DIBUTYL PHTHALATE For Synthesis |
| Synonyms : n-Butyl phthalate; DBP; Phthalic acid dibutyl ester |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | DIBUTYL PHTHALATE (for synthesis) | ||
| Catalogue No. : | AL1688 | Product form : | Substance |
| CAS Number : | 84-74-2 | EC Number : | 201-557-4 |
| Grade : | EC Index Number : | 607-318-00-4 | |
| Chemical Formula : | HSN Code : | 29173910 | |
| Synonyms : | n-Butyl phthalate / Phthalic acid dibutyl ester / DB | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Industrial. For professional use only | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Reproductive toxicity, Category 1A H360Df Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Repr.Cat.2; R61 Repr.Cat.3; R62 N; R50 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS08
 GHS09
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H360Df - May damage the unborn child. Suspected of damaging fertility. H400 - Very toxic to aquatic life. |
| Precautionary statements (CLP) : | P201 - Obtain special instructions before use. P273 - Avoid release to the environment. P308+P313 - IF exposed or concerned: Get medical advice/attention. |
2.3 Other hazards |
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| Other hazards : | This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | DIBUTYL PHTHALATE FOR SYNTHESIS | ||
| CAS No. : | 84-74-2 | ||
| EC Index No. : | 607-318-00-4 | ||
| EC No. : | 201-557-4 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Assure fresh air breathing. Allow the victim to rest. |
| First-aid measures after skin contact : | Wash with plenty of water/…. Get immediate medical advice/attention. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Do not induce vomiting. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects : Suspected of damaging fertility. May damage the unborn child. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Obtain special instructions before use. Avoid contact with skin and eyes. Do not breathe vapours. |
| Hygiene measures : | Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid |
| Molecular mass : | 278.35 g/mol |
| Colour : | Clear viscous. |
| Odour : | slight aromatic odor. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | -35 °C |
| Freezing point : | No data available |
| Boiling point : | 340 °C |
| Flash point : | 171 °C |
| Auto-ignition temperature : | 402 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | < 0.01 @20°C |
| Relative vapour density at 20°C : | 9.6 |
| Density : | 1.05 g/cm3 |
| Solubility : | Water: Insoluble in water |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | 0.0047 vol % |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Air contact. Direct sunlight. Open flame. Overheating. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Not classified |
| Skin corrosion/irritation : | Not classified |
| Serious eye damage/irritation : | Not classified |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| STOT-single exposure : | Not classified |
| STOT-repeated exposure : | Not classified |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | Ecology - water : Very toxic to aquatic life. |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| DIBUTYL PHTHALATE FOR SYNTHESIS (84-74-2) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII |
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12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 3082 |
| UN-No. (IMDG) : | 3082 |
| UN-No. (IATA) : | 3082 |
| UN-No. (ADN) : | 3082 |
| UN-No. (RID) : | 3082 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. |
| Proper Shipping Name (IMDG) : | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. |
| Proper Shipping Name (IATA) : | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. |
| Proper Shipping Name (ADN) : | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. |
| Proper Shipping Name (RID) : | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. |
| Transport document description (ADR) : | UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 9 |
| Danger labels : | 9 
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| IMDG | |
| Transport hazard class(es) : | 9 |
| Danger labels : | 9
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| IATA | |
| Transport hazard class(es) : | 9 |
| Danger labels : | 9
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| ADN | |
| Transport hazard class(es) : | 9 |
| Danger labels : | 9
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| RID | |
| Transport hazard class(es) : | 9 |
| Danger labels : | 9
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14.4. Packing group |
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| Packing group (ADR) : | III |
| Packing group (IMDG) : | III |
| Packing group (IATA) : | III |
| Packing group (ADN) : | III |
| Packing group (RID) : | III |
14.5. Environmental hazards |
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| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : M6 Special provisions (ADR) : 274, 335, 375, 601 Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Special packing provisions (ADR) : PP1 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1, TP29 Tank code (ADR) : LGBV Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13 Hazard identification number (Kemler No.) : 90 Orange plates : Tunnel restriction code (ADR) : - EAC code : •3Z |
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| - Transport by sea | |
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Special provisions (IMDG) : 274, 335, 969 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : LP01, P001 Special packing provisions (IMDG) : PP1 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP2, TP29 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-F Stowage category (IMDG) : A MFAG-No : 171 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y964 PCA limited quantity max net quantity (IATA) : 30kgG PCA packing instructions (IATA) : 964 PCA max net quantity (IATA) : 450L CAO packing instructions (IATA) : 964 CAO max net quantity (IATA) : 450L Special provisions (IATA) : A97, A158, A197 ERG code (IATA) : 9L |
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| - Inland waterway transport | |
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Classification code (ADN) : M6 Special provisions (ADN) : 274, 335, 375, 601 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : M6 Special provisions (RID) : 274, 335, 375, 601 Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Special packing provisions (RID) : PP1 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1, TP29 Tank codes for RID tanks (RID) : LGBV Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W12 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW31 Colis express (express parcels) (RID) : CE8 Hazard identification number (RID) : 90 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions Dibutyl phthalate (DBP) is on the REACH Candidate List Dibutyl phthalate (DBP) is on the REACH Annex XIV List: Authorisation number Sunset date REACH authorisation exemptions 21/01/2015 |
| 15.1.2. National regulations |
| Germany |
| Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to AwSV; ID No. 186) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : DIBUTYL PHTHALATE FOR SYNTHESIS is listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : DIBUTYL PHTHALATE FOR SYNTHESIS is listed |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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