SODIUM (metal) LUMPS

SODIUM (metal) LUMPS

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : SODIUM (metal) LUMPS
Catalogue No. : AL4052 Product form : Substance
CAS Number : 7440-23-5 EC Number :
Grade : EC Index Number :
Chemical Formula : Na HSN Code : 28051100
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Substances and Mixtures
which, in contact with
water, emit flammable
gases, Category 1
H260
Skin corrosion/irritation,
Category 1B
H314
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; R14/15
C; R34
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02 GHS05GHS05
Signal word (CLP) : Danger
Hazard statements (CLP) : H260 - In contact with water releases flammable gases which may ignite
spontaneously.
H314 - Causes severe skin burns and eye damage.
Precautionary statements (CLP) : P223 - Do not allow contact with water.
P231+P232 - Handle under inert gas. Protect from moisture.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P370+P378 - In case of fire: Use ... to extinguish.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
CAS No. : 7440-23-5
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
First-aid measures after skin contact : Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
Take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : Causes severe skin burns and eye damage.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Dry powder.
Unsuitable extinguishing media : Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard : In contact with water releases flammable gases which may ignite spontaneously.
Explosion hazard : Explosive with or without contact with air.
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Do not allow water (or moist air) contact with this material.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clean up immediately by sweeping or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Do not allow contact with water.
Precautions for safe handling : Protect from moisture. Handle under inert gas. Do not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a dry place. Protect from moisture. Store in dry protected location to prevent
any moisture contact.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 22.99 g/mol
Colour : Silvery white.
Odour : odourless.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 97.8 °C
Freezing point : No data available
Boiling point : 883 °C
Flash point : 82 °C
Auto-ignition temperature : > 1150 °C
Decomposition temperature : No data available
Flammability (solid, gas) : In contact with water releases flammable gases whi
Vapour pressure : No data available
Relative vapour density at 20°C : 0.003
Density : 0.968 g/cm3
Solubility : Water: Decomposes violently in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
No additional information available
10.3 Possibility of hazardous reactions
In contact with water releases flammable gases which may ignite spontaneously. Highly reactive mat
10.4 Conditions to avoid
Moisture. Air contact. Water, humidity.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Serious eye damage, category 1, implicit
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information : Do not allow water (or moist air) contact with this material.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1428
UN-No. (IMDG) : 1428
UN-No. (IATA) : 1428
UN-No. (ADN) : 1428
UN-No. (RID) : 1428
14.2. UN proper shipping name
Proper Shipping Name (ADR) : SODIUM
Proper Shipping Name (IMDG) : SODIUM
Proper Shipping Name (IATA) : SODIUM
Proper Shipping Name (ADN) : SODIUM
Proper Shipping Name (RID) : SODIUM
Transport document description (ADR) : UN 1428, SODIUM, 4.3, I
Transport document description (IMDG) : UN 1428, SODIUM, 4.3, I
Transport document description (IATA) : UN 1428, SODIUM, 4.3, I
Transport document description (ADN) : UN 1428, SODIUM, 4.3, I
Transport document description (RID) : UN 1428, SODIUM, 4.3, I
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 4.3
Danger labels : 4.3
IMDG
Transport hazard class(es) : 4.3
Danger labels : 4.3
IATA
Transport hazard class(es) : 4.3
Danger labels : 4.3
ADN
Transport hazard class(es) : 4.3
Danger labels : 4.3
RID
Transport hazard class(es) : 4.3
Danger labels : 4.3
14.4. Packing group
Packing group (ADR) : I
Packing group (IMDG) : I
Packing group (IATA) : I
Packing group (ADN) : I
Packing group (RID) : I
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : W2
Limited quantities (ADR) : 0
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P403, IBC04
Mixed packing provisions (ADR) : MP2
Portable tank and bulk container
instructions (ADR)
: T9
Portable tank and bulk container special
provisions (ADR)
: TP7, TP33
Tank code (ADR) : L10BN(+)
Tank special provisions (ADR) : TU1, TE5, TT3, TM2
Vehicle for tank carriage : AT
Transport category (ADR) : 1
Special provisions for carriage - Packages
(ADR)
: V1
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV23
Special provisions for carriage - Operation
(ADR)
: S20
Hazard identification number (Kemler No.) : X423
Orange plates :
Tunnel restriction code (ADR) : B/E
EAC code : 4W
- Transport by sea
Limited quantities (IMDG) : 0
Excepted quantities (IMDG) : E0
Packing instructions (IMDG) : P403
Special packing provisions (IMDG) : PP31
IBC packing instructions (IMDG) : IBC04
IBC special provisions (IMDG) : B1
Tank instructions (IMDG) : T9
Tank special provisions (IMDG) : TP7, TP33
EmS-No. (Fire) : F-G
EmS-No. (Spillage) : S-N
Stowage category (IMDG) : D
Stowage and handling (IMDG) : H1
Segregation (IMDG) : SG35, SG26
MFAG-No : 138
- Air transport
PCA Excepted quantities (IATA) : E0
PCA Limited quantities (IATA) : Forbidden
PCA limited quantity max net quantity
(IATA)
: Forbidden
PCA packing instructions (IATA) : Forbidden
PCA max net quantity (IATA) : Forbidden
CAO packing instructions (IATA) : 487
CAO max net quantity (IATA) : 15kg
Special provisions (IATA) : A1
ERG code (IATA) : 4W
- Inland waterway transport
Classification code (ADN) : W2
Limited quantities (ADN) : 0
Excepted quantities (ADN) : E0
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01
Provisions for handling and stowage of the
cargo (ADN)
: HA08
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : W2
Limited quantities (RID) : 0
Excepted quantities (RID) : E0
Packing instructions (RID) : P403, IBC04
Mixed packing provisions (RID) : MP2
Portable tank and bulk container
instructions (RID)
: T9
Portable tank and bulk container special
provisions (RID)
: TP7, TP33
Tank codes for RID tanks (RID) : L10BN(+)
Special provisions for RID tanks (RID) : TU1, TE5, TT3, TM2
Transport category (RID) : 1
Special provisions for carriage – Packages
(RID)
: W1
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW23
Hazard identification number (RID) : X423
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
SODIUM METAL Extra Pure is not on the REACH Candidate List
SODIUM METAL Extra Pure is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, Slightly hazardous to water (Classification according to
AwSV; ID No. 772)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Class for fire hazard : Class III-1
Store unit : 50 liter
Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management
guidelines for the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Skin Corr. 1B Skin corrosion/irritation, Category 1B
Water-react. 1 Substances and Mixtures which, in contact with water, emit flammable gases, Category 1
H260 In contact with water releases flammable gases which may ignite spontaneously.
H314 Causes severe skin burns and eye damage.
R14/15 Reacts violently with water, liberating extremely flammable gases
R34 Causes burns
C Corrosive
F Highly flammable