FURFURAL AR/ACS |
Synonyms : 2-Furaldehyde, Furan-2-carboxaldehyde |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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Chemical Name : | FURFURALDEHYDE AR | ||
Catalogue No. : | AL2245 | Product form : | Substance |
CAS Number : | 98-01-1 | EC Number : | 202-627-7 |
Grade : | EC Index Number : | 605-010-00-4 | |
Chemical Formula : | C5H4O2 | HSN Code : | 29321200 |
Synonyms : | 2-Furaldehyde, Furan-2-carboxaldehyde | ||
Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
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Use of the substance/mixture : | Industrial. For professional use only. | ||
Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
Acute toxicity (inhal.), Category 3 H331 Acute toxicity (oral), Category 3 H301 Acute toxicity (dermal), Category 4 H312 Carcinogenicity, Category 2 H351 Serious eye damage/eye irritation, Category 2 H319 Skin corrosion/irritation, Category 2 H315 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Full text of classification categories and H statements : see section 16 |
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Classification according to Directive 67/548/EEC or 1999/45/EC | |
Carc.Cat.3; R40 T; R23/25 Xn; R21 Xi; R36/37/38 Full text of R-phrases: see section 16 |
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Adverse physicochemical, human health and environmental effects | |
No additional information available | |
2.2 Label elements |
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Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
Hazard pictograms (CLP) : | GHS06 GHS08 |
Signal word (CLP) : | Danger |
Hazard statements (CLP) : | H301+H331 - Toxic if swallowed or if inhaled H312 - Harmful in contact with skin H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H351 - Suspected of causing cancer |
Precautionary statements (CLP) : | P261 - Avoid breathing dust, fume, gas, vapours, spray, mist P280 - Wear protective clothing, protective gloves, eye protection, face protection P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P311 - Call a POISON CENTER or doctor/physician |
2.3 Other hazards |
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Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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Name : | FURFURAL AR/ACS | ||
CAS No. : | 98-01-1 | ||
EC Index No. : | 605-010-00-4 | ||
EC No. : | 202-627-7 | ||
Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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Not applicable |
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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First-aid measures after inhalation : | Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. |
First-aid measures after skin contact : | Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap and water. Wash contaminated clothing before reuse. Get medical advice/attention. |
First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. |
First-aid measures after ingestion : | Rinse mouth. Obtain emergency medical attention. Immediately call a POISON CENTER or doctor/physician. Specific treatment (see ... on this label). |
4.2 Most important symptoms and effects, both acute and delayed |
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Symptoms relating to use : | Symptoms/injuries after inhalation : May cause respiratory irritation. Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Harmful in contact with skin. Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. |
4.3 Indication of any immediate medical attention and special treatment needed |
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General information : | No additional information available |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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Suitable extinguishing media : | Water spray. Foam. Dry powder. Carbon dioxide. |
Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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Special procedures : | No additional information available |
5.3 Advice for firefighters |
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Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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Protective equipment | Use personal protective equipment as required |
Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
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Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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Precautions for safe handling : | Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid contact with skin and eyes. Use only outdoors or in a well-ventilated area. Do not breathe vapours. |
Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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No additional information available |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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No additional information available | |
8.2 Exposure controls |
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Hand protection : | Protective gloves |
Eye protection : | Chemical goggles or safety glasses |
Skin and body protection : | Wear suitable protective clothing |
Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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Physical state : | Liquid Colour |
Colour : | Colorless to brown. |
Odour : | almond odor. |
Odour threshold : | No data available |
pH value : | No data available |
Relative evaporation rate (butylacetate=1) : | No data available |
Melting point : | -36 °C |
Freezing point : | No data available |
Boiling point : | 162 °C |
Flash point : | 60 °C |
Auto-ignition temperature : | 316 °C |
Decomposition temperature : | No data available |
Flammability (solid, gas) : | No data available |
Vapour pressure : | 2.3 hPa at 20 °C |
Relative vapour density at 20°C : | 3.32 |
Density : | 1.16 g/cm3 |
Solubility : | Water: Soluble |
Log Pow : | 0.41 |
Viscosity, kinematic : | No data available |
Viscosity, dynamic : | No data available |
