SODIUM (metal) LUMPS AR |
| Synonyms : |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | SODIUM (metal) LUMPS AR | ||
| Catalogue No. : | AL4053 | Product form : | Substance |
| CAS Number : | 7440-23-5 | EC Number : | |
| Grade : | EC Index Number : | ||
| Chemical Formula : | Na | HSN Code : | 28051100 |
| Synonyms : | |||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Substances and Mixtures which, in contact with water, emit flammable gases, Category 1 H260 Skin corrosion/irritation, Category 1B H314 Full text of classification categories and H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| F; R14/15 C; R34 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS02
 GHS05
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H260 - In contact with water releases flammable gases which may ignite spontaneously H314 - Causes severe skin burns and eye damage |
| Precautionary statements (CLP) : | P223 - Keep away from any possible contact with water, because of violent reaction and possible flash fire P231+P232 - Handle under inert gas. Protect from moisture P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P370+P378 - In case of fire: Use ... for extinction |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Not applicable | |||
| CAS No. : | 7440-23-5 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. |
| First-aid measures after skin contact : | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. |
| First-aid measures after ingestion : | Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/injuries : Causes severe skin burns and eye damage. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media : | Do not use extinguishing media containing water. |
5.2 Special hazards arising from the substance or mixture |
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| Fire hazard : | In contact with water releases flammable gases which may ignite spontaneously. |
| Explosion hazard : | Explosive with or without contact with air. |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Stop release. |
6.2 Environmental precautions |
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| Do not allow water (or moist air) contact with this material. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Clear up rapidly by scoop or vacuum. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Additional hazards when processed : | Keep away from any possible contact with water, because of violent reaction and possible flash fire. |
| Precautions for safe handling : | Protect from moisture. Handle under inert gas. Do not breathe dust/fume/gas/mist/vapours/spray. |
| Hygiene measures : | Wash ... thoroughly after handling. Wash contaminated clothing before reuse. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Technical measures : | Comply with applicable regulations. |
| Storage conditions : | Store in a dry place. Protect from moisture. Store in dry protected location to prevent any moisture contact. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or face shield |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Solid |
| Molecular mass : | 22.99 g/mol |
| Colour : | Silvery white. |
| Odour : | odourless. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 97.8 °C |
| Freezing point : | No data available |
| Boiling point : | 883 °C |
| Flash point : | 82 °C |
| Auto-ignition temperature : | > 1150 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | In contact with water releases flammable gases whi |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | 0.003 |
| Density : | 0.968 g/cm3 |
| Solubility : | Water: Decomposes violently in water |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| Thermal decomposition generates : Corrosive vapours. Reacts violently with water. | |
10.2 Chemical stability |
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| No additional information available | |
10.3 Possibility of hazardous reactions |
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| In contact with water releases flammable gases which may ignite spontaneously. Highly reactive mat | |
10.4 Conditions to avoid |
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| Moisture. Water, humidity. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| Thermal decomposition generates : Corrosive vapours. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Not classified |
| Skin corrosion/irritation : | Causes severe skin burns and eye damage. |
| Serious eye damage/irritation : | Serious eye damage, category 1, implicit |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| Reproductive toxicity : | Not classified |
| Specific target organ toxicity (single exposure) : | Not classified |
| Specific target organ toxicity (repeated exposure) : | Not classified |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
| Additional information : | Do not allow water (or moist air) contact with this material. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1428 |
| UN-No. (IMDG) : | 1428 |
| UN-No. (IATA) : | 1428 |
| UN-No. (ADN) : | 1428 |
| UN-No. (RID) : | 1428 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | SODIUM |
| Proper Shipping Name (IMDG) : | SODIUM |
| Proper Shipping Name (IATA) : | SODIUM |
| Proper Shipping Name (ADN) : | SODIUM |
| Proper Shipping Name (RID) : | SODIUM |
| Transport document description (ADR) : | UN 1428, SODIUM, 4.3, I |
| Transport document description (IMDG) : | UN 1428, SODIUM, 4.3, I |
| Transport document description (IATA) : | UN 1428, SODIUM, 4.3, I |
| Transport document description (ADN) : | UN 1428, SODIUM, 4.3, I |
| Transport document description (RID) : | UN 1428, SODIUM, 4.3, I |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 4.3 |
| Danger labels : | 4.3 
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| IMDG | |
| Transport hazard class(es) : | 4.3 |
| Danger labels : | 4.3
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| IATA | |
| Transport hazard class(es) : | 4.3 |
| Danger labels : | 4.3
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| ADN | |
| Transport hazard class(es) : | 4.3 |
| Danger labels : | 4.3
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| RID | |
| Transport hazard class(es) : | 4.3 |
| Danger labels : | 4.3
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14.4. Packing group |
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| Packing group (ADR) : | I |
| Packing group (IMDG) : | I |
| Packing group (IATA) : | I |
| Packing group (ADN) : | I |
| Packing group (RID) : | I |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : W2 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E0 Packing instructions (ADR) : P403, IBC04 Mixed packing provisions (ADR) : MP2 Portable tank and bulk container instructions (ADR) : T9 Portable tank and bulk container special provisions (ADR) : TP7, TP33 Tank code (ADR) : L10BN(+) Tank special provisions (ADR) : TU1, TE5, TT3, TM2 Vehicle for tank carriage : AT Transport category (ADR) : 1 Special provisions for carriage - Packages (ADR) : V1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV23 Special provisions for carriage - Operation (ADR) : S20 Hazard identification number (Kemler No.) : X423 Orange plates : Tunnel restriction code (ADR) : B/E EAC code : 4W |
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| - Transport by sea | |
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Limited quantities (IMDG) : 0 Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P403 Packing provisions (IMDG) : PP31 IBC packing instructions (IMDG) : IBC04 IBC special provisions (IMDG) : B1 Tank instructions (IMDG) : T9 Tank special provisions (IMDG) : TP7, TP33 EmS-No. (Fire) : F-G EmS-No. (Spillage) : S-N Stowage category (IMDG) : D Stowage and handling (IMDG) : H1 Segregation (IMDG) : SG35, SG26 MFAG-No : 138 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : 487 CAO max net quantity (IATA) : 15kg Special provision (IATA) : A1 ERG code (IATA) : 4W |
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| - Inland waterway transport | |
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Classification code (ADN) : W2 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Provisions for handling and stowage of the cargo (ADN) : HA08 Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : W2 Limited quantities (RID) : 0 Excepted quantities (RID) : E0 Packing instructions (RID) : P403, IBC04 Mixed packing provisions (RID) : MP2 Portable tank and bulk container instructions (RID) : T9 Portable tank and bulk container special provisions (RID) : TP7, TP33 Tank codes for RID tanks (RID) : L10BN(+) Special provisions for RID tanks (RID) : TU1, TE5, TT3, TM2 Transport category (RID) : 1 Special provisions for carriage – Packages (RID) : W1 Special provisions for carriage – Loading and unloading (RID) : CW23 Hazard identification number (RID) : X423 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions SODIUM (METAL) AR Coated with liquid paraffin is not on the REACH Candidate List SODIUM (METAL) AR Coated with liquid paraffin is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 3; WGK No 772) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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