SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	DIISOPROPYLAZODICARBOXYLATE
Catalogue No. :	AL1796	Product form :	Substance
CAS Number :	2446-83-5	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	29270090
Synonyms :	DIAD; Diisopropylazodiformate
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial. For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Carcinogenicity, Category 2 H351 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Specific target organ toxicity Repeated exposure, Category 2 H373 Hazardous to the aquatic environment Chronic Hazard, Category 2 H411 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.3; R40 Xn; R48/20/22 Xi; R36/37/38 N; R51/53 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS07 GHS08 GHS09
Signal word (CLP) :	Warning
Hazard statements (CLP) :	H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H351 - Suspected of causing cancer H373 - May cause damage to organs through prolonged or repeated exposure H411 - Toxic to aquatic life with long lasting effects
Precautionary statements (CLP) :	P261 - Avoid breathing vapours, spray, dust, fume, gas P273 - Avoid release to the environment P281 - Use personal protective equipment as required P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		DIISOPROPYLAZODICARBOXYLATE FOR SYNTHESIS
CAS No. :		2446-83-5
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact :	Wash with plenty of soap and water. Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Do not induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : Causes damage to organs. Symptoms/injuries after inhalation : May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Dry powder. Carbon dioxide. Foam. Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin and eyes. Use only outdoors or in a well-ventilated area. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Orange.
Odour :	No data available
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	3 - 5 °C
Freezing point :	No data available
Boiling point :	No data available
Flash point :	106 °C
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Density :	1.027 g/ml at 25°C
Solubility :	Water: Insoluble
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat.
10.5 Incompatible materials
Oxidizing agent. Strong bases.
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye irritation.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Suspected of causing cancer.
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	May cause respiratory irritation.
Specific target organ toxicity (repeated exposure) :	May cause damage to organs through prolonged or repeated exposure.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	DIISOPROPYLAZODICARBOXYLATE FOR SYNTHESIS (2446-83-5) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	3082
UN-No. (IMDG) :	3082
UN-No. (IATA) :	3082
UN-No. (ADN) :	3082
UN-No. (RID) :	3082
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Proper Shipping Name (IMDG) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Proper Shipping Name (IATA) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Proper Shipping Name (ADN) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Proper Shipping Name (RID) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Transport document description (ADR) :	UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	9
Danger labels :	9
IMDG
Transport hazard class(es) :	9
Danger labels :	9
IATA
Transport hazard class(es) :	9
Danger labels :	9
ADN
Transport hazard class(es) :	9
Danger labels :	9
RID
Transport hazard class(es) :	9
Danger labels :	9
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : M6 Special provision (ADR) : 274, 335, 601, 375 Limited quantities (ADR) : 5L Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Special packing provisions (ADR) : PP1 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1, TP29 Tank code (ADR) : LGBV Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13 Hazard identification number (Kemler No.) : 90 Orange plates : Tunnel restriction code (ADR) : E EAC code : •3Z
- Transport by sea
Special provision (IMDG) : 274, 335, 969 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 Packing provisions (IMDG) : PP1 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP2, TP29 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-F Stowage category (IMDG) : A MFAG-No : 171
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y964 PCA limited quantity max net quantity (IATA) : 30kgG PCA packing instructions (IATA) : 964 PCA max net quantity (IATA) : 450L CAO packing instructions (IATA) : 964 CAO max net quantity (IATA) : 450L Special provision (IATA) : A97, A158, A197 ERG code (IATA) : 9L
- Inland waterway transport
Classification code (ADN) : M6 Special provisions (ADN) : 274, 335, 375, 601 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : M6 Special provision (RID) : 274, 335, 375, 601 Limited quantities (RID) : 5L Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Special packing provisions (RID) : PP1 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1, TP29 Tank codes for RID tanks (RID) : LGBV Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W12 Special provisions for carriage – Loading and unloading (RID) : CW13, CW31 Colis express (express parcels) (RID) : CE8 Hazard identification number (RID) : 90
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions DIISOPROPYLAZODICARBOXYLATE FOR SYNTHESIS is not on the REACH Candidate List DIISOPROPYLAZODICARBOXYLATE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 3; WGK No 7045) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Recommendations Danish Regulation : Young people below the age of 18 years are not a
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2 Carc. 2 Carcinogenicity, Category 2 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H351 Suspected of causing cancer H373 May cause damage to organs through prolonged or repeated exposure H411 Toxic to aquatic life with long lasting effects R36/37/38 Irritating to eyes, respiratory system and skin R40 Limited evidence of a carcinogenic effect R48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment N Dangerous for the environment Xi Irritant Xn Harmful