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y641 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 654 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 662 CAO max net quantity (IATA) : 60L Special provision (IATA) : A113 ERG code (IATA) : 6F
- Inland waterway transport
Classification code (ADN) : TF1 Special provisions (ADN) : 279, 802 Limited quantities (ADN) : 100 ml Excepted quantities (ADN) : E4 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, TOX, A Ventilation (ADN) : VE01, VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : TF1 Special provision (RID) : 279 Limited quantities (RID) : 100ml Excepted quantities (RID) : E4 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE5 Hazard identification number (RID) : 63
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions EPICHLOROHYDRIN AR is not on the REACH Candidate List EPICHLOROHYDRIN AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to VwVwS, Annex 2; WGK No 92) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Carc. 1B Carcinogenicity, Category 1B Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Flam. Liq. 3 Flammable liquids, Category 3 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Sens. 1 Sensitisation — Skin, category 1 H226 Flammable liquid and vapour H301 Toxic if swallowed H311 Toxic in contact with skin H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H318 Causes serious eye damage H331 Toxic if inhaled H350 May cause cancer R10 Flammable R23/24/25 Toxic by inhalation, in contact with skin and if swallowed R34 Causes burns R43 May cause sensitisation by skin contact R45 May cause cancer C Corrosive T Toxic