FURFURAL AR/ACS

FURFURAL AR/ACS

Synonyms : 2-Furaldehyde, Furan-2-carboxaldehyde

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : FURFURALDEHYDE AR
Catalogue No. : AL2245 Product form : Substance
CAS Number : 98-01-1 EC Number : 202-627-7
Grade : EC Index Number : 605-010-00-4
Chemical Formula : C5H4O2 HSN Code : 29321200
Synonyms : 2-Furaldehyde, Furan-2-carboxaldehyde
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial. For professional use only.
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (inhal.),
Category 3
H331
Acute toxicity (oral),
Category 3
H301
Acute toxicity (dermal),
Category 4
H312
Carcinogenicity, Category
2
H351
Serious eye damage/eye
irritation, Category 2
H319
Skin corrosion/irritation,
Category 2
H315
Specific target organ
toxicity Single
exposure, Category 3,
Respiratory tract irritation
H335
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.3; R40
T; R23/25
Xn; R21
Xi; R36/37/38
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS06GHS06 GHS08GHS08
Signal word (CLP) : Danger
Hazard statements (CLP) : H301+H331 - Toxic if swallowed or if inhaled
H312 - Harmful in contact with skin
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
H351 - Suspected of causing cancer
Precautionary statements (CLP) : P261 - Avoid breathing dust, fume, gas, vapours, spray, mist
P280 - Wear protective clothing, protective gloves, eye protection, face protection
P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or
doctor/physician
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P311 - Call a POISON CENTER or doctor/physician
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : FURFURAL AR/ACS
CAS No. : 98-01-1
EC Index No. : 605-010-00-4
EC No. : 202-627-7
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact : Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap
and water. Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get immediate medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Obtain emergency medical attention. Immediately call a POISON
CENTER or doctor/physician. Specific treatment (see ... on this label).
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing
significant health hazard. Harmful in contact with skin. Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
Symptoms/injuries after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious
health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information : No additional information available

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Water spray. Foam. Dry powder. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills
with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid contact with skin and eyes. Use only outdoors or in a well-ventilated area. Do not breathe vapours.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Colorless to brown.
Odour : almond odor.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -36 °C
Freezing point : No data available
Boiling point : 162 °C
Flash point : 60 °C
Auto-ignition temperature : 316 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 2.3 hPa at 20 °C
Relative vapour density at 20°C : 3.32
Density : 1.16 g/cm3
Solubility : Water: Soluble
Log Pow : 0.41
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 2.1 - 19.3 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
No additional information available
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5 Incompatible materials
Strong acids. Strong bases.
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Inhalation: Toxic if inhaled. Oral: Toxic if swallowed. Dermal: Harmful in contact with
skin.
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : May cause respiratory irritation.
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful in contact with skin. Toxic if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : FURFURAL AR/ACS (98-01-1) Log Pow 0.41
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...
Ecology - waste materials : Hazardous waste due to toxicity.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1199
UN-No. (IMDG) : 1199
UN-No. (IATA) : 1199
UN-No. (ADN) : 1199
UN-No. (RID) : 1199
14.2. UN proper shipping name
Proper Shipping Name (ADR) : FURALDEHYDES
Proper Shipping Name (IMDG) : FURALDEHYDES
Proper Shipping Name (IATA) : FURALDEHYDES
Proper Shipping Name (ADN) : FURALDEHYDES
Proper Shipping Name (RID) : FURALDEHYDES
Transport document description (ADR) : UN 1199, FURALDEHYDES, 6.1 (3), II
Transport document description (IMDG) : UN 1199, FURALDEHYDES, 6.1 (3), II
Transport document description (IATA) : UN 1199, FURALDEHYDES, 6.1 (3), II
Transport document description (ADN) : UN 1199, FURALDEHYDES, 6.1 (3), II
Transport document description (RID) : UN 1199, FURALDEHYDES, 6.1 (3), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
IMDG
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
IATA
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
ADN
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
RID
Transport hazard class(es) : 6.1 (3)
Danger labels : 6.1, 3
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TF1
Limited quantities (ADR) : 100ml
Excepted quantities (ADR) : E4
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container
instructions (ADR)
: T7
Portable tank and bulk container special
provisions (ADR)
: TP2
Tank code (ADR) : L4BH
Tank special provisions (ADR) : TU15, TE19
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S2, S9, S19
Hazard identification number (Kemler No.) : 63
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : •3Y
- Transport by sea
Limited quantities (IMDG) : 100 ml
Excepted quantities (IMDG) : E4
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-D
Stowage category (IMDG) : A
MFAG-No : 132P
- Air transport
PCA Excepted quantities (IATA) : E4
PCA Limited quantities (IATA) : Y641
PCA limited quantity max net quantity
(IATA)
: 1L
PCA packing instructions (IATA) : 654
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 662
CAO max net quantity (IATA) : 60L
ERG code (IATA) : 6F
- Inland waterway transport
Not regulated
- Rail transport
Not regulated
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
FURFURAL AR/ACS is not on the REACH Candidate List
FURFURAL AR/ACS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to
VwVwS, Annex 2; WGK No 113)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class III-1
Store unit : 50 liter
Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management
guidelines for the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Carc. 2 Carcinogenicity, Category 2
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Skin Irrit. 2 Skin corrosion/irritation, Category 2
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation
H301 Toxic if swallowed
H312 Harmful in contact with skin
H315 Causes skin irritation
H319 Causes serious eye irritation
H331 Toxic if inhaled
H335 May cause respiratory irritation
H351 Suspected of causing cancer
R21 Harmful in contact with skin
R23/25 Toxic by inhalation and if swallowed
R36/37/38 Irritating to eyes, respiratory system and skin
R40 Limited evidence of a carcinogenic effect
T Toxic
Xi Irritant
Xn Harmful