Explosive properties : | No data available |
Oxidising properties : | No data available |
Explosive limits : | 2.1 - 19.3 vol % |
9.2 Other information |
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No additional information available |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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No additional information available | |
10.2 Chemical stability |
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No additional information available | |
10.3 Possibility of hazardous reactions |
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No additional information available | |
10.4 Conditions to avoid |
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Direct sunlight. Extremely high or low temperatures. | |
10.5 Incompatible materials |
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Strong acids. Strong bases. | |
10.6 Hazardous decomposition products |
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No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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Acute toxicity : | Inhalation: Toxic if inhaled. Oral: Toxic if swallowed. Dermal: Harmful in contact with skin. |
Skin corrosion/irritation : | Causes skin irritation. |
Serious eye damage/irritation : | Causes serious eye irritation. |
Respiratory or skin sensitisation : | Not classified |
Germ cell mutagenicity : | Not classified |
Carcinogenicity : | Suspected of causing cancer. |
Reproductive toxicity : | Not classified |
Specific target organ toxicity (single exposure) : | May cause respiratory irritation. |
Specific target organ toxicity (repeated exposure) : | Not classified |
Aspiration hazard : | Not classified |
Potential adverse human health effects and symptoms : | Harmful in contact with skin. Toxic if swallowed. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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Bioaccumulative potential : | FURFURAL AR/ACS (98-01-1) Log Pow 0.41 |
12.4 Mobility in soil |
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Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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No additional information available | |
12.6 Other adverse effects |
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Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
Ecology - waste materials : | Hazardous waste due to toxicity. |
SECTION 14: Transport information |
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In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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UN-No. (ADR) : | 1199 |
UN-No. (IMDG) : | 1199 |
UN-No. (IATA) : | 1199 |
UN-No. (ADN) : | 1199 |
UN-No. (RID) : | 1199 |
14.2. UN proper shipping name |
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Proper Shipping Name (ADR) : | FURALDEHYDES |
Proper Shipping Name (IMDG) : | FURALDEHYDES |
Proper Shipping Name (IATA) : | FURALDEHYDES |
Proper Shipping Name (ADN) : | FURALDEHYDES |
Proper Shipping Name (RID) : | FURALDEHYDES |
Transport document description (ADR) : | UN 1199, FURALDEHYDES, 6.1 (3), II |
Transport document description (IMDG) : | UN 1199, FURALDEHYDES, 6.1 (3), II |
Transport document description (IATA) : | UN 1199, FURALDEHYDES, 6.1 (3), II |
Transport document description (ADN) : | UN 1199, FURALDEHYDES, 6.1 (3), II |
Transport document description (RID) : | UN 1199, FURALDEHYDES, 6.1 (3), II |
14.3. Transport hazard class(es) |
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ADR | |
Transport hazard class(es) : | 6.1 (3) |
Danger labels : | 6.1, 3 |
IMDG | |
Transport hazard class(es) : | 6.1 (3) |
Danger labels : | 6.1, 3 |
IATA | |
Transport hazard class(es) : | 6.1 (3) |
Danger labels : | 6.1, 3 |
ADN | |
Transport hazard class(es) : | 6.1 (3) |
Danger labels : | 6.1, 3 |
RID | |
Transport hazard class(es) : | 6.1 (3) |
Danger labels : | 6.1, 3 |
14.4. Packing group |
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Packing group (ADR) : | II |
Packing group (IMDG) : | II |
Packing group (IATA) : | II |
Packing group (ADN) : | II |
Packing group (RID) : | II |
14.5. Environmental hazards |
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Dangerous for the environment : | No |
Marine pollutant : | No |
Other information : | No supplementary information available |
14.6. Special precautions for user |
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- Overland transport | |
Classification code (ADR) : TF1 Limited quantities (ADR) : 100ml Excepted quantities (ADR) : E4 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2, S9, S19 Hazard identification number (Kemler No.) : 63 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •3Y |
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- Transport by sea | |
Limited quantities (IMDG) : 100 ml Excepted quantities (IMDG) : E4 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : A MFAG-No : 132P |
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- Air transport | |
PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y641 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 654 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 662 CAO max net quantity (IATA) : 60L ERG code (IATA) : 6F |
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- Inland waterway transport | |
Not regulated | |
- Rail transport | |
Not regulated | |
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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Not applicable |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
15.1.1 EU-Regulations : |
No REACH Annex XVII restrictions FURFURAL AR/ACS is not on the REACH Candidate List FURFURAL AR/ACS is not on the REACH Annex XIV List |
15.1.2. National regulations |
Germany |
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 2; WGK No 113) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
Denmark |
Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
No additional information available |
SECTION 16: Other Information |
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